336 items found

Types: publication Tags: Biochemistry Chemical Sciences not elsewhere classified keywords.General Chemistry

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  • publication

    Pore-filling-dependent selectivity effects in the vapor-phase separation of x...

    Vapor-phase adsorption and separation of the C8 alkylaromatic components p-xylene, m-xylene, o-xylene, and ethylbenzene on the metal-organic framework MIL-47 have been studied....
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    An All-Inorganic, Polyoxometalate-Based Catechol Dioxygenase That Exhibits >1...

    Following a critical analysis of the dioxygenase literature and injection of the insights therein into the development of new dioxygenase catalysts, two new, of four total...
  • publication

    Design and Characterization of a Heterodimeric Coiled Coil that Forms Exclusi...

    Design and Characterization of a Heterodimeric Coiled Coil that Forms Exclusively with an Antiparallel Relative Helix Orientation
  • publication

    Source Apportionment of PAH in Hamilton Harbour Suspended Sediments: Comparis...

    A total of 26 suspended sediment samples collected over a 5-year period in Hamilton Harbour, Ontario, Canada and surrounding creeks were analyzed for a suite of polycyclic...
  • publication

    Remote Sensing Study of Emissions from Motor Vehicles in the Metropolitan Are...

    Remote sensing was employed for the first time to measure nitric oxide (NO) levels of on-road light-duty motor vehicles of the Metropolitan Area of Mexico City (MAMC). The...
  • publication

    Cross-Talk between Lung and Systemic Circulation during Carbon Nanotube Respi...

    Nanotechnology is an emerging field that demands urgent development of adequate toxicology and risk assessment. The previous experimental data on carbon nanotube respiratory...
  • publication

    A Gene Cluster Containing Two Fungal Polyketide Synthases Encodes the Biosynt...

    The genome sequencing of Aspergillus species including A. nidulans reveals that the products of many of the secondary metabolism pathways in these fungi have not been...
  • publication

    Reducing Motor Vehicle Greenhouse Gas Emissions in a Non-California State: A ...

    Approaches for reducing greenhouse gas (GHG) emissions from motor vehicles include more-efficient vehicles, lower-carbon fuels, and reducing vehicle-kilometers traveled (VKT)....
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    Packing Modes of Distyrylbenzene Derivatives

    A range of 1,4-distyrylbenzene derivatives were synthesized and characterized by single-crystal X-ray diffraction to investigate the effects of substitution on the resulting...
  • publication

    Toxicant Identification by a Luminescent Bacterial Bioreporter Panel: Applica...

    Genetically engineered microorganisms, tailored to respond by a dose-dependent signal to the presence of toxic chemicals, are a potentially useful tool for environmental...
  • publication

    Quantifying Volatile Organic Compounds in Porous Media: Effects of Sampling M...

    Understanding how sampling methods can impact the accuracy of volatile organic compound (VOC) measurements in samples of soil and subsurface porous media is often critical to...
  • publication

    Rationalizing Lead Optimization by Associating Quantitative Relevance with Mo...

    Historically, one of the characteristic activities of the medicinal chemist has been the iterative improvement of lead compounds until a suitable therapeutic entity is achieved....
  • publication

    Chiral Crown Ether Pillared Lamellar Lanthanide Phosphonates

    A new chiral bridging ligand, 2,2‘-pentaethylene glycol-1,1‘-binaphthyl-6,6‘-bis(phosphonic acid), was synthesized in 40.7% overall yield in five steps and used to generate...
  • publication

    Adsorption of Monoaromatic Compounds and Pharmaceutical Antibiotics on Carbon...

    The relatively low surface area and micropore volume of carbon nanotubes limit their potential application as effective adsorbents for hydrophobic organic contaminants. In this...
  • publication

    Evaluation of Some Carotenoids in Grapes by Reversed- and Normal-Phase Liquid...

    Carotenoids in grapes of three Port winemaking cultivars were investigated. Extracts were obtained with n-hexane/diethyl ether mixtures (0/100; 20/80; 50/50; 100/0) and analyzed...
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    Supramolecular Rhombic Grids Formed from Bimolecular Building Blocks

    A programmed assembly process produces rhombic grid networks from compounds L1−L4 in the crystal by π−π stacking interactions that generate a bimolecular grid synthon, which...
  • publication

    Hydration-Assisted Sorption of a Probe Organic Compound at Different Peat Hyd...

    Sorption isotherms of phenol on Pahokee Peat as model natural organic matter (NOM) have been measured at different partial NOM hydrations (water activities). Sorption at a given...
  • publication

    Emission of Polycyclic Aromatic Hydrocarbons in China

    Emission of 16 polycyclic aromatic hydrocarbons (PAHs) listed as U.S. Environmental Protection Agency (U.S. EPA) priority pollutants from major sources in China were compiled....
  • publication

    Aromatic Molecules in Anion Recognition:  Electrostatics versus H-Bonding

    Mass-selected complexes A-·C6FnH6-n (A = Cl, I, SF6; n = 0−5) were studied by infrared photodissociation spectroscopy and computational chemistry methods to investigate the...
  • publication

    Engineering of Microcrystaline Solid-State Networks Using Cross-Linked γ-Zirc...

    The construction of organic−inorganic scaffolds based on γ-zirconium phosphate and polyethylenoxa diphosphonates is described. Microcrystalline materials with a controlled, low...