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Asymmetry by Electrophilic Rearrangement of Symmetric 2-Pyridone Photodimers
Halogenation of achiral trans-2-pyridone photodimers results in 1,3-migration of an amide nitrogen and formation of a chiral structure with six stereogenic centers and... -
r37980778c78--fe56903a158c743992e0cb74e4d9fc72
A fascinating mechanistic study of ynamido−palladium−π-allyl complexes is described that features isolation of a unique silyl ketenimine via aza-Claisen rearrangement, which can... -
Asymmetry by Electrophilic Rearrangement of Symmetric 2-Pyridone Photodimers
Halogenation of achiral trans-2-pyridone photodimers results in 1,3-migration of an amide nitrogen and formation of a chiral structure with six stereogenic centers and... -
r37980778c78--de9c88c54aa1a1f8ee713fbd23a73810
Benzo[1,4]thiazin-3(4H)-one derivatives are conveniently prepared in one pot via a Smiles rearrangement (SR) tandem reaction. In order to understand the reaction, we present... -
Organocatalytic Asymmetric Vinylogous α-Ketol Rearrangement: Enantioselective...
Organocatalytic Asymmetric Vinylogous α-Ketol Rearrangement: Enantioselective Construction of Chiral All-Carbon Quaternary Stereocenters in Spirocyclic Diketones via...
