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Positive Cooperativity of Product Mimics in the Asymmetric Autoinduction of D...
Positive Cooperativity of Product Mimics in the Asymmetric Autoinduction of Diels−Alder Reactions Catalyzed by a VAPOL−Aluminum Catalyst -
Novel Amphiphilic Conetworks Composed of Telechelic Poly(ethylene oxide) and ...
Amphiphilic conetworks (APCNs) containing covalently bonded hydrophilic poly(ethyleneoxide) (PEO) and hydrophobic polyisobutylene (PIB) have been synthesized by chain end... -
Total Synthesis of the Ristocetin Aglycon
The first total synthesis of the ristocetin aglycon is described employing a modular and highly convergent strategy. An effective 12-step (12% overall) synthesis of the ABCD... -
Homochiral Crystallization of Microporous Framework Materials from Achiral Pr...
While it is not uncommon to form chiral crystals during crystallization, the formation of bulk porous homochiral materials from achiral building units is rare. Reported here is... -
Efficient Removal of Estrogenic Activity during Oxidative Treatment of Waters...
The discharge of synthetic and natural steroid estrogens from municipal wastewaters to the aquatic environment has received increased attention because of their potential... -
Phase-Vanishing Reactions that Use Fluorous Media as a Phase Screen. Facile, ...
In fluorous triphasic reactions, such as bromination of alkenes by dibromine and dealkylation of aromatic ethers by boron tribromide, the middle fluorous phase acts as a liquid... -
Design of an organic chromophore for p-type dye-sensitized solar cells [Errat...
A successful model for the design of efficient dyes for p-type dye-sensitized solar cells (DSSCs) is presented. As an example, a novel and efficient organic dye containing a... -
Strong Reduction of Thermal Conductivity in Nanostructured PbTe Prepared by M...
Experimental results are reported that demonstrate that nanostructuring in thermoelectric semiconductors enhances acoustic phonon scattering without the need to prepare solid... -
Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials
We report the H_2 uptake properties of six covalent organic frameworks (COFs) from first-principles-based grand canonical Monte-Carlo simulations. The predicted H_2 adsorption... -
Total Synthesis of (±)-Chartelline C
The first total synthesis of (±)-chartelline C in a concise 10-step sequence is reported. Highlights of the completion of this decades-old puzzle include (1) chemo- and... -
Au@ZIF-8: CO Oxidation over Gold Nanoparticles Deposited to Metal−Organic Fra...
Gold nanoparticles (NPs) were deposited to a zeolite-type metal−organic framework (MOF) by a simple solid grinding method. A catalyst, Au@ZIF-8, represents the first example of... -
Sol−Gel Derived Nitric-Oxide Releasing Materials that Reduce Bacterial Adhesion
Sol−Gel Derived Nitric-Oxide Releasing Materials that Reduce Bacterial Adhesion -
High-Precision Catalysts: Regioselective Hydroformylation of Internal Alkenes...
We report the formation of high-precision catalysts using encapsulated rhodium complexes. In the current example, the encapsulated rhodium catalyst shows unprecedented high... -
Spectroscopy and Electrochemistry of Ruthenium-Modified Nucleic Acids: Design...
Electron transfer (ET) reactions through DNA have been the subject of numerous investigations due to the implications for light-induced DNA damage and the quest for... -
Dissecting the Evolutionary Relationship between 14-Membered and 16-Membered ...
Dissecting the Evolutionary Relationship between 14-Membered and 16-Membered Macrolides -
Moore-Type Cyclization Leading to Arene Chromium Tricarbonyl 1,4-Diradical In...
Moore-Type Cyclization Leading to Arene Chromium Tricarbonyl 1,4-Diradical Intermediates and the Isolation of Indolines -
Halogen Substitution Patterns among Disinfection Byproducts in the Informatio...
Disinfection byproduct halogen substitution patterns were examined using Information Collection Rule data. A new metric was developed to quantify and compare extents of specific... -
A Selective and Sensitive Fluoroionophore for HgII, AgI, and CuIIwith Virtual...
A Selective and Sensitive Fluoroionophore for HgII, AgI, and CuII with Virtually Decoupled Fluorophore and Receptor Units -
Grain size effect on the plastic deformation of nanocrystalline silver
The plastic deformation of nanocrystalline Ag, with columnar grains, has been studied by molecular dynamics simulations. The nanocrystalline systems show two types of...
