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Evolving Carbapenemases: Can Medicinal Chemists Advance One Step Ahead of the...
Carbapenems can be an effective treatment of infections with multidrug-resistant Gram-negative bacteria such as Pseudomonas aeruginosa,1 Acinetobacter spp.,2 Klebsiella... -
Wind Lidar Digitalization
Wind lidar technology has been increasingly used for wind energy applications for over a decade. During this time there has been an impressive development of a lidar community... -
Metal-Mediated C−C Bond Making and Breaking: First Direct Evidence for a Rev...
Metal-Mediated C−C Bond Making and Breaking: First Direct Evidence for a Reversible Migration of a Benzyl Group along a Metal−Carbon Bond -
dedup_wf_001--4edd6b37544e4fc6acb3bb4fce0088b7
A major bottleneck for the exploitation of data from the Kepler mission for stellar astrophysics and exoplanet research has been the lack of precise radii and evolutionary... -
Polymorphic Packing Arrangements in a Class of Engineered Organic Crystals
Polymorphism occurs in the family of engineered cocrystals that form from N,N ‘-bis(p-X-phenyl)melamines (X = H, F, Cl, Br, I, CH3, and CF3) and barbital. X-ray powder... -
Thermal Degradation of Designed Carbohydrate <i>N</i>-Oxides: A Single Metho...
Thermal Degradation of Designed Carbohydrate N-Oxides: A Single Methodology for the Synthesis of Ketoses, Enol Ethers, and Branched-Chain Sugars from N-Oxides Derived from... -
Direct Thioepoxidation of Strained Cyclic Alkenes by the Photolytic Sulfur-At...
Direct Thioepoxidation of Strained Cyclic Alkenes by the Photolytic Sulfur-Atom Transfer from Thiocarbonyl S-Oxides (Sulfines) -
Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Tr...
Reduction of Zr/Co heterobimetallic complexes ICo(MesNPiPr2)3ZrCl (1) and ICo(iPrNPiPr2)3ZrCl (2) with excess Na/Hg under N2, followed by subsequent benzene extraction to remove... -
Emission Energy Correlates with Inverse of Gold−Gold Distance for Various [Au...
A series of bis(thiocyanato)gold(I) complexes with Au−Au interactions show luminescence in the range from 500 to 670 nm. The series of salts correlates emission energy with the... -
Ferromagnetic CoPt<sub>3</sub> Nanowires: Structural Evolution from fcc to Or...
This investigation demonstrates the magnetic properties and nanostructures of CoPt3 wire arrays that were fabricated by electrodeposition using a porous alumina template. The... -
r37980778c78--45c77806280e278526960e808d2b7b2b
Electrolysis of benzylthiocyanate, benzyl chloride, p-methylbenzyl chloride, p-methoxybenzyl chloride, or toluene in acetonitrile, at platinum electrodes in a two compartments... -
Dendrimer-Supported Oligothiophene Synthesis: Aliphatic Ether Dendrimers in ...
The first dendrimer-supported synthesis of oligothiophenes is reported. The dendrimer serves both as a solubilizing group and a “handle” to facilitate the iterative synthesis of... -
r37980778c78--fb2c9e56a071472b52b76dc212338718
The convergent total synthesis of brevetoxin B (1) has been achieved. The intramolecular allylation of the O,S-acetal 20, prepared from the α-chlorosulfide 17 and the alcohol 5,... -
r37980778c78--dcb21a10902c977732fbd5020f392453
Hydrogen peroxide oxidation of benzylidene acetals (and derivative benzyl ethers) that incorporate a siletane ring at the para position creates a deprotection pathway without... -
Reactivity of Aluminum Cluster Anions with Water: Origins of Reactivity and M...
The reactivity of aluminum anion clusters with water was found to exhibit variations with size, with some clusters exhibiting negligible reactivity, others absorbing one or more... -
Asymmetric Synthesis of New β,β-Difluorinated Cyclic Quaternary α-Amino Acid ...
The synthesis of new β,β-difluorinated cyclic quaternary α-amino acid derivatives 1 in which a ring-closing metathesis reaction (RCM) constitutes the key step is described. The... -
Efficient Charge Transport through a Metal Oxide Semiconductor in the Nanocom...
A nanocomposite film of tungsten trioxide (WO3) and [Ru(bpy)3]2+ (bpy = 2,2‘-bipyridine) (denoted as Ru−WO3) was prepared from an aqueous colloidal triad solution containing... -
r37980778c78--57dcb94f95d0bd5f5f7aea768ba2fb62
The well-defined head-to-tail oligothiophenes were synthesized via palladium-catalyzed CH arylation and halogen exchange sequentially through the 2-halothiophene derivatives. -
r37980778c78--b52a181e4486bbe4a71d31baba723d5c
A series of highly congested polyphenylbiphenyls and polyarylfluorenes has been prepared and their X-ray structures determined. Decaphenylbiphenyl adopts a very unusual... -
Total Synthesis of the Ristocetin Aglycon
The first total synthesis of the ristocetin aglycon is described employing a modular and highly convergent strategy. An effective 12-step (12% overall) synthesis of the ABCD...
