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Highly Emitting Near-Infrared Lanthanide "Encapsulated Sandwich" Metallacrown...
Near-infrared (NIR) luminescent lanthanide complexes hold great promise for practical applications, as their optical properties have several complementary advantages over... -
r37980778c78--bb1f4f032cdd2c2c3349da98fb9bd374
CpTiCl2(L) [L = C4H4N (1), 2,5-Me2C4H2N (2), 2,4-Me2C4H2N (3), 2,4-Me2-3-EtC4HN (4)], CpTiCl(2,4-Me2-3-EtC4HN)2 (5), and CpTi(C4H4N)3 (6) were prepared by treating CpTiCl3 with... -
Tridentate Benzimidazole-Pyridine-Tetrazolates as Sensitizers of Europium Lum...
We report on new anionic tridentate benzimidazole-pyridine-tetrazolate ligands that form neutral 3:1 complexes with trivalent lanthanides. The ligands are UV-absorbing... -
Luminescent Lanthanide Complexes with Stereocontrolled Tris(2-pyridylmethyl)a...
A series of tris(2-pyridylmethyl)amines including one and two asymmetric centers were synthesized in a stereo-controlled fashion as potential ligands of lanthanide cations. The... -
Syntheses, Structures, Near-Infrared and Visible Luminescence, and Magnetic P...
Reactions of tripodal ligand 1,3,5-tris(imidazole-1-ylmethyl)-2,4,6-trimethylbenzene (L) with lanthanide metal salts and triethyl orthoformate led to the formation of six... -
r37980778c78--739005c96424e598541437cab6ffda5f
Bis(diphenylphosphinomethyl)phenylphosphine (dpmp)-supported Pt2Au heterotrinuclear complexes [Pt2Au(dpmp)2(CCPh)4](ClO4) (1), [Pt2Au(dpmp)2(DEBf)(CCPh)2](ClO4) (2),... -
Enhancing Phosphorescence through Rigidifying the Conformation to Achieve Hig...
Bis(diphenylphosphinomethyl)phenylphosphine (dpmp)-supported Pt2Au heterotrinuclear complexes [Pt2Au(dpmp)2(CCPh)4](ClO4) (1), [Pt2Au(dpmp)2(DEBf)(CCPh)2](ClO4) (2),... -
Ga<sup>3+</sup>/Ln<sup>3+</sup> Metallacrowns: A Promising Family of Highly L...
Luminescent lanthanide(III)-based molecular scaffolds hold great promises for materials science and for biological applications. Their fascinating photophysical properties... -
Emission Tuning of Luminescent Copper(I) Complexes by Vapor-Induced Ligand Ex...
We have synthesized two luminescent mononuclear Cu(I) complexes, [Cu(PPh2Tol)(THF)(4Mepy)2](BF4) (1) and [Cu(PPh2Tol)(4Mepy)3](BF4) (2) (PPh2Tol =... -
Highly Intense Fluorescent Diarylboron Diketonate
Diarylboron diketonates were successfully prepared by the reaction of 1,3-diketone derivatives and arylboron compounds such as triphenylborane [BPh3] and... -
Data collection and refinement statistics.
1Statistics for data from the highest-resolution shell are shown in parentheses. 2 R sym =(ΣΣ|Ihkl−〈I〉|)/(ΣIhkl), where the average intensity <I> is taken... -
Prototypes of Lanthanide(III) Agents Responsive to Enzymatic Activities in Th...
We report first prototypes of responsive lanthanide(III) complexes that can be monitored independently in three complementary imaging modalities. Through the appropriate choice... -
Surprisingly Bright Near-Infrared Luminescence and Short Radiative Lifetimes ...
New heterobinuclear lanthanide complexes with benzoxazole-substituted 8-hydroxyquinolines, [Ln(ligand)2(μ-ligand)2Na] (Ln: Yb, Lu), have been prepared and their structure... -
r37980778c78--9936f0987496119bf67c0d361a5ca781
Optical recording and luminescence readout of novel covalently linked photochrome/luminophore supramolecular complexes has been demonstrated by near-field scanning optical... -
Luminescent Lanthanide Complexes with Stereocontrolled Tris(2-pyridylmethyl)a...
A series of tris(2-pyridylmethyl)amines including one and two asymmetric centers were synthesized in a stereo-controlled fashion as potential ligands of lanthanide cations. The... -
X-ray-Excited Optical Luminescence (XEOL) and X-ray Absorption Fine Structure...
Synchrotron techniques, X-ray-excited optical luminescence (XEOL) combined with X-ray absorption fine structures (XAFS), have been used to study the electronic structure and... -
Mesoporous Silica-Templated Assembly of Luminescent Polyester Particles
We report the template assembly of luminescent poly-3-hydroxybutyrate (PHB) particles doped with rare-earth complexes. The hydrophobic polymer, PHB, has been infiltrated into... -
r37980778c78--a0ab79e338dc0a70e60bbe6aaf3dfc66
Aminoglycoside antibiotics participate in a large variety of binding processes involving both RNA and proteins. The description, in recent years, of several clinically relevant... -
Photoswitchable Luminescence of Rhenium(I) Tricarbonyl Diimines
The synthesis, characterization, and X-ray crystal structures of Re(diimine)(CO)3(dpe) (dpe = 1,2-di(4-pyridyl)ethylene) compounds are reported. The cis-dpe complexes exhibit... -
Near-Field Optical Addressing of Luminescent Photoswitchable Supramolecular S...
Optical recording and luminescence readout of novel covalently linked photochrome/luminophore supramolecular complexes has been demonstrated by near-field scanning optical...
