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A Formal Total Synthesis of (+)-Zincophorin. Observation of an Unusual Urea-D...
A formal total synthesis of (+)-zincophorin via interception of Miyashita's advanced intermediates is described here. This effort features the first synthetic application of an... -
Investigation of Gas Adsorption Performances and H<sub>2</sub> Affinities of ...
Three isomorphous porous metal-organic frameworks (MOFs; PCN-9 (Co/Fe/Mn)) with entatic metal centers have been constructed on the basis of the trigonal planar H3TATB ligand and... -
Applications of Bis(1-R-imidazol-2-yl)disulfides and Diselenides as Ligands f...
Bis(1-R-imidazol-2-yl)disulfides, (mimR)2 (R = Ph, But), and diselenides, (seimMes)2, serve as bidentate N,N-donor ligands for main-group and transition metals. For example,... -
Supermolecular Building Blocks (SBBs) and Crystal Design: 12-Connected Open ...
The cubohemioctahedral supermolecular building blocks, SBBs, of formula [M6(bdc)12]12- (M = Ni, Co) (as illustrated) have the requisite symmetry to be cross-linked by rigid... -
Room Temperature Light Emission from the Low-Dimensional Semiconductors AZrPS...
Room Temperature Light Emission from the Low-Dimensional Semiconductors AZrPS6 (A = K, Rb, Cs) -
Primers used in this study.
a Liu et al., 2011 [19]. b Ji et al., 2007 [20]. c Wei et al., 2010 [21]. d Noteborn et al., 2013 [22]. *Positions correspond to: IBDV (JQ684022), IBV (KJ425500), AEV... -
r37980778c78--f98d876a48cd55e200228959b6eb0e73
Bis(1-R-imidazol-2-yl)disulfides, (mimR)2 (R = Ph, But), and diselenides, (seimMes)2, serve as bidentate N,N-donor ligands for main-group and transition metals. For example,... -
Hydrocarbon Activation via Reversible 1,2-RH-Elimination from (<sup>t</sup>Bu...
Hydrocarbyl complexes, (tBu3SiNH)3ZrR (1-R), were prepared via metatheses of (tBu3SiNH)3ZrCl (1-Cl) with RMgX or RLi (R = Me, Et, Cy, CH2Ph, allyl, CHCH2, Ph, CH2tBu, C⋮CPh,... -
r37980778c78--f66bbf3d096b9e2c206ac24281e864b4
We report the design and construction of tunable organic clay mimic structures with one-dimensional supramolecular synthons and aromatic tectons. By connecting the robust... -
r37980778c78--ee50f303f6bc049d824efa234557da57
Bis(1-R-imidazol-2-yl)disulfides, (mimR)2 (R = Ph, But), and diselenides, (seimMes)2, serve as bidentate N,N-donor ligands for main-group and transition metals. For example,... -
Hexa-<i>p</i><i>eri</i>-hexabenzocoronenes by Efficient Oxidative Cyclodehydr...
Oligophenylene precursors based on 1,3,5-tris-(2‘-biphenyl)ylbenzene (4a) and 1,4-bis-(2‘-biphenyl)yl-2,5-diphenylbenzene (5a) were prepared and utilized for efficient... -
r37980778c78--db8cc79aad22b6e3a089d1605f4e3e69
Simple, acyclic 3-aza-3-ene-1,5-diynes undergo an aza-Bergman rearrangement to a fleeting 2,5-didehydropyridine (2,5-ddp) intermediate that rapidly ring-opens to... -
Chiral Crown Ether Pillared Lamellar Lanthanide Phosphonates
A new chiral bridging ligand, 2,2‘-pentaethylene glycol-1,1‘-binaphthyl-6,6‘-bis(phosphonic acid), was synthesized in 40.7% overall yield in five steps and used to generate... -
Halogen Trimer-Mediated Hexagonal Host Framework of 2,4,6-Tris(4-halophenoxy)...
The hexagonal layer structure of host atoms in chloro, bromo, and iodo derivatives of 2,4,6-tris(4-halophenoxy)-1,3,5-triazine, X-POT, is stabilized by a cyclic and cooperative... -
Sterically Controlled Mono- or Dimetalation of a Thioether-Functionalized Pho...
The thioanisole-functionalized secondary phosphine {(Me3Si)2CH}PH(C6H4-2-SMe) (1) is readily accessible via the reaction of 2-LiC6H4SMe and {(Me3Si)2CH}PCl2, followed by... -
Multiplex Lateral-Flow Test Strips Fabricated by Two-Dimensional Shaping
We have fabricated paper- and nitrocellulose-based lateral-flow devices that are shaped in two dimensions by a computer-controlled knife. The resulting star, candelabra, and... -
Thermal Equilibrium between a Lattice-Framework Disilene and the Correspondin...
The existence of the thermal equilibrium between 2,3,4,6,7,8,2‘,3‘,4‘,6‘,7‘,8‘-dodeca-tert-butyl[5,5‘]bi{1,5-disilatricyclo[4.2.0.01,4]octylidene}-2,7,2‘,7‘-tetraene and the... -
A Formal Total Synthesis of (+)-Zincophorin. Observation of an Unusual Urea-D...
A formal total synthesis of (+)-zincophorin via interception of Miyashita's advanced intermediates is described here. This effort features the first synthetic application of an... -
r37980778c78--4e0383c107c53562d272d08f2edda7af
We have fabricated paper- and nitrocellulose-based lateral-flow devices that are shaped in two dimensions by a computer-controlled knife. The resulting star, candelabra, and... -
r37980778c78--2cec161f2b7f957dfe13dc16fcfa512f
The hexagonal layer structure of host atoms in chloro, bromo, and iodo derivatives of 2,4,6-tris(4-halophenoxy)-1,3,5-triazine, X-POT, is stabilized by a cyclic and cooperative...
