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Synthesis and Structure of Sr<sub>3</sub>GaN<sub>3</sub> and Sr<sub>6</sub>Ga...
Two new strontium gallium nitrides were obtained as single crystals by reaction in molten Na. Black Sr3GaN3 is isostructural with its transition metal analogues, Sr3MnN3,... -
Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Tr...
Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Trigonal Monopyramidal Geometries at both Zr and Co -
r37980778c78--33b2320384739ed76a8f1a72d6442152
Two layered vanadyl selenites with the compositions, [DABCOH2]0.5[(VIVO)(HSeO3)(SeO3)]·H2O, I, and [enH2][(VivO)2(VVO)O2(SeO3)3]-·1.25H2O, II, have been prepared by the reaction... -
Narrow-Rim Functionalization of Calix[4]arenes via Sonogashira Coupling React...
The narrow (or “lower”)-rim hydroxyl groups of calixarenes are known to be resistant to substitution/displacement. The Sonogashira coupling reaction with TMSA and... -
1,3-Bis(3,4-dimethylene-5-methyl-2-thienyl)benzene, a Singlet Tetraradical Pr...
1,3-Bis(3,4-dimethylene-5-methyl-2-thienyl)benzene, a Singlet Tetraradical Prototype of a Quasi-Alternant Nonclassical Conducting Polymer -
Concise Synthesis of Novel Oxa-Bridged Compounds
A stereoselective strategy for the replacement of the 1,2-dihaloalkene bridge of tetrahalonorbornyl derivatives by an oxygen bridge involving stepwise controlled oxidation,... -
r37980778c78--f37afb20a9754641d78d525665d2c681
The reactions of isolable dialkylsilylene 2,2,5,5-tetrakis(trimethylsilyl)-1-silacyclopentane-1,1-diyl with different types of ketones such as adamantanone, acetone,... -
r37980778c78--bc1a7e8debaa1c4e7a35f080b451a419
Macrocyclic and fused bicyclic dipeptides are complementary motifs for mimicry of different types of β-turn geometry. Macrocyclic dipeptide mimics have served as precursors for... -
r37980778c78--50343b547c566f5188639426ec76417c
3-Alkyl-1,4-dihydropyridines dimerize in acidic medium, at low temperature, to give polycyclic imminium salts derivatives that were reduced to afford new polycyclic diamine... -
r37980778c78--5cdb8bcdfbdb9055592629034333c428
The synthesis, crystal structures, inclusion ability, and structural robustness of novel crystalline inclusion compounds of [Ni(SCN)2(isoH)2]·xG (isoH = isonicotinic acid; G =... -
r37980778c78--87b37271eb2536e6729f03796c3904a2
Originally published in Optics Express on 01 September 2008 (oe-16-18-14076) -
r37980778c78--e9c3865085a5977c07e22e9a0fce3f85
The synthesis, crystal structures, inclusion ability, and structural robustness of novel crystalline inclusion compounds of [Ni(SCN)2(isoH)2]·xG (isoH = isonicotinic acid; G =... -
Enantioselective Organocatalytic <i>anti</i>-Mannich-Type Reaction of <i>N</i...
The modified cinchona alkaloid-catalyzed direct Mannich-type reaction of N-unprotected 2-oxindoles with N-Ts-imine was developed to afford anti-3,3-disubstituted 2-oxindoles... -
Evidence for a Boroxinate Based Brønsted Acid Derivative of VAPOL as the Acti...
Evidence for a Boroxinate Based Brønsted Acid Derivative of VAPOL as the Active Catalyst in the Catalytic Asymmetric Aziridination Reaction -
r37980778c78--6aa49dd0ac4cda71eae14d5dde9106fc
A new layered aluminophosphate, [C6N3H17][Al2(HPO4)(PO4)2] (denoted AlPO−CJ21), has been prepared in an alcoholic system by the use of N-(2-aminoethyl)-piperazine (AEPP) as the... -
r37980778c78--e2c0927e26249e077fd73f4915413d1c
T-Shaped Molecular Building Units in the Porous Structure of Ag(4,4‘-bpy)·NO3 -
Guest Inclusion and Structural Dynamics in 2-D Hydrogen-Bonded Metal−Organic ...
Guest Inclusion and Structural Dynamics in 2-D Hydrogen-Bonded Metal−Organic Frameworks -
Structural and Mechanistic Studies of the Dehydration of MoO<sub>2</sub>PO<su...
We report investigations into the dehydration pathway of the precursor material MoO2PO3OH·H2O to γ-(MoO2)2P2O7. The reaction occurs in three distinct stages via the formation of... -
6-Methoxy-<i>N</i>-alkyl Isatin Acylhydrazone Derivatives as a Novel Series o...
Recently, we discovered and reported a series of N-alkyl isatin acylhydrazone derivatives that are potent CB2 agonists. Here, we describe a novel series of selective CB2 inverse... -
Which One Is Preferred: Myers−Saito Cyclization of Ene-Yne-Allene or Garratt−...
A competitive scenario between Myers−Saito (MS) and Garratt−Braverman (GB) cyclization has been created in a molecule. High-level computations indicate a preference for GB over...