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Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene...
This contribution describes the implementation of the binuclear organotitanium “constrained geometry catalysts” (CGCs),... -
Homoatomic Stella Quadrangula [Tl<sub>8</sub>]<sup>6−</sup> in Cs<sub>18</sub...
Cs18Tl8O6 was synthesized reacting the binary compounds CsTl and Cs2O. According to single crystal X-ray analysis, the title compound crystallizes as a novel structure type in... -
Thermal Conductivities of Alternatives to CFC-11 for Foam Insulation
The present work examines the thermal conductivities of several dilute vapors which are potential alternatives to chlorofluorocarbons (CFCs) for cellular-plastic foams. Thermal... -
r37980778c78--bd0bde9a0115982ec94b687d90366bb5
The unusual luminescence behavior of the two-coordinate gold(I) carbene complex, Au{C(NHMe)2}2·0.5(acetone), is reported. Upon freezing in a liquid N2 bath, the colorless,... -
Applications of Bis(1-R-imidazol-2-yl)disulfides and Diselenides as Ligands f...
Bis(1-R-imidazol-2-yl)disulfides, (mimR)2 (R = Ph, But), and diselenides, (seimMes)2, serve as bidentate N,N-donor ligands for main-group and transition metals. For example,... -
Competing Patterns of Weak Directional Forces in Pressure-Frozen CH<sub>2</su...
Isostructural relations and phase transitions of dihalomethanes have been rationalized by the competing patterns of CH···halogen hydrogen bonds and halogen···halogen... -
1,8-Bis(diphenylmethylium)naphthalenediyl Dication as an Organic Oxidant: Sy...
1,8-Bis(diphenylmethylium)naphthalenediyl dications promoted oxidative coupling of various N,N-dialkylanilines to afford the corresponding para-coupled bisanilines, benzidines,... -
The Use of Imidazolium-2-dithiocarboxylates in the Formation of Gold(I) Compl...
The imidazolium-2-dithiocarboxylate ligands IPr·CS2, IMes·CS2, and IDip·CS2 react with [AuCl(PPh3)] to yield [(Ph3P)Au(S2C·IPr)]+, [(Ph3P)Au(S2C·IMes)]+, and... -
Synthesis, Structure, and Isomerization of Decapentynylcorannulene: Enediyne...
Decapentynylcorannulene (5) is prepared via aryl−alkyne coupling chemistry of decachlorocorannulene and trimethylstannylpentyne. The crystal structure of 5 is compared with the... -
Guest Inclusion and Structural Dynamics in 2-D Hydrogen-Bonded Metal−Organic ...
Guest Inclusion and Structural Dynamics in 2-D Hydrogen-Bonded Metal−Organic Frameworks -
Charge-Transfer Salts via Cocrystallization of the Cationic Ferrocenyl Donor ...
Four new charge-transfer (CT) salts based on the cationic ferrocenylmethylpyridinium (fmp) donor (CpFeCp-CH2-Py+) and polyoxometalate (POM) acceptors, Lindqvist-type [M6O19]2−... -
Mn(II)-Induced Formation and Structural Elucidation of a [3 + 3] Benzene Dime...
Mn(II)-Induced Formation and Structural Elucidation of a [3 + 3] Benzene Dimer Derivative from m-Phenylenebis(N-tert-butylaminoxyl) -
Room Temperature Light Emission from the Low-Dimensional Semiconductors AZrPS...
Room Temperature Light Emission from the Low-Dimensional Semiconductors AZrPS6 (A = K, Rb, Cs) -
r37980778c78--cb93bf378e256de6af0e26fd4b2fa9a0
Recent studies have demonstrated that the r-tctct isomer of ethylpyrogall[6]arene (6EPGR) can be readily isolated as a minor product of the synthesis of the corresponding... -
Magnetism of Conjugated Organic Nitroxides: Structural Scaffolding and Excha...
Magnetism of Conjugated Organic Nitroxides: Structural Scaffolding and Exchange Pathways -
Design of a New Family of Inorganic Compounds Ae<sub>2</sub>F<sub>2</sub>SnX<...
We could predict the structure of a new family of compounds Ae2F2SnX3 (Ae = Sr, Ba; X = S, Se) from the stacking of known 2D building blocks of the rock salt and fluorite types.... -
Ortho-Substituted Catechol Derivatives: The Effect of Intramolecular Hydroge...
This paper reports a series of chloride anion receptors containing two catechol head groups connected through their ortho-positions via a spacer chain. The linking group chosen... -
r37980778c78--f98d876a48cd55e200228959b6eb0e73
Bis(1-R-imidazol-2-yl)disulfides, (mimR)2 (R = Ph, But), and diselenides, (seimMes)2, serve as bidentate N,N-donor ligands for main-group and transition metals. For example,... -
Hydrocarbon Activation via Reversible 1,2-RH-Elimination from (<sup>t</sup>Bu...
Hydrocarbyl complexes, (tBu3SiNH)3ZrR (1-R), were prepared via metatheses of (tBu3SiNH)3ZrCl (1-Cl) with RMgX or RLi (R = Me, Et, Cy, CH2Ph, allyl, CHCH2, Ph, CH2tBu, C⋮CPh,... -
BaHg<sub>2</sub>Tl<sub>2</sub>. An Unusual Polar Intermetallic Phase with Str...
High yields of the novel BaHg2Tl2 are achieved from reactions of the appropriate cast alloys at ∼400 °C. (Isotypic SrHg2Tl2 also exists.) The tetragonal barium structure...
