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Applications of Bis(1-R-imidazol-2-yl)disulfides and Diselenides as Ligands f...
Bis(1-R-imidazol-2-yl)disulfides, (mimR)2 (R = Ph, But), and diselenides, (seimMes)2, serve as bidentate N,N-donor ligands for main-group and transition metals. For example,... -
r37980778c78--f98d876a48cd55e200228959b6eb0e73
Bis(1-R-imidazol-2-yl)disulfides, (mimR)2 (R = Ph, But), and diselenides, (seimMes)2, serve as bidentate N,N-donor ligands for main-group and transition metals. For example,... -
r37980778c78--f66bbf3d096b9e2c206ac24281e864b4
We report the design and construction of tunable organic clay mimic structures with one-dimensional supramolecular synthons and aromatic tectons. By connecting the robust... -
r37980778c78--ee50f303f6bc049d824efa234557da57
Bis(1-R-imidazol-2-yl)disulfides, (mimR)2 (R = Ph, But), and diselenides, (seimMes)2, serve as bidentate N,N-donor ligands for main-group and transition metals. For example,... -
Calculating Similarities between Biological Activities in the MDL Drug Data R...
There are a number of licensed databases that assign biological activities to druglike compounds. The MDL Drug Data Report (MDDR), compiled from the patent literature, is a... -
Novel 1,4-Homofragmentation via an α-Lactone
Conversion of an α,α-dichloroester to the corresponding α-keto acid was unexpectedly complicated by a novel 1,4-homofragmentation. Investigation of the kinetics of this reaction... -
r37980778c78--f5680ee4bfad1708193c9c95ea6978c9
Ultrafast 2D HMBC spectroscopy permits real-time monitoring of a reaction based on the structural changes produced in a carbonyl carbon atom. This new technique was used to... -
dedup_wf_001--08efdaeacfabe46954c22f54971b41d6
In this poster different mathematical models describing the heat transfer mechanisms through porous materials were analyzed. They were compared respectively fitted to measured... -
Design and Synthesis of 5‘-Deoxy-5‘-Phenyladenophostin A, a Highly Potent IP<...
5‘-Deoxy-5‘-phenyladenophostin A (5), designed as a useful IP3 receptor ligand based on the previous structure−activity relationship studies, was successfully synthesized via... -
Dendrimer-Supported Oligothiophene Synthesis: Aliphatic Ether Dendrimers in ...
The first dendrimer-supported synthesis of oligothiophenes is reported. The dendrimer serves both as a solubilizing group and a “handle” to facilitate the iterative synthesis of... -
Novel γ-Aminobutyric Acid ρ<sub>1</sub> Receptor Antagonists; Synthesis, Phar...
γ-Aminobutyric acid (GABA) analogues based on 4-amino-cyclopent-1-enyl phosphinic acid (34−42) and 3-aminocyclobutane phosphinic acids (51, 52, 56, 57) were investigated in... -
Rechargeable Batteries Driven by Redox Reactions of Mn12 Clusters with Struct...
Molecular clusters such as the Mn12 cluster (Mn12) can be used as a cathode-active material in Li batteries. X-ray absorption fine structure studies on the cathode materials in... -
Chemical Reactivity Indices as a Tool for Understanding the Support-Effect in...
The oxidation of methanol to formaldehyde on supported vanadium oxides is investigated with chemical reactivity indices. Starting from a simple model for isolated vanadium... -
r37980778c78--e12a76012b197e6080ba76bed600d7da
Parallel Synthesis of Tamoxifen and Derivatives on Solid Support via Resin Capture -
r37980778c78--c2d7d2831f125dfa0ff7f9444b401cb0
The solid-supported synthesis of a bicyclic diketopiperazine, a potential peptide β-turn mimetic, is described. The Ugi reaction between the resin ester of... -
r37980778c78--f415e8c04330d2807739adc8dccb0f1d
Homocysteine (Hcy) is a biomarker for significant disorders including Alzheimer's and cardiovascular disease. The monitoring of Hcy levels in plasma is of current concern. We... -
r37980778c78--c9dac6179c64b334522c0b828da436d0
The metal-organic framework, MIL-53, can have a structural transition from an open-pored to a closed-pored structure by adsorbing different guest molecules. The aid of guest... -
r37980778c78--38bdfd1bc1b53416d15bc5b7fcfa9edd
The total synthesis of the title compound (1), starting with (R)-(−)-α-phellandrene (6), has been accomplished. The synthesis rigorously proves the relative stereochemical... -
Morphology-Tuned Synthesis of Single-Crystalline V<sub>5</sub>Si<sub>3</sub> ...
We report the morphology-tuned synthesis of single-crystalline V5Si3 nanotubes and nanowires. Free-standing hexagonal V5Si3 nanostructures are grown on a vanadium foil substrate... -
Photoinduced Electron-Transfer Bicyclopropenyl-benzene Rearrangements of 2,2‘...
The 9,10-dicyanoanthracene-sensitized photoreaction of 1-methyl- and 1,1‘-dimethyl-2,2‘,3,3‘-tetraphenylbicyclopropenyl gives the corresponding benzene and Dewar benzene...