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Copper-Mediated Oxidative Coupling of Benzamides with Maleimides via Directed...
A Cu(OAc)2/Cy2NMe-mediated oxidative direct coupling of benzamides with maleimides has been developed. The aromatic C–H alkenylation with the aid of an 8-aminoquinoline-based... -
r37980778c78--b313220f916759f1f4acdbd0ac133c8f
The redox-neutral direct coupling of arylphosphine oxides with heterobicyclic alkenes proceeds smoothly under rhodium(III) catalysis involving hydroarylation followed by... -
A DFT Study on the Thermal Aryl Migration in Aryliodonium Ylides. Support for...
A DFT study on the intramolecular thermal phenyl migration in iodonium ylides supports a concerted mechanism. In contrast to the two, different than each other, suggested... -
Enantioselective Intramolecular Aromatic [4 + 4] Photocycloaddition in Crysta...
Photoreactivity of seven 9-anthryl-N-(naphthylcarbonyl)carboxamide derivatives, 1a−g, in their intramolecular [4 + 4] photocycloadditions in solid state is discussed on the... -
Ketone-Imide versus Ketone-Oxime Reductive Cross-Coupling Promoted by Samariu...
10 páginas, 5 figuiras, 5 esquemas, 2 tablas.-- Supporting Information Available: General experimental procedures, 1D (1H and 13C) and 2D NMR (DQ-COSY, NOESY, HSQC, and HMBC)... -
Revisiting the Ullmann−Ether Reaction: A Concise and Amenable Synthesis of N...
A concise synthesis of a series of novel dibenzoxepino[4,5-d]pyrazoles was accomplished by implementation of an intramolecular Ullmann-ether reaction on... -
Intramolecular and Intermolecular Kinetic Isotope Effects (KIE) in the Nitros...
The intramolecular and intermolecular kinetic isotope effects (KIE) have been determined for the nitrosoarene ene reaction with deuterium-stereolabeled 2,3-dimethyl-2-butenes... -
Intramolecular Anionic Diels—Alder Reactions of 1-Aryl-4-oxahepta-1,6-diyne S...
Base-promoted cycloaddition reactions of 1-aryl- or 1-aryl-7-substituted-4-oxahepta-1,6-diyne systems in DMSO have proven to involve an anionic intramolecular Diels−Alder... -
r37980778c78--d6b8a164df6686f513b0a8cc1015e173
The H-aggregates of a novel cyanine dye, 3,3′-di(3-sulfopropyl)-4,5,4′,5′-dibenzo-9-methyl-thiacarbocyanine triethylammonium salt (MTC), have been fabricated to verify...