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Blue-, Green- and Non-luminescent Crystals from One Reaction. Isolation and S...
The metalloligand [Au{C(NHMe)(NHCH2CH2NH2)}2]Cl, 1, has been prepared by the reaction of ethylenediamine with [Au(CNMe)2]Cl. Compound 1 crystallized as a luminescent dimer with... -
Selective Formation of Rearranged Silenes from Polysilylenones via 1,3- and 1...
The polysilylenones (E)-1-phenyl-2-pivaloyl-1-(tris(trimethylsilyl)silyl)ethene (E-1a) and (Z)-2-methyl-1-phenyl-2-pivaloyl-1-tris((trimethylsilyl)silyl)ethene (Z-1b) were... -
Tuning the Optical Properties of Aryl-Substituted Dispirofluorene-Indenofluor...
Two families of positional isomers of dispirofluorene-indenofluorene substituted by phenyl groups at the 2,7-positions of the fluorene moieties present drastically different... -
r37980778c78--99bb5aebe980265002528eb312db10f6
Photochromic behavior of diarylethene derivatives with (4-pyridyl)ethynyl group directly attached to the 6-π hexatriene moieties of the diarylethenes was investigated. Upon... -
r37980778c78--6ea1358f909dd7c03a42bff2d4aad982
The use of anionic polycyclization (AP) in constructing the steroidal backbone of cardenolides was investigated. The reaction of 2-carbomethoxy-2-cyclohexenone I with the... -
Insight into Substrate Binding in Shibasaki’s Li<sub>3</sub>(THF)<sub><i>n</i...
Heterobimetallic Lewis acids M3(THF)n(BINOLate)3Ln [M = Li, Na, K; Ln = lanthanide(III)] are exceptionally useful asymmetric catalysts that exhibit high levels of... -
Effect of 2,6-Disubstituted Aryl Groups on Acyclic Conformation: Preference ...
Multiple X-ray crystallographic and 1H NMR spectroscopic studies demonstrate that 2,6-disubstituted aryl groups exert a strong effect on acyclic conformation, inducing the... -
Homoatomic Stella Quadrangula [Tl<sub>8</sub>]<sup>6−</sup> in Cs<sub>18</sub...
Cs18Tl8O6 was synthesized reacting the binary compounds CsTl and Cs2O. According to single crystal X-ray analysis, the title compound crystallizes as a novel structure type in... -
r37980778c78--88c82537413be0a14224430803bf2bae
The aim of this study was to explore the association between taste and metabolite profiles of Japanese refined sake. Nontarget metabolome analysis was conducted using capillary... -
Chemical Markup, XML and the World-Wide Web. 2. Information Objects and the C...
We describe the development of a structured method of representing chemistry on the World-Wide Web using an object-oriented approach to information objects. We show how a... -
Concise Synthesis of Novel Oxa-Bridged Compounds
A stereoselective strategy for the replacement of the 1,2-dihaloalkene bridge of tetrahalonorbornyl derivatives by an oxygen bridge involving stepwise controlled oxidation,... -
Combination Chemistry of Hexa-Copper-Substituted Polyoxometalates Driven by t...
Reaction of CuCl2·2H2O and trivacant Keggin polyoxoanion Na9[A-α-PW9O34]·7H2O in the presence of ethylene-diamine/1,2-diaminopropane (en/enMe) under hydrothermal conditions led... -
Atomic Layer Deposition of Metal Tellurides and Selenides Using Alkylsilyl Co...
Atomic Layer Deposition of Metal Tellurides and Selenides Using Alkylsilyl Compounds of Tellurium and Selenium -
r37980778c78--9c0ccad547d0b599f42d67e222f24a59
The isolable bishomoaromatic cation containing a heavier Group 14 element, (2,3,5-deloc)-2-phenyl-1,4,5-tris(tri-tert-butylsilyl)-1,4,5-trigermabicyclo[2.1.0]pent-2-en-5-ylium... -
Synthesis of (+)-CP-99,994 via Pd(0)-Catalyzed Asymmetric Allylic and Homoall...
This paper describes an asymmetric synthesis of the potent substance P receptor antagonist (+)-CP-99,994 from 4-phenyl-1-butene via Pd(0)-catalyzed asymmetric allylic and... -
A Purely Lanthanide-Based Complex Exhibiting Ferromagnetic Coupling and Slow ...
Two lanthanide−organic frameworks, {Ln(TDA)1.5(H2O)2}n [TDA = thiophene-2,5-dicarboxylic acid anion; Ln = Gd (1), Dy (2)], were structurally and magnetically characterized. The... -
Evidence for a Boroxinate Based Brønsted Acid Derivative of VAPOL as the Acti...
Evidence for a Boroxinate Based Brønsted Acid Derivative of VAPOL as the Active Catalyst in the Catalytic Asymmetric Aziridination Reaction -
Structural and Magnetic Investigations for the Doping Effect of Nonmagnetic I...
A nonmagnetic compound, [NO2BzPy][Au(mnt)2] (NO2BzPy+ = 1-(4‘-nitrobenzyl)pyridinium; mnt2- = maleonitriledithiolate), was synthesized and characterized structurally, which is... -
r37980778c78--bbc65e5aaa91e35eb9525a2cda911978
Members of a new family of macrocycles have been synthesized in one step, from simple building blocks, by sequential Claisen−Schmidt condensations. -
Diesel Bus Emissions Measured in a Tunnel Study
The emission factors of a bus fleet consisting of approximately 300 diesel-powered buses were measured in a tunnel study under well-controlled conditions during a 2-d monitoring...
