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Complete Mapping of the Stereochemical Course of Retentive Deprotonation/Alky...
Enantiopure amino-acid derived 1H-benzo[e][1,4]diazepin-2(3H)-ones (BZDs) undergo highly retentive deprotonation/alkylation reactions. To confirm the role of stereolabile,... -
Control of S-Based Aggregation: Designed Synthesis of NiM<sub>2</sub> and Ni...
Modification of the nickel dithiolate metalloligand, Ni(bme-daco) [where bme-daco = bis(mercaptoethyl)diazacyclooctane] or Ni-1, by oxygenation of one thiolate into a sulfinate,... -
The Crystallographic Structure of a Lewis Acid-Assisted Chiral Brønsted Acid ...
It is difficult to control the enantioselectivity in the protonation of silyl enol ethers with simple chiral Brønsted acids, mainly due to bond flexibility between the proton... -
Supermolecular Building Blocks (SBBs) and Crystal Design: 12-Connected Open ...
The cubohemioctahedral supermolecular building blocks, SBBs, of formula [M6(bdc)12]12- (M = Ni, Co) (as illustrated) have the requisite symmetry to be cross-linked by rigid... -
r37980778c78--6aa49dd0ac4cda71eae14d5dde9106fc
A new layered aluminophosphate, [C6N3H17][Al2(HPO4)(PO4)2] (denoted AlPO−CJ21), has been prepared in an alcoholic system by the use of N-(2-aminoethyl)-piperazine (AEPP) as the... -
A New Ni<sub>12</sub> Cluster Based on Polyoxometalate Ligands
A new Ni12 cluster based on polyoxometalate ligands [Ni12(OH)9WO4(W7O26(OH))(PW9O34)3]25− (1) has been assembled in aqueous solution containing [PW9O34]9−, WO42−, and... -
Carbon Dioxide Adsorption-Induced Deformation of Microporous Carbons
Applying the thermodynamic model of adsorption-induced deformation of microporous carbons developed recently (Kowalczyk, P.; Ciach, A.; Neimark, A. Langmuir 2008, 24, 6603), we... -
Solid State Photochemistry: Absolute Asymmetric Photocyclization of an Achir...
Solid State Photochemistry: Absolute Asymmetric Photocyclization of an Achiral S-Aryl o-Benzoylbenzothioate to an Optically Active Phthalide Involving a Novel Phenyl Migration -
Primers used in this study.
a Liu et al., 2011 [19]. b Ji et al., 2007 [20]. c Wei et al., 2010 [21]. d Noteborn et al., 2013 [22]. *Positions correspond to: IBDV (JQ684022), IBV (KJ425500), AEV... -
Design of a New Family of Inorganic Compounds Ae<sub>2</sub>F<sub>2</sub>SnX<...
We could predict the structure of a new family of compounds Ae2F2SnX3 (Ae = Sr, Ba; X = S, Se) from the stacking of known 2D building blocks of the rock salt and fluorite types.... -
Heteroatomic Deltahedral Clusters: Synthesis and Structures of <i>closo</i>-...
Reactions of ethylenediamine solutions of K4Bi5 with Ni(PPh3)2(CO)2 yielded four novel hetero-atomic Bi/Ni deltahedral clusters. Three of them, the 7-atom pentagonal bipyramidal... -
Carbon Nanotubes Loaded with Magnetic Particles
We describe a simple and versatile technique to produce magnetic tubes by filling carbon nanotubes (CNTs) with paramagnetic iron oxide particles (∼10 nm diameter). Commercial... -
Discovery of Novel Benzopyranyl Tetracycles that Act as Inhibitors of Osteocl...
A novel benzopyran-fused molecular framework 7ai was discovered as a specific inhibitor of RANKL-induced osteoclastogenesis using a cell-based TRAP activity assay from drug-like... -
r37980778c78--c09fa2fc96ac23a0f1f061ad853d367a
We report the preparation of the first benzannulated phenalenyl neutral radical conductor (18), and we show that the compound displays unprecedented solid state behavior: the... -
Wood Cellulose Preparation Methods and Mass Spectrometric Analyses of δ<sup>1...
Interlaboratory comparisons involving nine European stable isotope laboratories have shown that the routine methods of cellulose preparation resulted in data that generally... -
Oxygen Ordered Phases in La<sub><i>x</i></sub>Sr<sub>1−<i>x</i></sub>MnO<sub>...
In situ neutron powder diffraction experiments have been performed on samples of SrMnOy, La0.1Sr0.9MnOy, and La0.2Sr0.8MnOy (2.5 ≤ y ≤ 3) to determine the existence of... -
Physalins from <i>Witheringia</i> <i>s</i><i>olanacea</i> as Modulators of th...
Crude extracts of Witheringia solanacea leaves showed inhibition of NF-κB activation at 100 μg/mL induced by phorbol 12-myristate-13-acetate (PMA) in HeLa cells stably... -
r37980778c78--3fc42d2db392444485182f193cd2ac02
By use of lipase R (Amano, Penicillium roqueforti) immobilized on Hyflo Super Cell it is possible to convert at ambient temperature 5-hydroxy-5H-furan-2-one (5) to acetic acid... -
Design of a New Family of Inorganic Compounds Ae<sub>2</sub>F<sub>2</sub>SnX<...
We could predict the structure of a new family of compounds Ae2F2SnX3 (Ae = Sr, Ba; X = S, Se) from the stacking of known 2D building blocks of the rock salt and fluorite types....
