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r37980778c78--a57187364aa6088f98ac332525f9982d
The transient titanium alkylidyne complex (PNP)Ti⋮CtBu (PNP = N[2-P(CHMe2)2-4-methylphenyl]2-) can readily activate, in some cases regioselectively, the aromatic C−H bond of... -
α-Po Nets of Copper(II)-<i>trans</i>-1,4-Cyclohexanedicarboxylate Frameworks ...
Two novel three-dimensional frameworks Cu2(CDC)2(4,4‘-Bipy)·0.5H2CDC·1.25H2O (1) and Cu4(CDC)4(4,4‘-Bpe) (2) (CDC = trans-1,4-cyclohexanedicarboxylate; 4,4‘-Bipy =... -
Applications of Bis(1-R-imidazol-2-yl)disulfides and Diselenides as Ligands f...
Bis(1-R-imidazol-2-yl)disulfides, (mimR)2 (R = Ph, But), and diselenides, (seimMes)2, serve as bidentate N,N-donor ligands for main-group and transition metals. For example,... -
r37980778c78--e2c0927e26249e077fd73f4915413d1c
T-Shaped Molecular Building Units in the Porous Structure of Ag(4,4‘-bpy)·NO3 -
r37980778c78--c5e3eb44e11eb98f4dc359580585404d
Synthesis and Characterization of a Borophosphate Anion Containing a Single Vanadium Atom: [N2C6H14]2VO(PO3OH)4(B3O3OH)·4H2O -
Reactivity of Palladium(II) Complexes Containing the Orthometalated C,C-Chela...
The dinuclear complex [Pd(μ-Cl)(C6H4-2-PPh2C(H)COCH2PPh3)]2(ClO4)2 reacts with Hg(OOCCH3)2 (1:1 molar ratio, CH2Cl2, room temperature) giving the trinuclear derivative... -
r37980778c78--b8a15f8c4ca1e3b1a90310c613071d8a
We demonstrate here the single-atom migration of Tb, Gd, or Ce metal from cage to cage through an intentionally induced atomic path within a carbon nanopeapod. The atomic path... -
Metal−Ligand Cooperation in C−H and H<sub>2</sub> Activation by an Electron-R...
Unusual reactions are reported, in which the aromatic PNP ligand (PNP = 2,6-bis-(di-tert-butylphosphinomethyl)pyridine) acts in concert with the metal in the activation of H2... -
Heteroleptic Complexes of Lanthanum(III) and Neodymium(III) with Oxygen- or N...
Metathesis reactions between LaI3(THF)4 and either 2 equiv of [(Me3Si)2{Me2(Me2N)Si}C]K or 1 equiv of {(Me3Si)(Me2MeOSi)C(SiMe2CH2)}2K2 in THF yield the heteroleptic lanthanum... -
Media 1: Simplified electroholographic color reconstruction system using grap...
Originally published in Optics Express on 31 August 2009 (oe-17-18-16038) -
r37980778c78--f98d876a48cd55e200228959b6eb0e73
Bis(1-R-imidazol-2-yl)disulfides, (mimR)2 (R = Ph, But), and diselenides, (seimMes)2, serve as bidentate N,N-donor ligands for main-group and transition metals. For example,... -
The Effects of Activators on Zirconium Phosphinimide Ethylene Polymerization ...
Synthetic routes to the species CpZr(NPt-Bu3)2Cl, 7, Cp2Zr(NPt-Bu3)Cl, 8, CpZr(NPt-Bu3)2Me, 9, Cp2Zr(NPt-Bu3)Me, 10, and CpZr(NPt-Bu3)2Bn, 11, were developed in a manner similar... -
r37980778c78--ee50f303f6bc049d824efa234557da57
Bis(1-R-imidazol-2-yl)disulfides, (mimR)2 (R = Ph, But), and diselenides, (seimMes)2, serve as bidentate N,N-donor ligands for main-group and transition metals. For example,... -
r37980778c78--5972394c55944f719d1f5c8b780bbdb5
Reaction of (PNP)Ir(COE)+PF6- (1) (PNP = 2,6-bis(di-tert-butylphosphinomethyl)pyridine; COE = cyclooctene) with benzene yields a stable unsaturated square pyramidal Ir(III)... -
Steric Influence on the Reactivity of Silyl-<i>o</i>-carboranes: Oxidative-A...
The reactivity of mono(silyl)- and bis(silyl)-o-carboranes (HSiR2)n(C2B10H12-n) (n = 1, R = Me, 1a; n = 1, R = Et, 1b; n = 2, R = Me, 3a; n = 2, R = Et, 3b) toward... -
r37980778c78--b8a1997a132765e1a40df811c7961f6c
A series of chiral ansa zirconocene compounds that feature (i) [Me2Si] and [Me4Si2] bridges and (ii) two tert-butyl substituents on each cyclopentadienyl ring, namely,... -
<i>ortho</i> C−H Activation of Haloarenes and Anisole by an Electron-Rich Iri...
Reaction of (PNP)Ir(COE)+PF6- (1) (PNP = 2,6-bis(di-tert-butylphosphinomethyl)pyridine; COE = cyclooctene) with benzene yields a stable unsaturated square pyramidal Ir(III)... -
r37980778c78--f8c3996d0f0d2e17b5be01cd938e7607
Five rare-earth copper tellurides have been synthesized by the reactions of the elements at 1073 K. The isostructural compounds LaCu0.40Te2 (a = 7.7063(13) Å, b = 8.5882(14) Å,... -
[(Pd−Pd)@Ge<sub>18</sub>]<sup>4-</sup>: A Palladium Dimer Inside the Largest...
The largest single-cage deltahedral cluster is made of 18 germanium atoms and is centered by a pair of palladium atoms. Its shape is very close to the ideal D3d symmetry... -
r37980778c78--ebc69acd6444a3b5fc91761f2d820dd8
The transient titanium alkylidyne complex (PNP)Ti⋮CtBu (PNP = N[2-P(CHMe2)2-4-methylphenyl]2-) can readily activate, in some cases regioselectively, the aromatic C−H bond of...
