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Intermolecular C−H Bond Activation Reactions Promoted by Transient Titanium A...
The neopentylidene−neopentyl complex (PNP)TiCHtBu(CH2tBu) (2; PNP- = N[2-P(CHMe2)2-4-methylphenyl]2), prepared from the precursor (PNP)TiCHtBu(OTf) (1) and LiCH2tBu, extrudes... -
Structural Transformations of Carbon Nanotubes under Hydrostatic Pressure
We used simulations with a classical force field to study the transformation under hydrostatic pressure of isolated single-walled nanotubes (SWNT) from a circular to a collapsed... -
r37980778c78--abc1e72da70bd099495e0a7da49cd264
This paper reports the synthesis and crystal structure of a cobalt aminomethylenediphosphonate compound NaCo2{NH3CH(PO3)(PO3H0.5)}2(H2O)2·xH2O (1). It shows a novel open... -
Structure Revision of Spiroleucettadine, a Sponge Alkaloid with a Bicyclic Co...
Our 2004 disclosure of the amino hemiketal-containing spiroleucettadine was met with keen interest by the natural products and synthetic communities. As repeated efforts to... -
r37980778c78--f7ae0791f29eb1b80d679c6aaac4c7af
A Methyl Group Bridging on Three Metal Atoms. Solid-State and Solution Structural Characterization of the [Re3(μ-H)3(μ3-CH3)(CO)9]- Anion -
r37980778c78--6431c2cf68a7a54fb1a5c928814018bd
In this work, we highlight several unusual characteristics of adsorption and diffusion of a variety of guest molecules, such as linear and branched alkanes with a number of C... -
Efficient Route for Cyclic Olefin Polymerization: Nonchelated Monodentate Be...
We developed a series of nonchelated monodentate benzimidazole nickel complexes, bis[2-(2,6-difluorophenyl)-1H-benzimidazole]nickel(II) dibromide (1),... -
Steering S−H and N−H Bond Activation by a Stable N-Heterocyclic Silylene: Dif...
The strikingly different behavior of the ylide-like, N-heterocyclic silylene LSi: (5: L = CH[(CCH2)CMe(NAr)2]; Ar = 2,6-iPrC6H3) versus its LSi→Ni(CO)3 complex 13 to activate... -
Synthesis, Structure, and Isomerization of Decapentynylcorannulene: Enediyne...
Decapentynylcorannulene (5) is prepared via aryl−alkyne coupling chemistry of decachlorocorannulene and trimethylstannylpentyne. The crystal structure of 5 is compared with the... -
Media 19: Propagation of polarized light in birefringent turbid media: time-r...
Originally published in Optics Express on 27 August 2001 (oe-9-5-254) -
Media 1: Channel and wedge plasmon modes of metallic V-grooves with finite me...
Originally published in Optics Express on 16 February 2009 (oe-17-4-2364) -
Detailed Magnetic Studies on Co(N<sub>3</sub>)<sub>2</sub>(4-acetylpyridine)<...
The magnetic properties of Co(N3)2(4acpy)2 have been thoroughly reexamined on both powder and well-oriented single crystal samples. This azido-bridged cobalt compound of (4, 4)... -
Multiple Coordination Geometries Supported by Methylene-Linked Guanidines
The methylene-linked bicyclic guanidine based on the 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine (hppH) framework provides a versatile platform able to support... -
r37980778c78--0f5ca9465cd716eb853ff1e1d54afccc
A kinetic model for the oxidation of mixtures of n-heptane/iso-octane, the primary reference fuels for octane rating in spark-ignited internal combustion engines, has been... -
r37980778c78--f64dae8a76d042b16f8c423ed1c32ca1
First Structural Investigation of a Super-Hydrated Zeolite -
Guest Inclusion and Structural Dynamics in 2-D Hydrogen-Bonded Metal−Organic ...
Guest Inclusion and Structural Dynamics in 2-D Hydrogen-Bonded Metal−Organic Frameworks -
Media 3: Dynamic multiple-beam counter-propagating optical traps using optica...
Originally published in Optics Express on 11 October 2010 (oe-18-21-22348) -
Charge-Transfer Salts via Cocrystallization of the Cationic Ferrocenyl Donor ...
Four new charge-transfer (CT) salts based on the cationic ferrocenylmethylpyridinium (fmp) donor (CpFeCp-CH2-Py+) and polyoxometalate (POM) acceptors, Lindqvist-type [M6O19]2−... -
Modeling the Claus Reaction: Preparation of <i>trans</i>-Pt(PPh<sub>3</sub>)...
Modeling the Claus Reaction: Preparation of trans-Pt(PPh3)2(phthalimido)S(O)2SR -
Lewis Acid Catalyzed Allylboration: Discovery, Optimization, and Application...
A full account of the development of the first catalytic manifold for the additions of allylboronates to aldehydes is described. The thermal additions (both diastereospecific...
