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r37980778c78--3512d613934d5053233d2075b7c28a31
The new hydridoruthenium complexes RuHCl(CO)(NHC)(PPh3) (NHC = IMes (4a), H2IMes (4b)), conveniently accessible from RuHCl(CO)(PPh3)3, exhibit high activity for hydrogenation of... -
Half-Sandwich Group 4 Metal Siloxy and Silsesquioxane Complexes: Soluble Mod...
The cuboctameric hydroxysilsesquioxane (c-C5H9)7Si8O12(OH) (2), obtained after hydrolysis of (c-C5H9)7Si8O12Cl (1), and triphenylsilanol have been applied as model supports for... -
Synthesis and Structural Analysis of (Cyclopentadienyl)(pyrrolide)titanium(IV...
CpTiCl2(L) [L = C4H4N (1), 2,5-Me2C4H2N (2), 2,4-Me2C4H2N (3), 2,4-Me2-3-EtC4HN (4)], CpTiCl(2,4-Me2-3-EtC4HN)2 (5), and CpTi(C4H4N)3 (6) were prepared by treating CpTiCl3 with... -
Differing Reactions of Functionalized Hydrocarbons with Cp*M(NO)(alkyl)(η<sup...
CpW(NO)(CH2CMe3)(η3-CH2CHCHMe) (1) is known to initiate facile and selective aliphatic C−H bond activations of hydrocarbons at ambient temperatures. Its ability to effect C−H... -
Executing a Series of Zinc(II) Complexes of Homologous Schiff Base Ligands fo...
Six zinc(II) complexes, namely, [Zn(HL1H)Cl2] (1), [Zn(HL1H)Br2] (2), [Zn2(HL1H)2(OH)I2]·I (3), [Zn(HL2)Cl] (4), [Zn2(HL2)Br3] (5), and [Zn(HL2)I] (6) have been...
