234 items found

Tags: Chemical Sciences not elsewhere classified Evolutionary Biology Marine Biology

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  • dataset

    Normal mucus transport is restored in ciliated airway cultures derived from p...

    Normal mucus transport is restored in ciliated airway cultures derived from patients with cystic fibrosis after replacement of the CFTR gene. This image represents yellow...
  • dataset

    Thermal Conductivities of Alternatives to CFC-11 for Foam Insulation

    The present work examines the thermal conductivities of several dilute vapors which are potential alternatives to chlorofluorocarbons (CFCs) for cellular-plastic foams. Thermal...
  • dataset

    1,8-Bis(diphenylmethylium)naphthalenediyl Dication as an Organic Oxidant:  Sy...

    1,8-Bis(diphenylmethylium)naphthalenediyl dications promoted oxidative coupling of various N,N-dialkylanilines to afford the corresponding para-coupled bisanilines, benzidines,...
  • dataset

    Structural Transformations of Carbon Nanotubes under Hydrostatic Pressure

    We used simulations with a classical force field to study the transformation under hydrostatic pressure of isolated single-walled nanotubes (SWNT) from a circular to a collapsed...
  • dataset

    An Intramolecular <i>aza</i>-[3 + 3] Annulation Approach to Azaphenalene Alka...

    A detailed account on the stereoselective total syntheses of azaphenalene alkaloids via an intramolecular aza-[3 + 3] annulation strategy is described here. All five members of...
  • dataset

    Primers used in this study.

    a Liu et al., 2011 [19]. b Ji et al., 2007 [20]. c Wei et al., 2010 [21]. d Noteborn et al., 2013 [22]. *Positions correspond to: IBDV (JQ684022), IBV (KJ425500), AEV...
  • dataset

    Chiral Brønsted Acid-Catalyzed Inverse Electron-Demand Aza Diels−Alder Reaction

    Inverse electron-demand aza Diels−Alder reaction of aldimine with enol ethers proceeded under the influence of a phosphoric acid diester, derived from (R)-BINOL, to give...
  • dataset

    Palladium-Assisted Regioselective Olefin Insertion into and β-Hydrogen Elimin...

    Smooth reversible olefin insertion of ethyl acrylate, acrylonitrile, ethylene, dimethyl fumarate, and dimethyl maleate into MHCp(CO)3 (M = Mo (1a), W (1b)) has been catalyzed by...
  • dataset

    r37980778c78--e63bc64b93e734e9841b9fd1551f176b

    An Icosahedral Array of Methyl Groups Supported by an Aromatic Borane Scaffold:  The [closo-B12(CH3)12]2- Ion
  • dataset

    r37980778c78--db8cc79aad22b6e3a089d1605f4e3e69

    Simple, acyclic 3-aza-3-ene-1,5-diynes undergo an aza-Bergman rearrangement to a fleeting 2,5-didehydropyridine (2,5-ddp) intermediate that rapidly ring-opens to...
  • dataset

    Chiral Crown Ether Pillared Lamellar Lanthanide Phosphonates

    A new chiral bridging ligand, 2,2‘-pentaethylene glycol-1,1‘-binaphthyl-6,6‘-bis(phosphonic acid), was synthesized in 40.7% overall yield in five steps and used to generate...
  • dataset

    Structural Effects Affecting the Thermal Electrocyclic Ring Closure of Vinyla...

    The thermal electrocyclic ring closure of (2E,7E)-3,4,7-trialkylnona-2,4,5,7-tetraenes (divinyl-4,5-allenes) is regioselective, occurring at the most sterically congested...
  • dataset

    Luminescence and Mesogenic Properties in Crown-Ether-Isocyanide or Carbene Go...

    A crown ether isocyanide CNR (R = benzo-15-crown-5) has been synthesized by dehydration of the corresponding formamide. Substitution reactions with the appropriate gold(I)...
  • dataset

    Diastereoselective Oxidative Carbon−Carbon Bond Formation via Silyl Bis-enol ...

    Diisopropylsilyl bis-enol ethers are shown to be powerful intermediates for the diastereoselective dimerization and cross-coupling of cyclic ketones. The trends observed for the...
  • dataset

    Photoinduced Magnetization in a Two-Dimensional Cobalt Octacyanotungstate

    A new type of cyano-bridged Co−W bimetallic assembly, CsI[{CoII(3-cyanopyridine)2}{WV(CN)8}]·H2O was synthesized. This compound exhibited a temperature-induced phase transition...
  • dataset

    A Viable Anionic N-Heterocyclic Dicarbene

    The first anionic N-heterocyclic dicarbene, polymeric [:C{[N(2,6-Pri2C6H3)]2CHCLi(THF)}]n 1, containing both normal (C2) and abnormal carbene (C4) centers in the same...
  • dataset

    Structural Transformations of Carbon Nanotubes under Hydrostatic Pressure

    We used simulations with a classical force field to study the transformation under hydrostatic pressure of isolated single-walled nanotubes (SWNT) from a circular to a collapsed...
  • dataset

    r37980778c78--a98034846ef1492e50f2d6683499c9e7

    Diisopropylsilyl bis-enol ethers are shown to be powerful intermediates for the diastereoselective dimerization and cross-coupling of cyclic ketones. The trends observed for the...
  • publication

    dedup_wf_001--4edd6b37544e4fc6acb3bb4fce0088b7

    A major bottleneck for the exploitation of data from the Kepler mission for stellar astrophysics and exoplanet research has been the lack of precise radii and evolutionary...
  • publication

    dedup_wf_001--064ad5f1987610e186aa55df575d4f33

    Die eindeutige Zuordnung von Autorinnen und Autoren zu den von ihnen geschaffenen Werken zählt zu den großen Herausforderungen des Publikationsmanagements in der Wissenschaft....