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Cadmium-Based Metal–Organic Framework as a Highly Selective and Sensitive Rat...
A novel cadmium-based metal–organic framework (MOF) material with dual-emission signals has been constructed that can act as the first example of MOF-implicated ratiometric... -
r37980778c78--af63de1f14c69346e626586853efec67
The properties and applications of metal–organic frameworks (MOFs) are strongly dependent on the nature of the metals and linkers, along with the specific conditions employed... -
r37980778c78--d50d7d7203eba60d7d44482f9ddadc8b
Promoters are ubiquitous in industrial heterogeneous catalysts. The wider roles of promoters in accelerating catalysis and/or controlling selectivity are, however, not well... -
r37980778c78--11b8fc1e0f1da20de15ac0c544b47165
Direct control over structure and location of catalytic species deposited on amorphous supports represents a formidable challenge in heterogeneous catalysis. In contrast, a... -
Well-Defined Rhodium–Gallium Catalytic Sites in a Metal–Organic Framework: Pr...
Promoters are ubiquitous in industrial heterogeneous catalysts. The wider roles of promoters in accelerating catalysis and/or controlling selectivity are, however, not well... -
Investigation of Gas Adsorption Performances and H<sub>2</sub> Affinities of ...
Three isomorphous porous metal-organic frameworks (MOFs; PCN-9 (Co/Fe/Mn)) with entatic metal centers have been constructed on the basis of the trigonal planar H3TATB ligand and... -
r37980778c78--7d277564b53cdb83ec7a97e55f3caba0
A quenching-triggered reversible single-crystal-to-single-crystal (SC-SC) phase transition was discovered in a metal–organic framework (MOF) PCN-526. During the phase... -
r37980778c78--893b54c2d2a2968fad1770a2b88fa27f
In this work a rigid asymmetrical tricarboxylate ligand p-terphenyl-3,4″,5-tricarboxylic acid (H3L) has been employed, and a unique heterometallic alkaline earth–lanthanide... -
Homochiral Metal–Organic Frameworks for Enantioselective Separations in Liqui...
Selective separation of enantiomers is a substantial challenge for the pharmaceutical industry. Chromatography on chiral stationary phases is the standard method, but at a very... -
r37980778c78--bc5ecf0542338cb165e42220969b7425
A robust, noncatenated, and permanently microporous metal−organic framework (MOF) material has been synthesized by combining a new nonplanar ligand,... -
Fluorescent Aromatic Tag-Functionalized MOFs for Highly Selective Sensing of ...
By varying the fluorescent tags of resorcin[4]arene-based tetracarboxylic acids from phenyl to naphthyl, two highly luminescent metal–organic frameworks (MOFs), namely,... -
r37980778c78--a37e72d916644dabb555b5bac1231923
A coordination polymer [Ln(C15H9O9)3(H2O)3]n (1-Ln = Eu(III), Tb(III)) assembled from benzophenonedicarboxylate was synthesized and characterized. The organic component is... -
r37980778c78--7264bfc0e69c8210c2169581068f5d6d
A quenching-triggered reversible single-crystal-to-single-crystal (SC-SC) phase transition was discovered in a metal–organic framework (MOF) PCN-526. During the phase... -
Designing Porous Materials to Resist Compression: Mechanical Reinforcement of...
The performance of metal–organic frameworks (MOFs) under mechanical stress is an important consideration in the design, synthesis, and application of MOF materials in both... -
A Robust Ethane-Trapping Metal–Organic Framework with a High Capacity for Eth...
The separation of ethane from ethylene is of prime importance in the purification of chemical feedstocks for industrial manufacturing. However, differentiating these compounds... -
r37980778c78--1dc9653adb16974ba28dfcabf6469d66
The charge equilibration (QEq) method has been parametrized to reproduce the ab-initio-derived electrostatic potential in a large and diverse training set of 543 metal organic... -
r37980778c78--8bd7414246d868ad8b4d893806979d49
The separation of ethane from ethylene is of prime importance in the purification of chemical feedstocks for industrial manufacturing. However, differentiating these compounds... -
Analysis of CH<sub>4</sub> Uptake over Metal–Organic Frameworks Using Data-Mi...
A database containing 2224 data points for CH4 storage or delivery in metal–organic frameworks (MOFs) was analyzed using machine-learning tools to extract knowledge for... -
r37980778c78--3bc7ce623b4166e987909c6d00c7e8bf
A new honeycomb-shaped electroactive metal–organic framework (MOF) has been constructed from an electron deficient naphthalenediimide (NDI) ligand equipped with two terminal... -
r37980778c78--bbf176442b8898c7cbfe59f765dfe535
The development of functional solid-state materials for carbon capture at low carbon dioxide (CO2) concentrations, namely, from confined spaces (<0.5%) and in particular from...
