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Dinuclear Catecholate Helicates: Their Inversion Mechanism
Dinuclear Catecholate Helicates: Their Inversion Mechanism -
r37980778c78--bc1a7e8debaa1c4e7a35f080b451a419
Macrocyclic and fused bicyclic dipeptides are complementary motifs for mimicry of different types of β-turn geometry. Macrocyclic dipeptide mimics have served as precursors for... -
Direct Catalytic Asymmetric Vinylogous Mannich-Type and Michael Reactions of ...
Direct Catalytic Asymmetric Vinylogous Mannich-Type and Michael Reactions of an α,β-Unsaturated γ-Butyrolactam under Dinuclear Nickel Catalysis -
Magnetism of Conjugated Organic Nitroxides: Structural Scaffolding and Excha...
Magnetism of Conjugated Organic Nitroxides: Structural Scaffolding and Exchange Pathways -
A Novel Synthesis of Oxabicyclo[3.3.1]nonanone via (3,5)-Oxonium−Ene Reaction
Oxabicyclo[3.3.1]nonanone can conveniently be prepared by the reaction of trans-p-menth-6-ene-2,8-diol and aldehyde or epoxide mediated by boron trifluoride etherate in good... -
Kinetics of Chemical Degradation in Monoclonal Antibodies: Relationship betwe...
This article describes a method to analyze the kinetics of monoclonal antibody degradation and to determine the quantitative relationship between the degradation rates observed... -
First Structure of a Cyclopentadienyl Trihydride d<sup>2</sup> System: A Pse...
First Structure of a Cyclopentadienyl Trihydride d2 System: A Pseudotrigonal Prism Rather Than the Expected Pseudooctahedron and Its Mechanism of Hydrogen Scrambling -
Brownian Motion of Graphene
Brownian motion is a manifestation of the fluctuation−dissipation theorem of statistical mechanics. It regulates systems in physics, biology, chemistry, and finance. We use... -
Heterometallic 3d−4f Polyoxometalate Derived from the Weakley-Type Dimeric St...
Polyanion [{Ce(H2O)2}2Mn2(B-α-GeW9O34)2]8− (1) constitutes the first example of a heterometallic 3d−4f cluster related to the Weakley-type dimeric structure, and it contains an... -
Reaction Discovery Employing Macrocycles: Transannular Cyclizations of Macroc...
Macrocyclic bis-lactams have been synthesized by cyclodimerization of homoallylic amino esters employing a Zr(IV)-catalyzed ester-amide exchange protocol. Base-mediated... -
r37980778c78--97c6ff392b7735aa567ed88da59b8c9d
Molecular Ladders with Multiple Interpenetration of the Lateral Arms into the Squares of Adjacent Ladders Observed for M2(4,4‘-bpy)3(H2O)2(phba)22·4H2O (M = Cu2+ or Co2+;... -
Additional file 16: Figure S7. of MitoRS, a method for high throughput, sensi...
Coverage drop at the position 310 human C-stretch. The human sample #12878 from the CEPH family 1463 was sequenced either following the pipeline described in this paper or from... -
dedup_wf_001--c1c339b21dfdc3668c86021311e8d90a
Material 16, Western Blot 20, 30 and 60 μg, Western blots performed on HMFs encapsulated in 20, 30 and 60 μg hydrogels. (PPTX 18885 kb) -
Additional file 6: Figure S5. of Follistatin is a metastasis suppressor in a ...
FST expression is associated with overall survival and metastasis in multiple cohorts of patients with breast cancer. Tumors are stratified into the highest 10% and lowest... -
Engineering the enolase magnesium II binding site: implications for its evolu...
The glycolytic enzyme enolase catalyzes the reversible elimination of water from 2-phosphoglycerate (2-PGA) to form phosphoenolpyruvate (PEP). Two magnesium ions in the active... -
Reactions of α,α‘-Dihydroxy Ketones with Phosgene. Structural Requirements fo...
α,α‘-Dihydroxy ketones having two OH groups that can come into close proximity react with phosgene in the presence of DMAP to produce 1,3-dioxane-2,5-diones. When covalent... -
r37980778c78--846564b65f52c385ecb3cccfd64a98dc
Protein ADP-ribosyltransferases catalyze the transfer of adenosine diphosphate ribose (ADP-ribose) from nicotinamide adenine dinucleotide (NAD) onto specific target proteins.... -
r37980778c78--abf8e30a95480dae802c80ac51f3c098
Mineral-catalyzed decarboxylation reactions are important in both crude oil formation and, increasingly, biofuel production. In this study we examined decarboxylation reactions... -
r37980778c78--bf2c1a7fa126b07a7d5ef3333acbb9b0
Mixtures of butyllithium and copper iodide prepared in toluene react with α,β-unsaturated ketones predominantly in a 1,2-fashion. Addition of various ethers to the system... -
Rechargeable Batteries Driven by Redox Reactions of Mn12 Clusters with Struct...
Molecular clusters such as the Mn12 cluster (Mn12) can be used as a cathode-active material in Li batteries. X-ray absorption fine structure studies on the cathode materials in...
