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Designing Green Oxidation Catalysts for Purifying Environmental Waters
We describe the synthesis, characterization, aqueous behavior, and catalytic activity of a new generation of FeIII−TAML (tetraamido macrocycle ligand) activators of peroxides... -
Regioselective and Enantiospecific Rhodium-Catalyzed Allylic Alkylation React...
The transition metal-catalyzed allylic alkylation represents a fundamentally important cross-coupling reaction for the construction of ternary carbon stereogenic centers. We... -
Spectroscopy and Electrochemistry of Ruthenium-Modified Nucleic Acids: Design...
Electron transfer (ET) reactions through DNA have been the subject of numerous investigations due to the implications for light-induced DNA damage and the quest for... -
A Stable Four-Membered N-Heterocyclic Carbene
The synthesis of the first four-membered N-heterocyclic carbene is described. Depending on the substituents on the nitrogen atoms, it is possible to characterize at room... -
Dissecting the Evolutionary Relationship between 14-Membered and 16-Membered ...
Dissecting the Evolutionary Relationship between 14-Membered and 16-Membered Macrolides -
Thermally Cross-Linked Superparamagnetic Iron Oxide Nanoparticles: Synthesis ...
We report the fabrication and characterization of thermally cross-linked superparamagnetic iron oxide nanoparticles (TCL-SPION) and their application to the dual imaging of... -
Polymetallic Lanthanide Complexes with PAMAM-Naphthalimide Dendritic Ligands:...
Generation 3 PAMAM dendrimers functionalized with 2,3-naphthalimide chromophoric groups on the end branches were synthesized, and the formation of Eu3+ polymetallic complexes... -
Highly Porous and Robust 4,8-Connected Metal−Organic Frameworks for Hydrogen ...
Highly porous and robust metal−organic frameworks (MOFs) were constructed based on aromatics-rich octa-carboxylate ligands and copper paddle-wheel building units. Each... -
A Selective and Sensitive Fluoroionophore for HgII, AgI, and CuIIwith Virtual...
A Selective and Sensitive Fluoroionophore for HgII, AgI, and CuII with Virtually Decoupled Fluorophore and Receptor Units -
Tin Nanoparticles Encapsulated in Porous Multichannel Carbon Microtubes: Prep...
Tin nanoparticles encapsulated in porous multichannel carbon microtubes (denoted as SPMCTs) were prepared by carbonization of electrospun PAN−PMMA−tin octoate nanofibers... -
Total Synthesis of the Anticancer Natural Product OSW-1
The highly potent anticancer natural saponin OSW-1 has been successfully synthesized from commercially available 5-androsten-3β-ol-17-one 79 in 10 operations with 28% overall... -
Iridium-catalyzed borylation of benzene with diboron. Theoretical elucidation...
Iridium-catalyzed borylation of benzene with diboron was theoretically investigated with the DFT method, where an iridium(I) boryl complex, Ir(Beg)(NN) 1, and an iridium(III)... -
Responsive Periodic Mesoporous Polydiacetylene/Silica Nanocomposites
Responsive PMO materials have been synthesized through co-assembly of bridged diacetylenic silsesquioxane and surfactant. The spatially defined polydiacetylenic component,... -
Photooxidation of 8-Oxo-7,8-dihydro-2‘-deoxyguanosine by Thermally Generated ...
Calf thymus DNA and 8-oxo-7,8-dihydro-2‘-deoxyguanosine (8-oxodGuo) were photooxidized in the dark by triplet-excited ketones generated in the thermal decomposition of... -
Engineering Target-Responsive Hydrogels Based on Aptamer−Target Interactions
In this communication, we report a simple, but highly adaptable, method of constructing selective target-responsive hydrogels using DNA aptamers. The simplicity of the design is... -
Azobenzene-Tethered T7 Promoter for Efficient Photoregulation of Transcription
Azobenzene was additionally introduced into side chain of T7 promoter for the photocontrol of transcription reaction by T7 RNA polymerase (T7 RNAP). When a single azobenzene... -
Enantioselective Epoxidation of ω-Bromo-2-methyl-1-alkenes Catalyzed by Chlor...
Enantioselective Epoxidation of ω-Bromo-2-methyl-1-alkenes Catalyzed by Chloroperoxidase. Effect of Chain Length on Selectivity and Efficiency -
Formation of Indene Derivatives from Bis(cyclopentadienyl)titanacyclopentadie...
A novel type of migration of an alkyl group in the formation of indene derivatives from titanacyclopentadienes was found. When titanacyclopentadienes with four alkyl groups were... -
Magnetically-Induced Solid-State Electrochemical Detection of DNA Hybridization
A magnetic triggering of a solid-state electrical transduction of DNA hybridization is described. Positioning of an external magnet below the thick-film electrode attracts the... -
Design and Construction of a 2D Metal Organic Framework with Multiple Cavitie...
A metal organic framework with two different nodes (circle and square) and a structure related to one of the 20 known 2-uniform nets has been constructed using an organic...
