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Luminescent Lanthanide Complexes with Stereocontrolled Tris(2-pyridylmethyl)a...
A series of tris(2-pyridylmethyl)amines including one and two asymmetric centers were synthesized in a stereo-controlled fashion as potential ligands of lanthanide cations. The... -
X-ray-Excited Optical Luminescence (XEOL) and X-ray Absorption Fine Structure...
Synchrotron techniques, X-ray-excited optical luminescence (XEOL) combined with X-ray absorption fine structures (XAFS), have been used to study the electronic structure and... -
Photoswitchable Luminescence of Rhenium(I) Tricarbonyl Diimines
The synthesis, characterization, and X-ray crystal structures of Re(diimine)(CO)3(dpe) (dpe = 1,2-di(4-pyridyl)ethylene) compounds are reported. The cis-dpe complexes exhibit... -
Tin- and Germanium-Substituted Enol Ethers from Fischer Carbene Complexes and...
Trialkyltin- or trialkylgermanium-substituted enol ethers 5 and 2-alkoxy-1,3-butadienes 7 have been prepared by the reaction of Fischer carbene complexes 1−3 and 6 with... -
Nickel(0) Complexes of N-Alkyl-Substituted N-Heterocyclic Carbenes and Their ...
The reaction of [Ni(COD)2] with stable N-heterocyclic carbenes R2Im (R2Im = 1,3-di(R)imidazole-2-ylidene; R2 = Me2, nPr2, MeiPr, iPr2) affords homoleptic [Ni(Me2Im)3] (1) or... -
Diverse Structure−Activity Trends in Amine Bis(phenolate) Titanium Polymeriza...
The activity of amine bis(phenolate) Ti dibenzyl complexes in 1-hexene polymerization catalysis as a function of the phenolate substituents was investigated. Two series of Ti... -
Preparation, Structure, and Ethylene Polymerization Behavior of Bis(imino)pyr...
The synthesis, characterization, and ethylene polymerization behavior of a family of chromium(III) complexes of formula [2,6-bis(imino)pyridyl]CrCl3 is reported. The X-ray... -
Syntheses, Structures, Near-Infrared and Visible Luminescence, and Magnetic P...
Reactions of tripodal ligand 1,3,5-tris(imidazole-1-ylmethyl)-2,4,6-trimethylbenzene (L) with lanthanide metal salts and triethyl orthoformate led to the formation of six... -
Highly Luminescent Homoleptic Europium Chelates
The need for efficient and photostable lanthanide luminescent materials is dramatically increasing, in particular with respect to their growing application in lighting devices... -
Surprisingly Bright Near-Infrared Luminescence and Short Radiative Lifetimes ...
New heterobinuclear lanthanide complexes with benzoxazole-substituted 8-hydroxyquinolines, [Ln(ligand)2(μ-ligand)2Na] (Ln: Yb, Lu), have been prepared and their structure... -
Half-Sandwich Group 4 Metal Siloxy and Silsesquioxane Complexes: Soluble Mod...
The cuboctameric hydroxysilsesquioxane (c-C5H9)7Si8O12(OH) (2), obtained after hydrolysis of (c-C5H9)7Si8O12Cl (1), and triphenylsilanol have been applied as model supports for... -
Synthesis and Structural Analysis of (Cyclopentadienyl)(pyrrolide)titanium(IV...
CpTiCl2(L) [L = C4H4N (1), 2,5-Me2C4H2N (2), 2,4-Me2C4H2N (3), 2,4-Me2-3-EtC4HN (4)], CpTiCl(2,4-Me2-3-EtC4HN)2 (5), and CpTi(C4H4N)3 (6) were prepared by treating CpTiCl3 with...
