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Remarkable Effect of Pore Size on the Catalytic Activity of Mesoporous Silica...
The catalytic activity of mesoporous silica (MCM-41) for the acetalization of cyclohexanone shows a volcano-shaped dependence on the pore diameter. The diameter of the... -
Highly Luminescent, Triple- and Quadruple-Stranded, Dinuclear Eu, Nd, and Sm(...
The bis(β-diketone) ligands 1,3-bis(3-phenyl-3-oxopropanoyl)benzene, H2L1 and 1,3-bis(3-phenyl-3-oxopropanoyl) 5-ethoxy-benzene, H2L2, have been prepared for the examination of... -
Amphiphilic Janus Gold Nanoparticles via Combining "Solid-State Grafting-to" ...
Despite the great efforts that have been made toward obtaining Janus architectures, synthesizing sub-10 nanometer Janus nanoparticles (NPs) modified with different types of... -
Multiplexed Sandwich Immunoassays using Electrochemiluminescence Imaging Reso...
A new class of bead-based microarray that uses electrogenerated chemiluminescence (ECL) as a readout mechanism to detect multiple antigens simultaneously is presented. This... -
Mechanism of Hydrogen Sorption in Single-Walled Carbon Nanotubes
Mechanism of Hydrogen Sorption in Single-Walled Carbon Nanotubes -
Modulation of T2 Relaxation Time by Light-Induced, Reversible Aggregation of ...
A reversible T2 contrast agent consisting of cross-linked anionic dextran coated iron oxide nanoparticles covalently coupled to a light-sensitive spiropyran (SP)/merocyanine... -
Pressure-Induced Infiltration of Aqueous Solutions of Multiple Promoters in a...
By applying an external pressure, an aqueous solution of promoters can be forced into a hydrophobic nanoporous silica gel. The promoter molecule demands a free volume several... -
Iridium Luminophore Complexes for Unimolecular Oxygen Sensors
In this study, a series of novel luminescent cyclometalated Ir(III) complexes has been synthesized and evaluated for use in unimolecular oxygen-sensing materials. The complexes... -
Formation of Streptavidin-Supported Lipid Bilayers on Porous Anodic Alumina: ...
Formation of Streptavidin-Supported Lipid Bilayers on Porous Anodic Alumina: Electrochemical Monitoring of Triggered Vesicle Fusion -
Correlated Layer Structures: A Novel Type of Liquid Crystalline Phase with 2...
A novel liquid crystalline quaternary five-block molecule is reported which is composed of four incompatible molecular parts, a rigid biphenyl core, two polar... -
Mechanism of Helix Induction on a Stereoregular Poly((4-carboxyphenyl)acetyle...
Cis−transoidal poly((4-carboxyphenyl)acetylene) (poly-1) is an optically inactive polymer but forms an induced one-handed helical structure upon complexation with optically... -
Thermally Cross-Linked Superparamagnetic Iron Oxide Nanoparticles: Synthesis ...
We report the fabrication and characterization of thermally cross-linked superparamagnetic iron oxide nanoparticles (TCL-SPION) and their application to the dual imaging of... -
Polymetallic Lanthanide Complexes with PAMAM-Naphthalimide Dendritic Ligands:...
Generation 3 PAMAM dendrimers functionalized with 2,3-naphthalimide chromophoric groups on the end branches were synthesized, and the formation of Eu3+ polymetallic complexes... -
Sensitized NIR Erbium(III) Emission in Confined Geometries: A New Strategy fo...
A new hybrid material, based on Er3+ exchanged zeolite L loaded with DFB molecules, is proposed as an efficient emitter in the third telecommunication window. The close... -
Coordination Copolymerization of Severely Encumbered Isoalkenes with Ethylene...
This contribution describes the implementation of the binuclear organotitanium “constrained geometry catalysts” (CGCs),... -
Azobenzene-Tethered T7 Promoter for Efficient Photoregulation of Transcription
Azobenzene was additionally introduced into side chain of T7 promoter for the photocontrol of transcription reaction by T7 RNA polymerase (T7 RNAP). When a single azobenzene... -
Mechanism and Dynamics of Azobenzene Photoisomerization
The excited-state dynamics of trans-azobenzene were investigated by femtosecond time-resolved photoelectron spectroscopy and ab initio molecular dynamics. Two near-degenerate... -
Hierarchical Porous Silica Materials with a Trimodal Pore System Using Surfac...
Porous silica exhibiting a hierarchically ordered trimodal pore system with a well-defined reverse opal microstructure and bimodal mesoporosity in the walls has been prepared by... -
Magnetically-Induced Solid-State Electrochemical Detection of DNA Hybridization
A magnetic triggering of a solid-state electrical transduction of DNA hybridization is described. Positioning of an external magnet below the thick-film electrode attracts the... -
Scaling Laws for Charge Transfer in Multiply Bridged Donor/Acceptor Molecules...
The ability of multiple spatial pathways to sum coherently and facilitate charge transfer is examined theoretically. The role of multiple spatial pathways in mediating charge...