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Highly Emitting Near-Infrared Lanthanide "Encapsulated Sandwich" Metallacrown...
Near-infrared (NIR) luminescent lanthanide complexes hold great promise for practical applications, as their optical properties have several complementary advantages over... -
Generating Active "L-Pd(0)" via Neutral or Cationic π‑Allylpalladium Complexe...
Two new classes of highly active yet air- and moisture-stable π-R-allylpalladium complexes containing bulky biaryl- and bipyrazolylphosphines with extremely broad ligand scope... -
r37980778c78--bb1f4f032cdd2c2c3349da98fb9bd374
CpTiCl2(L) [L = C4H4N (1), 2,5-Me2C4H2N (2), 2,4-Me2C4H2N (3), 2,4-Me2-3-EtC4HN (4)], CpTiCl(2,4-Me2-3-EtC4HN)2 (5), and CpTi(C4H4N)3 (6) were prepared by treating CpTiCl3 with... -
Tridentate Benzimidazole-Pyridine-Tetrazolates as Sensitizers of Europium Lum...
We report on new anionic tridentate benzimidazole-pyridine-tetrazolate ligands that form neutral 3:1 complexes with trivalent lanthanides. The ligands are UV-absorbing... -
r37980778c78--d4f37e7d58fa593993eba62ad3404fb8
A series of 3d–4f binuclear complexes, [M(3-MeOsaltn)(MeOH)x(ac)Ln(hfac)2] (x = 0 for M = CuII, ZnII; x = 1 for M = CoII, NiII; Ln = GdIII, TbIII, DyIII, LaIII), have been... -
r37980778c78--3ca0fe93c39133907a0c28621cbe2d16
A series of highly volatile eight-coordinate air and moisture stable lanthanide complexes of the type [Ln(hfaa)3(L)2] (Ln = Pr (1), Nd (2), Eu (3), Gd (4), Tb (5), Dy (6), Ho... -
New Lanthanide Complexes for Sensitized Visible and Near-IR Light Emission: ...
We describe the syntheses, the 1H NMR studies in CD3OD and D2O as solvent, the X-ray characterization, and the luminescence properties in D2O solution of the two complexes Eu·1... -
Steering S−H and N−H Bond Activation by a Stable N-Heterocyclic Silylene: Dif...
The strikingly different behavior of the ylide-like, N-heterocyclic silylene LSi: (5: L = CH[(CCH2)CMe(NAr)2]; Ar = 2,6-iPrC6H3) versus its LSi→Ni(CO)3 complex 13 to activate... -
Luminescent Lanthanide Complexes with Stereocontrolled Tris(2-pyridylmethyl)a...
A series of tris(2-pyridylmethyl)amines including one and two asymmetric centers were synthesized in a stereo-controlled fashion as potential ligands of lanthanide cations. The... -
Syntheses, Structures, Near-Infrared and Visible Luminescence, and Magnetic P...
Reactions of tripodal ligand 1,3,5-tris(imidazole-1-ylmethyl)-2,4,6-trimethylbenzene (L) with lanthanide metal salts and triethyl orthoformate led to the formation of six... -
r37980778c78--739005c96424e598541437cab6ffda5f
Bis(diphenylphosphinomethyl)phenylphosphine (dpmp)-supported Pt2Au heterotrinuclear complexes [Pt2Au(dpmp)2(CCPh)4](ClO4) (1), [Pt2Au(dpmp)2(DEBf)(CCPh)2](ClO4) (2),... -
Control of C–H Bond Activation by Mo-Oxo Complexes: p<i>K</i><sub>a</sub> or ...
A density functional theory (DFT) study (BMK/6-31+G(d)) was initiated to investigate the activation of benzylic carbon–hydrogen bonds by a molybdenum-oxo complex with a... -
Enhancing Phosphorescence through Rigidifying the Conformation to Achieve Hig...
Bis(diphenylphosphinomethyl)phenylphosphine (dpmp)-supported Pt2Au heterotrinuclear complexes [Pt2Au(dpmp)2(CCPh)4](ClO4) (1), [Pt2Au(dpmp)2(DEBf)(CCPh)2](ClO4) (2),... -
Strongly Luminescent Palladium(0) and Platinum(0) Diphosphine Complexes
The synthesis, structure, and photoluminescence of palladium(0) and platinum(0) complexes containing biarydiphosphines, biphep (biphep =... -
Ga<sup>3+</sup>/Ln<sup>3+</sup> Metallacrowns: A Promising Family of Highly L...
Luminescent lanthanide(III)-based molecular scaffolds hold great promises for materials science and for biological applications. Their fascinating photophysical properties... -
r37980778c78--c7d62f122111ef0e7c0bcd6c4bac0bd8
The reactivities of different 3-imino-functionalized indoles with rare-earth-metal amides [(Me3Si)2N]3RE(μ-Cl)Li(THF)3 were studied to reveal unexpected substituent effects... -
Emission Tuning of Luminescent Copper(I) Complexes by Vapor-Induced Ligand Ex...
We have synthesized two luminescent mononuclear Cu(I) complexes, [Cu(PPh2Tol)(THF)(4Mepy)2](BF4) (1) and [Cu(PPh2Tol)(4Mepy)3](BF4) (2) (PPh2Tol =... -
Highly Intense Fluorescent Diarylboron Diketonate
Diarylboron diketonates were successfully prepared by the reaction of 1,3-diketone derivatives and arylboron compounds such as triphenylborane [BPh3] and... -
Luminescence and Mesogenic Properties in Crown-Ether-Isocyanide or Carbene Go...
A crown ether isocyanide CNR (R = benzo-15-crown-5) has been synthesized by dehydration of the corresponding formamide. Substitution reactions with the appropriate gold(I)... -
r37980778c78--fe56903a158c743992e0cb74e4d9fc72
A fascinating mechanistic study of ynamido−palladium−π-allyl complexes is described that features isolation of a unique silyl ketenimine via aza-Claisen rearrangement, which can...
