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Magnetic Fluorescent Delivery Vehicle Using Uniform Mesoporous Silica Spheres...
We synthesized uniform pore-sized mesoporous silica spheres embedded with magnetite nanocrystal and quantum dots. The magnetic separation, luminescent detection, and controlled... -
Alumina Nanotubes Containing Lithium of High Ion Mobility
We revealed the first example of a crystalline lithium aluminate nanotube with thermal stability prepared by a surfactant-driven hydrothermal procedure. The obtained nanotube... -
Construction of Novel Polycyclic Ring Systems by Transition-Metal-Catalyzed C...
Construction of Novel Polycyclic Ring Systems by Transition-Metal-Catalyzed Cycloisomerization of Ene−Ene−Ynes. Interception of a Carbenoid Intermediate in Skeletal... -
Highly selective cobalt-catalyzed hydrovinylation of styrene
: The hydrovinylation reaction is a codimerization of a 1,3-diene or vinyl arene and ethene with great potential for fine chemicals and pharmaceuticals. For the first time,... -
Multiplexed Sandwich Immunoassays using Electrochemiluminescence Imaging Reso...
A new class of bead-based microarray that uses electrogenerated chemiluminescence (ECL) as a readout mechanism to detect multiple antigens simultaneously is presented. This... -
Pressure-Induced Amorphization and Porosity Modification in a Metal−Organic F...
The impact of modest, industrially accessible pressures (0−1.2 GPa) on the structure and porosity of the zeolitic imidazolate framework Zn(2-methylimidazole)2, ZIF-8, was... -
Pressure-Induced Infiltration of Aqueous Solutions of Multiple Promoters in a...
By applying an external pressure, an aqueous solution of promoters can be forced into a hydrophobic nanoporous silica gel. The promoter molecule demands a free volume several... -
Domino Coupling Relay Approach to Polycyclic Pyrrole-2-carboxylates
CuBr2-catalyzed three-component coupling of N-benzylallylamine, ethyl glyoxalate, and terminal alkynes afforded glycine-tethered 1,6-enynes, which were further transformed into... -
Local Current Mapping and Patterning of Reduced Graphene Oxide
Conductive atomic force microscopy (C-AFM) has been used to correlate the detailed structural and electrical characteristics of graphene derived from graphene oxide. Uniform... -
Conduction Band Energy Level Control of Titanium Dioxide: Toward an Efficient...
Through the use of a strategy that involves narrowing the TiO2 band gap by shifting its conduction band positively and utilizing the catalytic activity of photoproduced Cu(I)... -
How to Design Linear Allenic-Type Trisilaallenes and Trigermaallenes
A theoretical prescription as to how to design allenic-type linear trisilaallenes and trigermaallenes is provided. Until now, all of the heavier group − 14 analogues of allene... -
Au@ZIF-8: CO Oxidation over Gold Nanoparticles Deposited to Metal−Organic Fra...
Gold nanoparticles (NPs) were deposited to a zeolite-type metal−organic framework (MOF) by a simple solid grinding method. A catalyst, Au@ZIF-8, represents the first example of... -
Iridium Luminophore Complexes for Unimolecular Oxygen Sensors
In this study, a series of novel luminescent cyclometalated Ir(III) complexes has been synthesized and evaluated for use in unimolecular oxygen-sensing materials. The complexes... -
Oxidative DNA Cleavage by the Antitumor Antibiotic Leinamycin and Simple 1,2-...
Oxidative DNA Cleavage by the Antitumor Antibiotic Leinamycin and Simple 1,2-Dithiolan-3-one 1-Oxides: Evidence for Thiol-Dependent Conversion of Molecular Oxygen to... -
Correlated Layer Structures: A Novel Type of Liquid Crystalline Phase with 2...
A novel liquid crystalline quaternary five-block molecule is reported which is composed of four incompatible molecular parts, a rigid biphenyl core, two polar... -
Spectroscopy and Electrochemistry of Ruthenium-Modified Nucleic Acids: Design...
Electron transfer (ET) reactions through DNA have been the subject of numerous investigations due to the implications for light-induced DNA damage and the quest for... -
Chiral Arylaminophosphonium Barfates as a New Class of Charged Brønsted Acid ...
Heterochiral [7.7]-P-spirocyclic arylaminophosphonium barfates have been designed as a novel charged, cationic Bronsted acid catalyst, and their catalytic and stereocontrolling... -
Thermally Cross-Linked Superparamagnetic Iron Oxide Nanoparticles: Synthesis ...
We report the fabrication and characterization of thermally cross-linked superparamagnetic iron oxide nanoparticles (TCL-SPION) and their application to the dual imaging of... -
Separation of Styrene and Ethylbenzene on Metal−Organic Frameworks: Analogous...
The metal−organic frameworks MIL-47 (VIVO{O2C-C6H4-CO2}) and MIL-53(Al) (AlIII(OH)·{O2C-C6H4-CO2}) are capable of separating ethylbenzene and styrene. Both materials adsorb up... -
Palladium-Catalyzed Aromatic C−H Halogenation with Hydrogen Halides by Means ...
A new strategy for catalytic functionalization of C−H bonds by means of electrochemical oxidation is described. Combination of palladium-catalyzed aromatic C−H bond cleavage and...
