-
r37980778c78--9936f0987496119bf67c0d361a5ca781
Optical recording and luminescence readout of novel covalently linked photochrome/luminophore supramolecular complexes has been demonstrated by near-field scanning optical... -
r37980778c78--be450c80302e239cf9b27b593fff0421
Three luminescent palladium(II) and platinum(II) acetylide complexes, 1,3-[Cl(PEt3)2PdC⋮CC6H4C⋮C]2-5-[(iPr)3SiC⋮C]C6H3 and 1,3,5-[Cl(PEt3)2MC⋮CC6H4C⋮C]3C6H3 (M = Pd or Pt), have... -
Luminescent Lanthanide Complexes with Stereocontrolled Tris(2-pyridylmethyl)a...
A series of tris(2-pyridylmethyl)amines including one and two asymmetric centers were synthesized in a stereo-controlled fashion as potential ligands of lanthanide cations. The... -
X-ray-Excited Optical Luminescence (XEOL) and X-ray Absorption Fine Structure...
Synchrotron techniques, X-ray-excited optical luminescence (XEOL) combined with X-ray absorption fine structures (XAFS), have been used to study the electronic structure and... -
Mesoporous Silica-Templated Assembly of Luminescent Polyester Particles
We report the template assembly of luminescent poly-3-hydroxybutyrate (PHB) particles doped with rare-earth complexes. The hydrophobic polymer, PHB, has been infiltrated into... -
r37980778c78--a0ab79e338dc0a70e60bbe6aaf3dfc66
Aminoglycoside antibiotics participate in a large variety of binding processes involving both RNA and proteins. The description, in recent years, of several clinically relevant... -
Photoswitchable Luminescence of Rhenium(I) Tricarbonyl Diimines
The synthesis, characterization, and X-ray crystal structures of Re(diimine)(CO)3(dpe) (dpe = 1,2-di(4-pyridyl)ethylene) compounds are reported. The cis-dpe complexes exhibit... -
Near-Field Optical Addressing of Luminescent Photoswitchable Supramolecular S...
Optical recording and luminescence readout of novel covalently linked photochrome/luminophore supramolecular complexes has been demonstrated by near-field scanning optical... -
Tin- and Germanium-Substituted Enol Ethers from Fischer Carbene Complexes and...
Trialkyltin- or trialkylgermanium-substituted enol ethers 5 and 2-alkoxy-1,3-butadienes 7 have been prepared by the reaction of Fischer carbene complexes 1−3 and 6 with... -
Nickel(0) Complexes of N-Alkyl-Substituted N-Heterocyclic Carbenes and Their ...
The reaction of [Ni(COD)2] with stable N-heterocyclic carbenes R2Im (R2Im = 1,3-di(R)imidazole-2-ylidene; R2 = Me2, nPr2, MeiPr, iPr2) affords homoleptic [Ni(Me2Im)3] (1) or... -
r37980778c78--d6d08a42f0bc99e5afa83e89bbc0688e
Diarylboron diketonates were successfully prepared by the reaction of 1,3-diketone derivatives and arylboron compounds such as triphenylborane [BPh3] and... -
Diverse Structure−Activity Trends in Amine Bis(phenolate) Titanium Polymeriza...
The activity of amine bis(phenolate) Ti dibenzyl complexes in 1-hexene polymerization catalysis as a function of the phenolate substituents was investigated. Two series of Ti... -
Unusual Luminescence Spectra and Decay Dynamics in Crystalline Supramolecular...
Luminescence and electronic energy transport characteristics of supramolecular cubic F23 [(A18C6)4MnBr4][TlBr4]2 complexes (A = Rb, 1; A = K, 2) were studied with the... -
Carboxylate Ligand-Induced Intramolecular C−H Bond Activation of Iridium Comp...
We report the synthesis and structure of iridium(I) complexes with N,N′-disubstituted perimidine carbene ligands and halides or carboxylate ligands. Iodo-, chloro-, and... -
Synthesis, Structural Characterization, and Luminescence Properties of Branch...
Three luminescent palladium(II) and platinum(II) acetylide complexes, 1,3-[Cl(PEt3)2PdC⋮CC6H4C⋮C]2-5-[(iPr)3SiC⋮C]C6H3 and 1,3,5-[Cl(PEt3)2MC⋮CC6H4C⋮C]3C6H3 (M = Pd or Pt), have... -
r37980778c78--e49815be5b0256ca1e4710f99f513ccb
A new synthetic procedure has been developed which makes possible the preparation of IrLL‘3+ complexes (L, L‘ = terpyridine derivative) in good yields. In a first step, IrLCl3... -
Preparation, Structure, and Ethylene Polymerization Behavior of Bis(imino)pyr...
The synthesis, characterization, and ethylene polymerization behavior of a family of chromium(III) complexes of formula [2,6-bis(imino)pyridyl]CrCl3 is reported. The X-ray... -
Syntheses, Structures, Near-Infrared and Visible Luminescence, and Magnetic P...
Reactions of tripodal ligand 1,3,5-tris(imidazole-1-ylmethyl)-2,4,6-trimethylbenzene (L) with lanthanide metal salts and triethyl orthoformate led to the formation of six... -
Highly Luminescent Homoleptic Europium Chelates
The need for efficient and photostable lanthanide luminescent materials is dramatically increasing, in particular with respect to their growing application in lighting devices... -
r37980778c78--f7c790e34f51c62f3fd6f1f3485e8109
The electronic and molecular structures of the complexes [(η5-C5H5)(CO)2MEMe] and [(η5-C5H5)(CO)3M−EMe] (M = Cr, Mo, W; E = Si, Sn, Pb) are calculated at the density-functional...