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Electronic Tuning of Mg<sub>2</sub>Cu<sub>6</sub>Ga<sub>5</sub>. A Route to C...
Studies of Mg2Cu6Ga5 reveal that this compound contains incomplete Bergman clusters in its structure and shows a pseudogap and empty bonding states just above the Fermi energy... -
r37980778c78--857e3e72d75b6cd28e0058c646588f22
Three lanthanide-thiophenedicarboxylate hybrid compounds, [(Eu2(TDC)3(CH3OH)2·(CH3OH)] (1), [(Yb2(TDC)3(DMF)(H2O)·(CH3CH2OH)] (2), and [(Tb2(TDC)3(H2O)4] (3) (where TDC is... -
The Use of Imidazolium-2-dithiocarboxylates in the Formation of Gold(I) Compl...
The imidazolium-2-dithiocarboxylate ligands IPr·CS2, IMes·CS2, and IDip·CS2 react with [AuCl(PPh3)] to yield [(Ph3P)Au(S2C·IPr)]+, [(Ph3P)Au(S2C·IMes)]+, and... -
r37980778c78--c7ce3793de8830f55f7f32851009bf95
Reaction of the Au(I) N-heterocyclic carbene (NHC) compound [Au(im(CH2py)2)2]PF6 with 2 equiv of [Cu(MeCN)4]PF6 affords the tricationic compound Au(im(CH2py)2)2(Cu(MeCN)2)23... -
Synthesis, Structure, and Isomerization of Decapentynylcorannulene: Enediyne...
Decapentynylcorannulene (5) is prepared via aryl−alkyne coupling chemistry of decachlorocorannulene and trimethylstannylpentyne. The crystal structure of 5 is compared with the... -
Charge-Transfer Salts via Cocrystallization of the Cationic Ferrocenyl Donor ...
Four new charge-transfer (CT) salts based on the cationic ferrocenylmethylpyridinium (fmp) donor (CpFeCp-CH2-Py+) and polyoxometalate (POM) acceptors, Lindqvist-type [M6O19]2−... -
A Series of New Manganese(II) Sulfonate-Arsonates with 2D Layer, 1D Chain, an...
Hydrothermal reactions of manganese(II) salts with o-sulfophenylarsonic acid (o-HO3S−C6H4−AsO3H2, H3L) afforded Mn3(L)2(H2O)3·H2O (1) with a layered structure. When... -
r37980778c78--cb93bf378e256de6af0e26fd4b2fa9a0
Recent studies have demonstrated that the r-tctct isomer of ethylpyrogall[6]arene (6EPGR) can be readily isolated as a minor product of the synthesis of the corresponding... -
Design of a New Family of Inorganic Compounds Ae<sub>2</sub>F<sub>2</sub>SnX<...
We could predict the structure of a new family of compounds Ae2F2SnX3 (Ae = Sr, Ba; X = S, Se) from the stacking of known 2D building blocks of the rock salt and fluorite types.... -
Ternary Lanthanoid Ruthenium Gallides with a High Gallium Content: Ln<sub>2<...
The title compounds were prepared by reaction of the elemental components at high temperatures. The compounds Yb2Ru3Ga10 and Lu2Ru3Ga10 crystallize with a new structure type,... -
Hydrocarbon Activation via Reversible 1,2-RH-Elimination from (<sup>t</sup>Bu...
Hydrocarbyl complexes, (tBu3SiNH)3ZrR (1-R), were prepared via metatheses of (tBu3SiNH)3ZrCl (1-Cl) with RMgX or RLi (R = Me, Et, Cy, CH2Ph, allyl, CHCH2, Ph, CH2tBu, C⋮CPh,... -
Aggregation Dependent S1 and S2 Dual Emissions of Thiophene−Acrylonitrile−Car...
Dual emissions from S1 (blue region) and S2 (UV region) states of a chromophore with donor−acceptor structure were observed at room temperature. The photophysical properties of... -
Luminescent and Magnetic Properties of Lanthanide-Thiophene-2,5-dicarboxylate...
Three lanthanide-thiophenedicarboxylate hybrid compounds, [(Eu2(TDC)3(CH3OH)2·(CH3OH)] (1), [(Yb2(TDC)3(DMF)(H2O)·(CH3CH2OH)] (2), and [(Tb2(TDC)3(H2O)4] (3) (where TDC is... -
Design of a New Family of Inorganic Compounds Ae<sub>2</sub>F<sub>2</sub>SnX<...
We could predict the structure of a new family of compounds Ae2F2SnX3 (Ae = Sr, Ba; X = S, Se) from the stacking of known 2D building blocks of the rock salt and fluorite types.... -
Modulation of the Ring Size and Nuclearity of Metallamacrocycles via the Ster...
Hexanuclear, octanuclear, and decanuclear manganese metalladiazamacrocycles have been prepared by reacting a series of pentadentate ligands, N-acylsalicylhydrazides... -
r37980778c78--9618cc8528b077bac7ffa08e55628b32
Four new charge-transfer (CT) salts based on the cationic ferrocenylmethylpyridinium (fmp) donor (CpFeCp-CH2-Py+) and polyoxometalate (POM) acceptors, Lindqvist-type [M6O19]2−... -
r37980778c78--47497c71a06f5eb154bea9bfdd58ebbe
Reaction of the Au(I) N-heterocyclic carbene (NHC) compound [Au(im(CH2py)2)2]PF6 with 2 equiv of [Cu(MeCN)4]PF6 affords the tricationic compound Au(im(CH2py)2)2(Cu(MeCN)2)23... -
r37980778c78--e3cea60ce9696f3d21a96238ef855049
Four new charge-transfer (CT) salts based on the cationic ferrocenylmethylpyridinium (fmp) donor (CpFeCp-CH2-Py+) and polyoxometalate (POM) acceptors, Lindqvist-type [M6O19]2−... -
Novel Bis(ethylenedithio)tetrathiafulvalene-Based Organic Conductor with 1,1‘...
A new bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF)-based salt with a ferrocenyl moiety, α‘ ‘‘-(BEDT-TTF)4(Fe(C5H4SO3)2)·6H2O, has been prepared. The ferrocenyl part of this... -
Guest-Induced Assembly of Tetracarboxyl-Cavitand and Tetra(3-pyridyl)-Cavitan...
The guest- or solvent-induced assembly of a tetracarboxyl-cavitand 1 and a tetra(3-pyridyl)-cavitand 2 into a heterodimeric capsule 1·2 in a rim-to-rim fashion via four...
