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Dinuclear Catecholate Helicates: Their Inversion Mechanism
Dinuclear Catecholate Helicates: Their Inversion Mechanism -
r37980778c78--bc1a7e8debaa1c4e7a35f080b451a419
Macrocyclic and fused bicyclic dipeptides are complementary motifs for mimicry of different types of β-turn geometry. Macrocyclic dipeptide mimics have served as precursors for... -
Magnetism of Conjugated Organic Nitroxides: Structural Scaffolding and Excha...
Magnetism of Conjugated Organic Nitroxides: Structural Scaffolding and Exchange Pathways -
First Structure of a Cyclopentadienyl Trihydride d<sup>2</sup> System: A Pse...
First Structure of a Cyclopentadienyl Trihydride d2 System: A Pseudotrigonal Prism Rather Than the Expected Pseudooctahedron and Its Mechanism of Hydrogen Scrambling -
Brownian Motion of Graphene
Brownian motion is a manifestation of the fluctuation−dissipation theorem of statistical mechanics. It regulates systems in physics, biology, chemistry, and finance. We use... -
Reaction Discovery Employing Macrocycles: Transannular Cyclizations of Macroc...
Macrocyclic bis-lactams have been synthesized by cyclodimerization of homoallylic amino esters employing a Zr(IV)-catalyzed ester-amide exchange protocol. Base-mediated... -
r37980778c78--97c6ff392b7735aa567ed88da59b8c9d
Molecular Ladders with Multiple Interpenetration of the Lateral Arms into the Squares of Adjacent Ladders Observed for M2(4,4‘-bpy)3(H2O)2(phba)22·4H2O (M = Cu2+ or Co2+;... -
Additional file 16: Figure S7. of MitoRS, a method for high throughput, sensi...
Coverage drop at the position 310 human C-stretch. The human sample #12878 from the CEPH family 1463 was sequenced either following the pipeline described in this paper or from... -
Engineering the enolase magnesium II binding site: implications for its evolu...
The glycolytic enzyme enolase catalyzes the reversible elimination of water from 2-phosphoglycerate (2-PGA) to form phosphoenolpyruvate (PEP). Two magnesium ions in the active... -
Reactions of α,α‘-Dihydroxy Ketones with Phosgene. Structural Requirements fo...
α,α‘-Dihydroxy ketones having two OH groups that can come into close proximity react with phosgene in the presence of DMAP to produce 1,3-dioxane-2,5-diones. When covalent... -
Rechargeable Batteries Driven by Redox Reactions of Mn12 Clusters with Struct...
Molecular clusters such as the Mn12 cluster (Mn12) can be used as a cathode-active material in Li batteries. X-ray absorption fine structure studies on the cathode materials in... -
r37980778c78--14bcc011c7267c7c62ea1fe11790c0db
Regulation of Singlet Oxygen Generation Using Single-Walled Carbon Nanotubes -
Quaternary Structural Transitions in the DeoR-Type Repressor UlaR Control Tra...
UlaR is a DNA binding protein of the DeoR family of eubacterial transcriptional repressors which maintains the utilization of the l-ascorbate ula regulon in a repressed state.... -
dedup_wf_001--ef627442c71aa0dd061b9eedf5e56d5e
Ponencia en las sesiones de presentación, Universidad de Navarra 25 y 26 de Marzo de 2013. -
Multiplexed Real-Time Polymerase Chain Reaction on a Digital Microfluidic Pla...
This paper details the development of a digital microfluidic platform for multiplexed real-time polymerase chain reactions (PCR). Liquid samples in discrete droplet format are... -
An Efficient C−H Oxidation Protocol for α-Hydroxylation of Cyclic Steroidal E...
Various C-16 hydroxy steroids have been prepared with the aid of CrO3/Bu4NIO4. Out of the two possible reaction courses, transition state B is favored because of less steric... -
r37980778c78--1e13d726e90796f167fd4fd4eacc3a18
Modulation of soluble guanylate cyclase (sGC) activity by nitric oxide (NO) involves two distinct steps. Low-level activation of sGC is achieved by the stoichiometric binding of... -
Iridium-catalyzed borylation of benzene with diboron. Theoretical elucidation...
Iridium-catalyzed borylation of benzene with diboron was theoretically investigated with the DFT method, where an iridium(I) boryl complex, Ir(Beg)(NN) 1, and an iridium(III)... -
Computational Study on the Aminolysis of β-Hydroxy-α,β-Unsaturated Ester via ...
The possible mechanisms of the aminolysis of N-methyl-3-(methoxycarbonyl)-4-hydroxy-2-pyridone (β-hydroxy-α,β-unsaturated ester) with dimethylamine are investigated at the... -
Azobenzene-Tethered T7 Promoter for Efficient Photoregulation of Transcription
Azobenzene was additionally introduced into side chain of T7 promoter for the photocontrol of transcription reaction by T7 RNA polymerase (T7 RNAP). When a single azobenzene...
