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The Rate of False Positive Sequence Matches of Peptides Profiled by MALDI MS ...
In most MALDI peptide profiling cases, sequencing is required to identify peptides of interest, preferentially by using different mass spectrometry techniques. Using identical... -
Diverse Structure−Activity Trends in Amine Bis(phenolate) Titanium Polymeriza...
The activity of amine bis(phenolate) Ti dibenzyl complexes in 1-hexene polymerization catalysis as a function of the phenolate substituents was investigated. Two series of Ti... -
Multiple Emissions and Brilliant White Luminescence from Gold(I) <i>O,O</i><i...
The Au(I) dimers Au2{S2P(OR)2}2 for R = Me, Et are found to exhibit a structure in which aurophilic interactions yield one-dimensional Au···Au chains with intermolecular... -
r37980778c78--bc001d315c0aa0c725a9c9c3ca539c9b
Color tuning and switching of the solid-state luminescence of organic materials are attractive subjects for both the fundamental research and practical applications such as... -
r37980778c78--77decee5d844927dd218e6ce40954484
We present a quantum mechanical/molecular mechanical (QM/MM) study using the AM1 Hamiltonian and a flexible MM part on the mode of action of the bovine lens leucine... -
Synthesis of Fischer Carbene Complexes of Iridium by C−H Bond Activation of M...
Synthesis of Fischer Carbene Complexes of Iridium by C−H Bond Activation of Methyl and Cyclic Ethers: Evidence for Reversible α-Hydrogen Migration -
Revisiting the Thermal Decomposition of Layered γ-Titanium Phosphate and Stru...
The thermal transformations of γ-titanium phosphate, Ti(PO4)(H2PO4)·2H2O, have been studied by thermal analyses (thermogravimetry (TG) and differential thermal analysis (DTA))... -
Zirconium-Catalyzed Kinetic Resolution of Cyclic Allylic Ethers. An Enantiose...
Zirconium-Catalyzed Kinetic Resolution of Cyclic Allylic Ethers. An Enantioselective Route to Unsaturated Medium Ring Systems -
Tuning the Optical Properties of Aryl-Substituted Dispirofluorene-Indenofluor...
Two families of positional isomers of dispirofluorene-indenofluorene substituted by phenyl groups at the 2,7-positions of the fluorene moieties present drastically different... -
<i>ansa</i>-Metallocene-Based Cyclic[2]pyrroles
Syntheses and X-ray structural analyses of ansa-metallocene-based cyclic[2]pyrroles are described. The pyrrole units in the macrocycles adopt partial 1,2-alternate conformation... -
r37980778c78--6ea1358f909dd7c03a42bff2d4aad982
The use of anionic polycyclization (AP) in constructing the steroidal backbone of cardenolides was investigated. The reaction of 2-carbomethoxy-2-cyclohexenone I with the... -
r37980778c78--a57187364aa6088f98ac332525f9982d
The transient titanium alkylidyne complex (PNP)Ti⋮CtBu (PNP = N[2-P(CHMe2)2-4-methylphenyl]2-) can readily activate, in some cases regioselectively, the aromatic C−H bond of... -
Current-Induced Metallic State in an Organic (EDT-TSF)<sub>2</sub>GaCl<sub>4<...
A newly prepared organic conductor, (EDT-TSF)2GaCl4, shows considerable nonlinear conductance in the insulating state below 20 K, and a metallic state is restored by the... -
r37980778c78--33b2320384739ed76a8f1a72d6442152
Two layered vanadyl selenites with the compositions, [DABCOH2]0.5[(VIVO)(HSeO3)(SeO3)]·H2O, I, and [enH2][(VivO)2(VVO)O2(SeO3)3]-·1.25H2O, II, have been prepared by the reaction... -
Normal mucus transport is restored in ciliated airway cultures derived from p...
Normal mucus transport is restored in ciliated airway cultures derived from patients with cystic fibrosis after replacement of the CFTR gene. This image represents yellow... -
r37980778c78--1267032f9b82bd6f3e84436e545df86c
C,D-ring symmetric chlorins 8 were prepared in 47−85% yield, on scales up to several hundred milligrams, by condensation of appropriately substituted bis-formyldihydrodipyrrins... -
Polyhydroxylated Sapphyrins: Multisite Non-metallic Catalysts for Activated ...
Enhanced hydrolysis rates for the cleavage of bis(4-nitrophenyl)phosphate (BNPP), a model phosphodiester, may be achieved by using appropriately designed ditopic receptors... -
Antiferromagnetic Behavior Based on Quasi-Orthogonal MOs: Synthesis and Char...
We report the synthesis and structural and magnetic characterization of an original Cu3 oxidase model. The Schiff base ligand used in the synthesis derives from condensation of... -
Noninvasive Imaging of Quantum Dots in Mice
Quantum dots having four different surface coatings were tested for use in in vivo imaging. Localization was successfully monitored by fluorescence imaging of living animals, by... -
Development of a Bioactive Paper Sensor for Detection of Neurotoxins Using Pi...
There is an increasing interest in new strategies to rapidly detect analytes of clinical and environmental interest without the need for sophisticated instrumentation. As an...