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r37980778c78--e17098d9bfd440ef43783be384687738
The ammonium-directed olefinic oxidation of a range of cyclic allylic and homoallylic amines has been investigated. Functionalization of a range of allylic... -
r37980778c78--833fc9e710336efda2e0ef40cc96bf68
The neopentylidene−neopentyl complex (PNP)TiCHtBu(CH2tBu) (2; PNP- = N[2-P(CHMe2)2-4-methylphenyl]2), prepared from the precursor (PNP)TiCHtBu(OTf) (1) and LiCH2tBu, extrudes... -
r37980778c78--1027c85e2469821348a40816b55daba2
Directly-Observed β-Hydrogen Elimination of a Late Transition Metal Amido Complex and Unusual Fate of Imine Byproducts -
Luminescence and Mesogenic Properties in Crown-Ether-Isocyanide or Carbene Go...
A crown ether isocyanide CNR (R = benzo-15-crown-5) has been synthesized by dehydration of the corresponding formamide. Substitution reactions with the appropriate gold(I)... -
A shorter spacing between the −35 and −10 reduces fitness.
A shorter spacing between the −35 and −10 reduces fitness. -
The Fitness Landscapes of <i>cis</i>-Acting Binding Sites in Different Promot...
The biophysical nature of the interaction between a transcription factor and its target sequences in vitro is sufficiently well understood to allow for the effects of DNA... -
Photoinduced Metal-to-Metal Charge Transfer toward Single-Chain Magnet
Photoinduced Metal-to-Metal Charge Transfer toward Single-Chain Magnet -
Inverse Aggregation Behavior of Alkali-Metal Triazenides
Higher aggregated alkali-metal compounds are usually obtained with increasing radius of the metal. Alkali-metal salts derived from the sterically crowded triazenido ligand... -
r37980778c78--ebc69acd6444a3b5fc91761f2d820dd8
The transient titanium alkylidyne complex (PNP)Ti⋮CtBu (PNP = N[2-P(CHMe2)2-4-methylphenyl]2-) can readily activate, in some cases regioselectively, the aromatic C−H bond of... -
r37980778c78--c2e058e9f2f01b1c25af7d03fb1f0979
The structure of {p-C6H4[CH2OCH2C(pz)3]2[Ru(p-cymene)]2}Cl4·14H2O (pz = pyrazolyl ring) contains a one-dimensional water chain associated into an inorganic (carbon-free) layer... -
Novel Bile Acid-Based Cyclic Bisimidazolium Receptors for Anion Recognition
Novel deoxycholic acid-based cyclic receptors, 3 and 4, containing two imidazolium groups and m-xylene and p-xylene as spacers have been synthesized. These receptors bind anions... -
r37980778c78--2f61df8bf3f2c60d93cd74266705fb7c
The ammonium-directed olefinic oxidation of a range of cyclic allylic and homoallylic amines has been investigated. Functionalization of a range of allylic... -
Fitness landscapes of individual −35 binding sites.
The relative fitness of an individual binding site (z-axis) in different tetracycline concentrations (x-axis) and promoter contexts (y-axis) is shown. The name of each binding... -
Photoinduced Magnetization in a Two-Dimensional Cobalt Octacyanotungstate
A new type of cyano-bridged Co−W bimetallic assembly, CsI[{CoII(3-cyanopyridine)2}{WV(CN)8}]·H2O was synthesized. This compound exhibited a temperature-induced phase transition... -
r37980778c78--e307e337007ed3d1bd6b425b1a087b0b
Photoinduced Metal-to-Metal Charge Transfer toward Single-Chain Magnet -
r37980778c78--bbd4945cba965c19bacbd13ad769325b
The ammonium-directed olefinic oxidation of a range of cyclic allylic and homoallylic amines has been investigated. Functionalization of a range of allylic... -
Spherical versus Linear Anion Encapsulation in the Cavity of a Protonated Aza...
Grams scale synthesis of an octaaminocryptand L2 with high yield is obtained in one-pot by low-temperature [2 + 3] condensation of tris(2-aminoethyl)amine with... -
r37980778c78--9bc688e08d34c969b8a08f30af6c6a02
The intermetallic phase GdCo1-xGa3Ge exhibits a charge density wave distortion in the square nets of Ga which was elucidated with superspace crystallography. The distortion... -
Structural and Photophysical Properties of Adducts of [Ru(bipy)(CN)<sub>4</su...
We show in this paper how the 3MLCT luminescence of [Ru(bipy)(CN)4]2-, which is known to be highly solvent-dependent, may be varied over a much wider range than can be achieved... -
Structural Transformations of Carbon Nanotubes under Hydrostatic Pressure
We used simulations with a classical force field to study the transformation under hydrostatic pressure of isolated single-walled nanotubes (SWNT) from a circular to a collapsed...
