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r37980778c78--1027c85e2469821348a40816b55daba2
Directly-Observed β-Hydrogen Elimination of a Late Transition Metal Amido Complex and Unusual Fate of Imine Byproducts -
r37980778c78--ebc69acd6444a3b5fc91761f2d820dd8
The transient titanium alkylidyne complex (PNP)Ti⋮CtBu (PNP = N[2-P(CHMe2)2-4-methylphenyl]2-) can readily activate, in some cases regioselectively, the aromatic C−H bond of... -
r37980778c78--2f61df8bf3f2c60d93cd74266705fb7c
The ammonium-directed olefinic oxidation of a range of cyclic allylic and homoallylic amines has been investigated. Functionalization of a range of allylic... -
r37980778c78--bbd4945cba965c19bacbd13ad769325b
The ammonium-directed olefinic oxidation of a range of cyclic allylic and homoallylic amines has been investigated. Functionalization of a range of allylic... -
r37980778c78--9bc688e08d34c969b8a08f30af6c6a02
The intermetallic phase GdCo1-xGa3Ge exhibits a charge density wave distortion in the square nets of Ga which was elucidated with superspace crystallography. The distortion... -
r37980778c78--217139c4552aa5b2ef2625eb7f3eac55
The ammonium-directed olefinic oxidation of a range of cyclic allylic and homoallylic amines has been investigated. Functionalization of a range of allylic... -
Highly Porous and Robust 4,8-Connected Metal−Organic Frameworks for Hydrogen ...
Highly Porous and Robust 4,8-Connected Metal−Organic Frameworks for Hydrogen Storage -
r37980778c78--b17266cd8216db9c7e191e90a626af2b
The transient titanium alkylidyne complex (PNP)Ti⋮CtBu (PNP = N[2-P(CHMe2)2-4-methylphenyl]2-) can readily activate, in some cases regioselectively, the aromatic C−H bond of... -
r37980778c78--8e57eef8cacfa9ab8ebc1ffe98ab6635
A low-temperature, nonaqueous synthesis approach is described that produces a series of gallium sulfide and polysulfide three-dimensional superlattices from binary Ga−S and... -
r37980778c78--bfe9f2934cdd7c2ac5bedaf5e6898bcc
The ammonium-directed olefinic oxidation of a range of cyclic allylic and homoallylic amines has been investigated. Functionalization of a range of allylic... -
An <i>in</i>-Fluorosilaphane: The Largest <i>in</i>-Functional Group Is a Un...
An in-Fluorosilaphane: The Largest in-Functional Group Is a Uniquely Encapsulated Fluorine Atom -
r37980778c78--84f22e940b4a51fdeb09ab46b2fb69e2
The factors that affect the kinetics of the aza-Bergman cyclization of aza-enediynes (C,N-dialkynyl imines) have not previously been elucidated. Here we report our kinetic... -
r37980778c78--7cf5bff9ac03b62812c0ec303d82c6a5
Reaction of an enyne (1,1-diphenyl-pent-1-ene-3-yne) with a preheated mixture of Mo(CO)6/4-chlorophenol/3-hexyne at 130 °C furnished 1,1,6,6-tetraphenylhex-1,5-diene-3-yne in an... -
r37980778c78--ef547f0ddd1d2771d82e2bf79fc30f59
Transition metal fluorides with tetragonal tungsten bronze (TTB) structure, having general formula KxMIIxMIII1-xF3 with 0.4 < x < 0.6 and M belonging to transition metals,... -
r37980778c78--10f3640c4ae8c8acc4ed00d948d26633
We demonstrate here the single-atom migration of Tb, Gd, or Ce metal from cage to cage through an intentionally induced atomic path within a carbon nanopeapod. The atomic path... -
r37980778c78--e0c7f820bfabfe1e7fcbc1dd9377860c
A variety of substituted quinolines are synthesized from imines and enolizable carbonyl compounds under aerobic conditions, in which only water is a byproduct. In DMSO, a...
