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Generating Active "L-Pd(0)" via Neutral or Cationic π‑Allylpalladium Complexe...
Two new classes of highly active yet air- and moisture-stable π-R-allylpalladium complexes containing bulky biaryl- and bipyrazolylphosphines with extremely broad ligand scope... -
r37980778c78--bb1f4f032cdd2c2c3349da98fb9bd374
CpTiCl2(L) [L = C4H4N (1), 2,5-Me2C4H2N (2), 2,4-Me2C4H2N (3), 2,4-Me2-3-EtC4HN (4)], CpTiCl(2,4-Me2-3-EtC4HN)2 (5), and CpTi(C4H4N)3 (6) were prepared by treating CpTiCl3 with... -
r37980778c78--3ca0fe93c39133907a0c28621cbe2d16
A series of highly volatile eight-coordinate air and moisture stable lanthanide complexes of the type [Ln(hfaa)3(L)2] (Ln = Pr (1), Nd (2), Eu (3), Gd (4), Tb (5), Dy (6), Ho... -
Steering S−H and N−H Bond Activation by a Stable N-Heterocyclic Silylene: Dif...
The strikingly different behavior of the ylide-like, N-heterocyclic silylene LSi: (5: L = CH[(CCH2)CMe(NAr)2]; Ar = 2,6-iPrC6H3) versus its LSi→Ni(CO)3 complex 13 to activate... -
Luminescent Lanthanide Complexes with Stereocontrolled Tris(2-pyridylmethyl)a...
A series of tris(2-pyridylmethyl)amines including one and two asymmetric centers were synthesized in a stereo-controlled fashion as potential ligands of lanthanide cations. The... -
Syntheses, Structures, Near-Infrared and Visible Luminescence, and Magnetic P...
Reactions of tripodal ligand 1,3,5-tris(imidazole-1-ylmethyl)-2,4,6-trimethylbenzene (L) with lanthanide metal salts and triethyl orthoformate led to the formation of six... -
r37980778c78--739005c96424e598541437cab6ffda5f
Bis(diphenylphosphinomethyl)phenylphosphine (dpmp)-supported Pt2Au heterotrinuclear complexes [Pt2Au(dpmp)2(CCPh)4](ClO4) (1), [Pt2Au(dpmp)2(DEBf)(CCPh)2](ClO4) (2),... -
Control of C–H Bond Activation by Mo-Oxo Complexes: p<i>K</i><sub>a</sub> or ...
A density functional theory (DFT) study (BMK/6-31+G(d)) was initiated to investigate the activation of benzylic carbon–hydrogen bonds by a molybdenum-oxo complex with a... -
Enhancing Phosphorescence through Rigidifying the Conformation to Achieve Hig...
Bis(diphenylphosphinomethyl)phenylphosphine (dpmp)-supported Pt2Au heterotrinuclear complexes [Pt2Au(dpmp)2(CCPh)4](ClO4) (1), [Pt2Au(dpmp)2(DEBf)(CCPh)2](ClO4) (2),... -
Strongly Luminescent Palladium(0) and Platinum(0) Diphosphine Complexes
The synthesis, structure, and photoluminescence of palladium(0) and platinum(0) complexes containing biarydiphosphines, biphep (biphep =... -
Ga<sup>3+</sup>/Ln<sup>3+</sup> Metallacrowns: A Promising Family of Highly L...
Luminescent lanthanide(III)-based molecular scaffolds hold great promises for materials science and for biological applications. Their fascinating photophysical properties... -
r37980778c78--c7d62f122111ef0e7c0bcd6c4bac0bd8
The reactivities of different 3-imino-functionalized indoles with rare-earth-metal amides [(Me3Si)2N]3RE(μ-Cl)Li(THF)3 were studied to reveal unexpected substituent effects... -
Emission Tuning of Luminescent Copper(I) Complexes by Vapor-Induced Ligand Ex...
We have synthesized two luminescent mononuclear Cu(I) complexes, [Cu(PPh2Tol)(THF)(4Mepy)2](BF4) (1) and [Cu(PPh2Tol)(4Mepy)3](BF4) (2) (PPh2Tol =... -
Highly Intense Fluorescent Diarylboron Diketonate
Diarylboron diketonates were successfully prepared by the reaction of 1,3-diketone derivatives and arylboron compounds such as triphenylborane [BPh3] and... -
r37980778c78--fe56903a158c743992e0cb74e4d9fc72
A fascinating mechanistic study of ynamido−palladium−π-allyl complexes is described that features isolation of a unique silyl ketenimine via aza-Claisen rearrangement, which can... -
Bifunctional Zn<sup>II</sup>Ln<sup>III</sup> Dinuclear Complexes Combining Fi...
There were new dinuclear ZnII–LnIII complexes of general formulas [Zn(μ-L)(μ-OAc)Ln(NO3)2] (LnIII = Tb (1), Dy (2), Er (3), and Yb (4)), [Zn(μ-L)(μ-NO3)Er(NO3)2] (5),... -
Data collection and refinement statistics.
1Statistics for data from the highest-resolution shell are shown in parentheses. 2 R sym =(ΣΣ|Ihkl−〈I〉|)/(ΣIhkl), where the average intensity <I> is taken... -
Prototypes of Lanthanide(III) Agents Responsive to Enzymatic Activities in Th...
We report first prototypes of responsive lanthanide(III) complexes that can be monitored independently in three complementary imaging modalities. Through the appropriate choice... -
Syntheses and Crystal Structures of Dinuclear Complexes Containing d-Block an...
Mononuclear complexes [Re(bpym)(CO)3Cl] and [Pt(bpym)(CC−C6H4CF3)2] (bpym = 2,2‘-bipyrimidine), in which one of the bipyrimidine sites is vacant, have been used as “complex... -
Structural and Photophysical Properties of Lathanide(III) Complexes with a No...
We report here a structural and photophysical study of lanthanide complexes with the di-deprotonated form of the bibracchial lariat ether...
