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r37980778c78--545011d4dd4486c56f37a2898bd5d021
We present a quantum mechanical/molecular mechanical (QM/MM) study using the AM1 Hamiltonian and a flexible MM part on the mode of action of the bovine lens leucine... -
Hydrocarbon Activation via Reversible 1,2-RH-Elimination from (<sup>t</sup>Bu...
Hydrocarbyl complexes, (tBu3SiNH)3ZrR (1-R), were prepared via metatheses of (tBu3SiNH)3ZrCl (1-Cl) with RMgX or RLi (R = Me, Et, Cy, CH2Ph, allyl, CHCH2, Ph, CH2tBu, C⋮CPh,... -
Role of the Ancillary Ligand <i>N</i>,<i>N</i>-Dimethylaminoethanol in the Se...
Two types of dimeric complexes [Ln2(hfa)6(μ2-O(CH2)2NHMe2)2] and [Ln(thd)2(μ2,η2-O(CH2)2NMe2)]2 (Ln = YIII, EuIII, GdIII, TbIII, TmIII, LuIII; hfa- = hexafluoroacetylacetonato,... -
Metalloradical-Catalyzed Aliphatic Carbon−Carbon Activation of Cyclooctane
Metalloradical-Catalyzed Aliphatic Carbon−Carbon Activation of Cyclooctane -
Nanoporous Amino Acid Derived Material Formed via In-Situ Dimerization of Asp...
A new mixed-ligand three-dimensional metal−organic framework is reported, where one component, meso-iminodisuccinic acid, is formed in-situ by the dimerization of aspartic acid... -
The Ternary Silicide ZrPd<sub>3</sub>Si<sub>3</sub>, a Stacking Variant of th...
The ternary zirconium palladium silicide ZrPd3Si3 has been synthesized by arc-melting of the elemental components. It adopts a new structure type and crystallizes in the... -
Multiferroic Homochiral Metal−Organic Framework
The hydrothermal reaction of (l)-ethyl lactate (Lig-Et) with Tb(ClO4)3·6H2O gives colorless block (Lig)2Tb(H2O)2(ClO4) (1), in which 1 displays a laminar 2D framework.... -
r37980778c78--5972394c55944f719d1f5c8b780bbdb5
Reaction of (PNP)Ir(COE)+PF6- (1) (PNP = 2,6-bis(di-tert-butylphosphinomethyl)pyridine; COE = cyclooctene) with benzene yields a stable unsaturated square pyramidal Ir(III)... -
A Catalytic Cycle for Oxidation of <i>tert</i>-Butyl Methyl Ether by a Double...
A Catalytic Cycle for Oxidation of tert-Butyl Methyl Ether by a Double C−H Activation-Group Transfer Process -
Steric Influence on the Reactivity of Silyl-<i>o</i>-carboranes: Oxidative-A...
The reactivity of mono(silyl)- and bis(silyl)-o-carboranes (HSiR2)n(C2B10H12-n) (n = 1, R = Me, 1a; n = 1, R = Et, 1b; n = 2, R = Me, 3a; n = 2, R = Et, 3b) toward... -
r37980778c78--cb2f7e7bdd004676b2e120d51c4d86cc
Cs+-Selective Ion Exchange and Magnetic Ordering in a Three-Dimensional Framework Uranyl Vanadium(IV) Phosphate -
Spectroscopic Studies on Cobalt(II)-Substituted Metallo-β-lactamase ImiS from...
In an effort to probe the structure of a group Bb metallo-β-lactamase, Co(II)-substituted ImiS was prepared and characterized by electronic absorption, NMR, and EPR... -
r37980778c78--c1ad79ff55a20c4949a9681423ce3c39
We present a quantum mechanical/molecular mechanical (QM/MM) study using the AM1 Hamiltonian and a flexible MM part on the mode of action of the bovine lens leucine... -
<i>ortho</i> C−H Activation of Haloarenes and Anisole by an Electron-Rich Iri...
Reaction of (PNP)Ir(COE)+PF6- (1) (PNP = 2,6-bis(di-tert-butylphosphinomethyl)pyridine; COE = cyclooctene) with benzene yields a stable unsaturated square pyramidal Ir(III)... -
Changes of the Molecular Structure in Polyelectrolyte Multilayers under Stress
Polyelectrolyte multilayers (PEMs) produced by layer-by-layer (LbL) self-assembly find different applications. Often the PEMs are exposed to mechanical stress which they have to... -
r37980778c78--04497b4f536281bee8e95f8059bb1301
We present a quantum mechanical/molecular mechanical (QM/MM) study using the AM1 Hamiltonian and a flexible MM part on the mode of action of the bovine lens leucine... -
Impact of Environmental Chemicals on Key Transcription Regulators and Correla...
Exposure to environmental chemicals adds to the burden of disease in humans and wildlife to a degree that is difficult to estimate and, thus, mitigate. The ability to assess the... -
r37980778c78--c298b938c06b33098f75d78a6be3906f
We present a quantum mechanical/molecular mechanical (QM/MM) study using the AM1 Hamiltonian and a flexible MM part on the mode of action of the bovine lens leucine... -
Diverse Cyclization Catalyzed by In(OTf)<sub>3</sub> for the Convergent Assem...
A novel In(OTf)3-catalyzed (3,5) oxonium-ene type cyclization for the facile construction of various multisubstituted tetrahydrofurans and tetrahydropyrans was successfully... -
[(Pd−Pd)@Ge<sub>18</sub>]<sup>4-</sup>: A Palladium Dimer Inside the Largest...
The largest single-cage deltahedral cluster is made of 18 germanium atoms and is centered by a pair of palladium atoms. Its shape is very close to the ideal D3d symmetry...
