-
Deprotonation and Addition Reactions of Frustrated Lewis Pairs with Alkynes
Deprotonation of terminal alkynes is effected by the treatment with tBu3P and B(C6F5)3 to give [tBu3PH][PhCCB(C6F5)3] (1a) and [tBu3PH][RCCB(C6F5)3] (R = nBu 2, tBu 3, Me3Si 4,... -
Applications of Bis(1-R-imidazol-2-yl)disulfides and Diselenides as Ligands f...
Bis(1-R-imidazol-2-yl)disulfides, (mimR)2 (R = Ph, But), and diselenides, (seimMes)2, serve as bidentate N,N-donor ligands for main-group and transition metals. For example,... -
Synthesis, Structure, and Isomerization of Decapentynylcorannulene: Enediyne...
Decapentynylcorannulene (5) is prepared via aryl−alkyne coupling chemistry of decachlorocorannulene and trimethylstannylpentyne. The crystal structure of 5 is compared with the... -
Guest Inclusion and Structural Dynamics in 2-D Hydrogen-Bonded Metal−Organic ...
Guest Inclusion and Structural Dynamics in 2-D Hydrogen-Bonded Metal−Organic Frameworks -
Mn(II)-Induced Formation and Structural Elucidation of a [3 + 3] Benzene Dime...
Mn(II)-Induced Formation and Structural Elucidation of a [3 + 3] Benzene Dimer Derivative from m-Phenylenebis(N-tert-butylaminoxyl) -
r37980778c78--cb93bf378e256de6af0e26fd4b2fa9a0
Recent studies have demonstrated that the r-tctct isomer of ethylpyrogall[6]arene (6EPGR) can be readily isolated as a minor product of the synthesis of the corresponding... -
Magnetism of Conjugated Organic Nitroxides: Structural Scaffolding and Excha...
Magnetism of Conjugated Organic Nitroxides: Structural Scaffolding and Exchange Pathways -
r37980778c78--f98d876a48cd55e200228959b6eb0e73
Bis(1-R-imidazol-2-yl)disulfides, (mimR)2 (R = Ph, But), and diselenides, (seimMes)2, serve as bidentate N,N-donor ligands for main-group and transition metals. For example,... -
Hydrocarbon Activation via Reversible 1,2-RH-Elimination from (<sup>t</sup>Bu...
Hydrocarbyl complexes, (tBu3SiNH)3ZrR (1-R), were prepared via metatheses of (tBu3SiNH)3ZrCl (1-Cl) with RMgX or RLi (R = Me, Et, Cy, CH2Ph, allyl, CHCH2, Ph, CH2tBu, C⋮CPh,... -
Nanoporous Amino Acid Derived Material Formed via In-Situ Dimerization of Asp...
A new mixed-ligand three-dimensional metal−organic framework is reported, where one component, meso-iminodisuccinic acid, is formed in-situ by the dimerization of aspartic acid... -
r37980778c78--ee50f303f6bc049d824efa234557da57
Bis(1-R-imidazol-2-yl)disulfides, (mimR)2 (R = Ph, But), and diselenides, (seimMes)2, serve as bidentate N,N-donor ligands for main-group and transition metals. For example,... -
Cation-Triggered Drug Release from a Porous Zinc−Adeninate Metal−Organic Fram...
Cation-Triggered Drug Release from a Porous Zinc−Adeninate Metal−Organic Framework -
Structural Effects Affecting the Thermal Electrocyclic Ring Closure of Vinyla...
The thermal electrocyclic ring closure of (2E,7E)-3,4,7-trialkylnona-2,4,5,7-tetraenes (divinyl-4,5-allenes) is regioselective, occurring at the most sterically congested... -
r37980778c78--274a8756b10bae8a03e673b230a8ff19
Upon dehydration at 220 °C under vacuum, an open-framework zinc tetrahydrofuran-2,3,4,5-tetracarboxylate undergoes reversible single crystal to single crystal conversion by some... -
Synthesis and Characterization of Zirconogermanates
Six new zirconogermanates have been prepared under hydrothermal conditions using amines as bases. There are four new structure types (ASU-n) with a common motif of ZrGe5. ASU-23... -
Study of Sialon S-phases M<sub>2</sub>Al<i><sub>x</sub></i>Si<sub>12</sub><su...
The crystal structure of the sialon Ba S-phase Ba2AlxSi12-xN16-xO2+x was refined, for x ≈ 2, using Mo Kα single-crystal data in Imm2 with a = 8.230(1) Å, b = 9.655(2) Å, c =... -
Multiplex Lateral-Flow Test Strips Fabricated by Two-Dimensional Shaping
We have fabricated paper- and nitrocellulose-based lateral-flow devices that are shaped in two dimensions by a computer-controlled knife. The resulting star, candelabra, and... -
r37980778c78--3817f57513d87f4b8a6f00a53d461351
A crystallographic study and theoretical analysis of the Si/Ga site preferences in the Gd5GaxSi4−x series is presented. Gd5GaxSi4−x adopt the orthorhombic Gd5Si4-type structure... -
Thermal Equilibrium between a Lattice-Framework Disilene and the Correspondin...
The existence of the thermal equilibrium between 2,3,4,6,7,8,2‘,3‘,4‘,6‘,7‘,8‘-dodeca-tert-butyl[5,5‘]bi{1,5-disilatricyclo[4.2.0.01,4]octylidene}-2,7,2‘,7‘-tetraene and the... -
Highly Porous and Robust 4,8-Connected Metal−Organic Frameworks for Hydrogen ...
Highly Porous and Robust 4,8-Connected Metal−Organic Frameworks for Hydrogen Storage
