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Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene...
This contribution describes the implementation of the binuclear organotitanium “constrained geometry catalysts” (CGCs),... -
Highly Activated Vinyl Hydrogen in a Significantly Twisted Styrene
The novel example of a vinylic hydrogen more reactive than a benzylic hydrogen was found by treatment of a twisted styrene derivative with a strong base followed by D2O... -
Thermal Conductivities of Alternatives to CFC-11 for Foam Insulation
The present work examines the thermal conductivities of several dilute vapors which are potential alternatives to chlorofluorocarbons (CFCs) for cellular-plastic foams. Thermal... -
r37980778c78--bd0bde9a0115982ec94b687d90366bb5
The unusual luminescence behavior of the two-coordinate gold(I) carbene complex, Au{C(NHMe)2}2·0.5(acetone), is reported. Upon freezing in a liquid N2 bath, the colorless,... -
Competing Patterns of Weak Directional Forces in Pressure-Frozen CH<sub>2</su...
Isostructural relations and phase transitions of dihalomethanes have been rationalized by the competing patterns of CH···halogen hydrogen bonds and halogen···halogen... -
1,8-Bis(diphenylmethylium)naphthalenediyl Dication as an Organic Oxidant: Sy...
1,8-Bis(diphenylmethylium)naphthalenediyl dications promoted oxidative coupling of various N,N-dialkylanilines to afford the corresponding para-coupled bisanilines, benzidines,... -
Ortho-Substituted Catechol Derivatives: The Effect of Intramolecular Hydroge...
This paper reports a series of chloride anion receptors containing two catechol head groups connected through their ortho-positions via a spacer chain. The linking group chosen... -
Synthesis, Characterization, and Spectroscopy of 4,7,12,15-[2.2]Paracyclophan...
This paper reports the synthesis of 4,7,12,15-tetra(4‘-dihexylaminostyryl)[2.2]paracyclophane (1), 4-(4‘-dihexylaminostyryl)-7,12,15-tri(4‘ ‘-nitrostyryl)[2.2]paracyclophane... -
r37980778c78--cb2f7e7bdd004676b2e120d51c4d86cc
Cs+-Selective Ion Exchange and Magnetic Ordering in a Three-Dimensional Framework Uranyl Vanadium(IV) Phosphate -
r37980778c78--1638705836aac7fe8e091197730072c2
In this report, an open-framework aluminophosphite (denoted as NKX-6) with large cavities and channel structure has been synthesized hydrothermally. Two crystals of NKX-6 with... -
Frustration of Magnetic and Ferroelectric Long-Range Order in Bi<sub>2</sub>M...
The slight incommensurate modulation of the structure of Bi2Mn4/3Ni2/3O6 is sufficient to suppress the electrical polarization which arises in commensurate treatments of the... -
Inverse Aggregation Behavior of Alkali-Metal Triazenides
Higher aggregated alkali-metal compounds are usually obtained with increasing radius of the metal. Alkali-metal salts derived from the sterically crowded triazenido ligand... -
Wind Lidar Digitalization
Wind lidar technology has been increasingly used for wind energy applications for over a decade. During this time there has been an impressive development of a lidar community... -
dedup_wf_001--4edd6b37544e4fc6acb3bb4fce0088b7
A major bottleneck for the exploitation of data from the Kepler mission for stellar astrophysics and exoplanet research has been the lack of precise radii and evolutionary... -
Polymorphic Packing Arrangements in a Class of Engineered Organic Crystals
Polymorphism occurs in the family of engineered cocrystals that form from N,N ‘-bis(p-X-phenyl)melamines (X = H, F, Cl, Br, I, CH3, and CF3) and barbital. X-ray powder... -
r37980778c78--45c77806280e278526960e808d2b7b2b
Electrolysis of benzylthiocyanate, benzyl chloride, p-methylbenzyl chloride, p-methoxybenzyl chloride, or toluene in acetonitrile, at platinum electrodes in a two compartments... -
Efficient Preparation of Chiral <i>C</i><sub>2</sub>-Symmetrical 2,6,9-Trioxa...
Efficient Preparation of Chiral C2-Symmetrical 2,6,9-Trioxabicyclo[3.3.1]nonanes from Cholesteryl Benzoate -
Solid-Phase Synthesis of Bis-2-imidazolidinethiones from Resin-Bound Tripeptides
The exhaustive reduction of resin-bound tripeptides with borane afforded three secondary amines and one primary amine. The treatment of the solid-support polyamines with... -
Ethylene polymerization with dimeric zirconium and hafnium silsesquioxane com...
Treatment of the silanol (c-C5H9)7Si8O12(OH) with Cp‘‘Ti(CH2Ph)3 (Cp‘‘ = 1,3-C5H3(SiMe3)2) or TiCl4 selectively affords the mono(silsesquioxane) complexes... -
Diethyl Chlorophosphite: A Versatile Reagent
Diethyl chlorophosphite (DECP) was previously described as a reducing agent for nitro compounds to the corresponding amines (Fischer, B.; Sheihet, L. J. Org. Chem. 1998, 63,...
