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r37980778c78--20d5cb9ef2131f7c2f5fd1f5ab7c3f3a
The development of n-pentenyl furanosyl donors has been tested using arabinose as a model. The readily prepared ortho ester (NPOE) is converted into disarmed (NPGAC) and thence... -
Hybrid-DFT Study on Electronic Structures of the Active Site of Sweet Potato ...
The electronic structure and magnetic interactions of the active site of sweet potato purple acid phosphatase (PAP) were investigated by using UHF, pure DFT (UBLYP), and hybrid... -
r37980778c78--45c77806280e278526960e808d2b7b2b
Electrolysis of benzylthiocyanate, benzyl chloride, p-methylbenzyl chloride, p-methoxybenzyl chloride, or toluene in acetonitrile, at platinum electrodes in a two compartments... -
Synthesis of Fluoroalkene Dipeptide Isosteres by an Intramolecular Redox Reac...
(Z)-Fluoroalkene dipeptide isosteres (FADIs 16) have served as potential dipeptide mimetics possessing the substitution of fluoroalkenes for parent peptide bonds. Previously, we... -
Theoretical Investigation of 1,2-Interchange of a Chlorine Atom and Methyl Gr...
A recent photofragment translational spectroscopy study of 1,1-dichloroacetone at 193 nm reported two primary unimolecular decomposition channels: C−Cl bond cleavage and... -
Chemical Reactivity Indices as a Tool for Understanding the Support-Effect in...
The oxidation of methanol to formaldehyde on supported vanadium oxides is investigated with chemical reactivity indices. Starting from a simple model for isolated vanadium... -
r37980778c78--e88f8d488d533574ad314f400c833006
Benzheterazole derivatives with ethylene and phenyl linkers have been studied as model compounds to understand the role of (i) aromatic and heteroaromatic rings on the... -
r37980778c78--e12a76012b197e6080ba76bed600d7da
Parallel Synthesis of Tamoxifen and Derivatives on Solid Support via Resin Capture -
r37980778c78--c2d7d2831f125dfa0ff7f9444b401cb0
The solid-supported synthesis of a bicyclic diketopiperazine, a potential peptide β-turn mimetic, is described. The Ugi reaction between the resin ester of... -
Anodic Coupling Reactions: The Use of <i>N</i>,<i>O</i>-Ketene Acetal Coupli...
Intramolecular anodic olefin coupling reactions utilizing N,O-ketene acetals have been studied. Coupling reactions with both enol ether and allylsilane terminating groups were... -
Morphology-Tuned Synthesis of Single-Crystalline V<sub>5</sub>Si<sub>3</sub> ...
We report the morphology-tuned synthesis of single-crystalline V5Si3 nanotubes and nanowires. Free-standing hexagonal V5Si3 nanostructures are grown on a vanadium foil substrate... -
r37980778c78--591ea16362208c6c7ccaac4572660df7
1,8-Bis(bis(p-chlorophenyl)methylium)naphthalenediyl dication has been prepared by treatment of the corresponding diol with a mixture of [HBF4]aq and (CF3CO)2O. The proximity of... -
Anodic Coupling Reactions: A Sequential Cyclization Route to the Arteannuin ...
A pair of intramolecular anodic olefin coupling reactions has been used to construct the arteannuin ring skeleton. Both coupling reactions took advantage of a furan ring as one... -
Synthesis of Monodisperse Spiro-Bridged Ladder-Type Oligo-<i>p</i>-phenylenes
Monodisperse spiro-bridged ladder-type oligo-p-phenylenes, which have very rigid backbones, exhibited intensive emissions with very small Stocks shifts, displayed very good... -
r37980778c78--1e13d726e90796f167fd4fd4eacc3a18
Modulation of soluble guanylate cyclase (sGC) activity by nitric oxide (NO) involves two distinct steps. Low-level activation of sGC is achieved by the stoichiometric binding of... -
1,8-Bis(diphenylmethylium)naphthalenediyl Dication as an Organic Oxidant: Sy...
1,8-Bis(diphenylmethylium)naphthalenediyl dications promoted oxidative coupling of various N,N-dialkylanilines to afford the corresponding para-coupled bisanilines, benzidines,... -
r37980778c78--e566fd3a81587c206488d7815d43b84f
Simple preparation methods of modified guanidines have been explored as potential chiral superbases. Thus, 3,7,8-trisubstituted and 3,6,7,8-tetrasubstituted... -
Mechanism of Metal Chloride-Promoted Mukaiyama Aldol Reactions
Ab initio calculations (MP2/6-311+G*//B3LYP/6-31G) were employed to investigate the mechanism of metal chloride-promoted Mukaiyama aldol reaction between trihydrosilyl enol... -
Mn(II)-Induced Formation and Structural Elucidation of a [3 + 3] Benzene Dime...
Mn(II)-Induced Formation and Structural Elucidation of a [3 + 3] Benzene Dimer Derivative from m-Phenylenebis(N-tert-butylaminoxyl) -
r37980778c78--acde7a20d0b9659e7d1b36d92a65cff2
Oxone is found to be an effective oxidant for the oxidative amidation of aldehydes with anilines to furnish amides in a one-pot process under mechanical milling conditions.
