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Intermolecular Activation of Hydrocarbon C−H Bonds Initiated by the Tungsten ...
trans-CpW(NO)(CH2EMe3)(H)(PMe3) (E = C, Si) complexes can be prepared by the hydrogenation at 1 atm of the appropriate CpW(NO)(CH2EMe3)2 precursor in the presence of a slight... -
Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene...
This contribution describes the implementation of the binuclear organotitanium “constrained geometry catalysts” (CGCs),... -
Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Tr...
Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Trigonal Monopyramidal Geometries at both Zr and Co -
Thermal Conductivities of Alternatives to CFC-11 for Foam Insulation
The present work examines the thermal conductivities of several dilute vapors which are potential alternatives to chlorofluorocarbons (CFCs) for cellular-plastic foams. Thermal... -
r37980778c78--bd0bde9a0115982ec94b687d90366bb5
The unusual luminescence behavior of the two-coordinate gold(I) carbene complex, Au{C(NHMe)2}2·0.5(acetone), is reported. Upon freezing in a liquid N2 bath, the colorless,... -
r37980778c78--0e3ed717b28aa9ee7521453dd30ee1ee
The ammonium-directed olefinic oxidation of a range of cyclic allylic and homoallylic amines has been investigated. Functionalization of a range of allylic... -
r37980778c78--bc1a7e8debaa1c4e7a35f080b451a419
Macrocyclic and fused bicyclic dipeptides are complementary motifs for mimicry of different types of β-turn geometry. Macrocyclic dipeptide mimics have served as precursors for... -
Electrocatalytic Hydrogen Evolution at Low Overpotentials by Cobalt Macrocycl...
Cobalt complexes supported by diglyoxime ligands of the type Co(dmgBF2)2(CH3CN)2 and Co(dpgBF2)2(CH3CN)2 (where dmgBF2 is difluoroboryl-dimethylglyoxime and dpgBF2 is... -
C−H Bond Activation and Subsequent C−C Bond Formation Promoted by Osmium: 2-...
Complex OsH2Cl2(PiPr3)2 promotes the C−H activation of 2-vinylpyridine and subsequently couples the activated substrate with a second 2-vinylpyridine and two acetylene... -
r37980778c78--b8a15f8c4ca1e3b1a90310c613071d8a
We demonstrate here the single-atom migration of Tb, Gd, or Ce metal from cage to cage through an intentionally induced atomic path within a carbon nanopeapod. The atomic path... -
Primers used in this study.
a Liu et al., 2011 [19]. b Ji et al., 2007 [20]. c Wei et al., 2010 [21]. d Noteborn et al., 2013 [22]. *Positions correspond to: IBDV (JQ684022), IBV (KJ425500), AEV... -
Gd<sub>5−<i>x</i></sub>Y<sub><i>x</i></sub><i>Tt</i><sub>4</sub> (<i>Tt</i> =...
A crystallographic study and theoretical assessment of the Gd/Y site preferences in the Gd5−xYxTt4 (Tt = Si, Ge) series prepared by high-temperature methods is presented. All... -
Chiral Induction in Quinoline-Derived Oligoamide Foldamers: Assignment of He...
Chiral groups attached to the end of quinoline-derived oligoamide foldamers give rise to chiral helical induction in solution. Using various chiral groups, diastereomeric... -
Ortho-Substituted Catechol Derivatives: The Effect of Intramolecular Hydroge...
This paper reports a series of chloride anion receptors containing two catechol head groups connected through their ortho-positions via a spacer chain. The linking group chosen... -
Domino Metathesis Involving ROM-RCM of Substituted Norbornenes. Rapid Access ...
Domino metathesis involving ROM-RCM of appropriately constructed norbornene derivatives having multiple alkene chains leads to direct access of highly functionalized bridged... -
r37980778c78--1638705836aac7fe8e091197730072c2
In this report, an open-framework aluminophosphite (denoted as NKX-6) with large cavities and channel structure has been synthesized hydrothermally. Two crystals of NKX-6 with... -
r37980778c78--e17098d9bfd440ef43783be384687738
The ammonium-directed olefinic oxidation of a range of cyclic allylic and homoallylic amines has been investigated. Functionalization of a range of allylic... -
r37980778c78--c2e058e9f2f01b1c25af7d03fb1f0979
The structure of {p-C6H4[CH2OCH2C(pz)3]2[Ru(p-cymene)]2}Cl4·14H2O (pz = pyrazolyl ring) contains a one-dimensional water chain associated into an inorganic (carbon-free) layer... -
r37980778c78--2f61df8bf3f2c60d93cd74266705fb7c
The ammonium-directed olefinic oxidation of a range of cyclic allylic and homoallylic amines has been investigated. Functionalization of a range of allylic... -
r37980778c78--bbd4945cba965c19bacbd13ad769325b
The ammonium-directed olefinic oxidation of a range of cyclic allylic and homoallylic amines has been investigated. Functionalization of a range of allylic...
