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Ethylene polymerization with dimeric zirconium and hafnium silsesquioxane com...
Treatment of the silanol (c-C5H9)7Si8O12(OH) with Cp‘‘Ti(CH2Ph)3 (Cp‘‘ = 1,3-C5H3(SiMe3)2) or TiCl4 selectively affords the mono(silsesquioxane) complexes... -
Crystal Structures and Magnetic and Ferroelectric Properties of Chiral Layere...
Two homochiral 2D-layered frameworks composed of a Cu2O2 core and dicyanamide (dca) linkers, [Cu((R)-hmp)(dca)]n (1) and [Cu((S)-hmp)(dca)]n (2) (hmp* =... -
E−H Bond Activation Reactions (E = H, C, Si, Ge) at Ruthenium: Terminal Phosp...
The placement of a strongly trans-influencing ligand on a ruthenium center opposite an anchoring silyl group of the tetradentate tripodal tris(phosphino)silyl ligand, [SiPPh3]−... -
Quick, Efficient Conversion of Phenones to Conjugated Trienes via Germylene C...
The germylene Ge[CH(Si(CH3)3)2]2 reacts with phenones to give conjugated trienes. This reaction is quantitative at room temperature in minutes and has some functional group... -
Photoswitchable Luminescence of Rhenium(I) Tricarbonyl Diimines
The synthesis, characterization, and X-ray crystal structures of Re(diimine)(CO)3(dpe) (dpe = 1,2-di(4-pyridyl)ethylene) compounds are reported. The cis-dpe complexes exhibit... -
Calix[4]azacrowns as Novel Molecular Scaffolds for the Generation of Visible ...
Two calix[4]azacrowns, capped with two aminopolyamide bridges, were used as ligands for the complexation of lanthanide ions [Eu(III), Tb(III), Nd(III), Er(III), La(III)]. The... -
Highly Transparent and Refractive Polyimides with Controlled Molecular Struct...
Transparent polyimides (PIs) that have a high refractive index and low birefringence as well as good thermal and mechanical stability were synthesized by the judicious... -
Intramolecular Thiopalladation of Thioanisole-Substituted Propargyl Imines: S...
A highly selective intramolecular thiopalladation has been achieved by the treatment of o-SMeC6H4CCC(CF3)(N-4-OCH3C6H4), 1, with PdCl2(PhCN)2 in THF at 0 °C to afford... -
A Unique Nickel System having Versatile Catalytic Activity of Biological Sign...
A new dinuclear nickel(II) complex, Ni2(LH2)(H2O)2(OH)(NO3)3 (1), of an “end-off” compartmental ligand 2,6-bis(N-ethylpiperazine-iminomethyl)-4-methyl-phenolato, has been... -
Highly Luminescent Poly(Methyl Methacrylate)-Incorporated Europium Complex Su...
A novel efficient antenna complex of Eu3+ [Eu(CPFHP)3(DDXPO)] supported by a highly fluorinated carbazole-substituted β-diketonate ligand, namely,... -
Synthesis of new indolocarbazole-acceptor alternating conjugated copolymers a...
We report synthesis, properties, and optoelectronic device characteristics of six new indolocarbazole−acceptor conjugated copolymers prepared by Suzuki coupling reaction. Two... -
Hydrogen Adsorption in an Interpenetrated Dynamic Metal−Organic Framework
A metal−organic framework Zn(NDC)(4,4‘-Bpe)0.5·xG [NDC = 2,6-naphthalenedicarboxylate; 4,4‘-Bpe = 4,4‘-trans-bis(4-pyridyl)ethylene; G = guest molecules] has been synthesized,... -
Novel Manganese(II) Sulfonate−Phosphonates with Dinuclear, Tetranuclear, and ...
Hydrothermal reactions of manganese(II) salts with m-sulfophenylphosphonic acid (m-HO3S−Ph−PO3H2, H3L) and 1,10-phenanthroline (phen) led to six novel manganese(II)... -
Preparation, Structure, and Ethylene Polymerization Behavior of Bis(imino)pyr...
The synthesis, characterization, and ethylene polymerization behavior of a family of chromium(III) complexes of formula [2,6-bis(imino)pyridyl]CrCl3 is reported. The X-ray... -
Syntheses, Structures, Near-Infrared and Visible Luminescence, and Magnetic P...
Reactions of tripodal ligand 1,3,5-tris(imidazole-1-ylmethyl)-2,4,6-trimethylbenzene (L) with lanthanide metal salts and triethyl orthoformate led to the formation of six... -
Highly Luminescent Homoleptic Europium Chelates
The need for efficient and photostable lanthanide luminescent materials is dramatically increasing, in particular with respect to their growing application in lighting devices... -
Noncentrosymmetry in New Templated Gallium Fluorophosphates
Two new noncentrosymmetric polar gallium fluorophosphates have been synthesized under mild hydrothermal conditions through the use of enantiomorphically pure sources of either... -
Reverse Photochromic Behavior of an Iron−Magnesium Complex
We have obtained a novel heterobimetallic iron−magnesium complex, (THF)4Mg(μ-Br)2FeBr2 (THF = tetrahydrofuran), which showed reverse photochromism in THF. The response exhibited... -
New Luminescent Cyclometalated Iridium(III) Diimine Complexes as Biological L...
We report the synthesis, characterization, and photophysical and electrochemical properties of thirty luminescent cyclometalated iridium(III) diimine complexes Ir(N-C)2(N-N)... -
Disilyl Complexes of Zirconium, Hafnium, and Tantalum. Their Synthesis, Chara...
Cyclopentadienyl-free disilyl amide complexes [(Me2N)3M(SiButPh2)2]- (M = Zr, 1; Hf, 2 as [Li(THF)4]+ salts), K(18-crown-6)3/2{(Me2N)3M[(Me3Si)2Si-(CH2)2-Si(SiMe3)2]} (M = Zr,...
