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Novel Manganese(II) Sulfonate−Phosphonates with Dinuclear, Tetranuclear, and ...
Hydrothermal reactions of manganese(II) salts with m-sulfophenylphosphonic acid (m-HO3S−Ph−PO3H2, H3L) and 1,10-phenanthroline (phen) led to six novel manganese(II)... -
A Formal Total Synthesis of (+)-Zincophorin. Observation of an Unusual Urea-D...
A formal total synthesis of (+)-zincophorin via interception of Miyashita's advanced intermediates is described here. This effort features the first synthetic application of an... -
Synthesis of Fischer Carbene Complexes of Iridium by C−H Bond Activation of M...
Synthesis of Fischer Carbene Complexes of Iridium by C−H Bond Activation of Methyl and Cyclic Ethers: Evidence for Reversible α-Hydrogen Migration -
Normal mucus transport is restored in ciliated airway cultures derived from p...
Normal mucus transport is restored in ciliated airway cultures derived from patients with cystic fibrosis after replacement of the CFTR gene. This image represents yellow... -
Synthesis and Electronic Properties of Isotruxene-Derived Star-Shaped Ladder-...
The synthesis of star-shaped ladder-type oligophenylenes Sn (n = 4, 7, 10, 13, and 16), where n is the number of π-conjugated phenylene rings, is reported. The two-dimensional... -
Homoatomic Stella Quadrangula [Tl<sub>8</sub>]<sup>6−</sup> in Cs<sub>18</sub...
Cs18Tl8O6 was synthesized reacting the binary compounds CsTl and Cs2O. According to single crystal X-ray analysis, the title compound crystallizes as a novel structure type in... -
Highly Activated Vinyl Hydrogen in a Significantly Twisted Styrene
The novel example of a vinylic hydrogen more reactive than a benzylic hydrogen was found by treatment of a twisted styrene derivative with a strong base followed by D2O... -
Thermal Conductivities of Alternatives to CFC-11 for Foam Insulation
The present work examines the thermal conductivities of several dilute vapors which are potential alternatives to chlorofluorocarbons (CFCs) for cellular-plastic foams. Thermal... -
Synthesis, Characterization, and Crystal Growth of Cs<sub>2</sub>Hg<sub>3</su...
This paper reports, for the first time, the second-order nonlinear optical (NLO) property of Cs2Hg3I8, a new potential NLO material in the infrared region. The compound exhibits... -
r37980778c78--ae4aee7484bbcc34ecdfe69868502683
The 5-hydroxytryptamine 2A (5-HT2A) receptor is a member of the G protein-coupled receptor superfamily (GPCR) and plays a key role in transducing a variety of cellular signals... -
Applications of Bis(1-R-imidazol-2-yl)disulfides and Diselenides as Ligands f...
Bis(1-R-imidazol-2-yl)disulfides, (mimR)2 (R = Ph, But), and diselenides, (seimMes)2, serve as bidentate N,N-donor ligands for main-group and transition metals. For example,... -
1,8-Bis(diphenylmethylium)naphthalenediyl Dication as an Organic Oxidant: Sy...
1,8-Bis(diphenylmethylium)naphthalenediyl dications promoted oxidative coupling of various N,N-dialkylanilines to afford the corresponding para-coupled bisanilines, benzidines,... -
Efficient Route for Cyclic Olefin Polymerization: Nonchelated Monodentate Be...
We developed a series of nonchelated monodentate benzimidazole nickel complexes, bis[2-(2,6-difluorophenyl)-1H-benzimidazole]nickel(II) dibromide (1),... -
Steering S−H and N−H Bond Activation by a Stable N-Heterocyclic Silylene: Dif...
The strikingly different behavior of the ylide-like, N-heterocyclic silylene LSi: (5: L = CH[(CCH2)CMe(NAr)2]; Ar = 2,6-iPrC6H3) versus its LSi→Ni(CO)3 complex 13 to activate... -
Synthesis, Structure, and Isomerization of Decapentynylcorannulene: Enediyne...
Decapentynylcorannulene (5) is prepared via aryl−alkyne coupling chemistry of decachlorocorannulene and trimethylstannylpentyne. The crystal structure of 5 is compared with the... -
H-Type Dimer Formation of Fluorophores: A Mechanism for Activatable, <i>in Vi...
In vivo molecular imaging with target-specific activatable “smart” probes, which yield fluorescence only at the intended target, enables sensitive and specific cancer detection.... -
Indium Chalcogenido Clusters Coordinated by 1,10-Phenanthroline, [InQ(phen)Cl...
Most metal−1,10-phenanthroline-complex-sensitized inorganic semiconductors are multicomponent materials. This fundamental study was devoted to the single-phase materials fused... -
Guest Inclusion and Structural Dynamics in 2-D Hydrogen-Bonded Metal−Organic ...
Guest Inclusion and Structural Dynamics in 2-D Hydrogen-Bonded Metal−Organic Frameworks -
Luminescent Lanthanide Complexes with Stereocontrolled Tris(2-pyridylmethyl)a...
A series of tris(2-pyridylmethyl)amines including one and two asymmetric centers were synthesized in a stereo-controlled fashion as potential ligands of lanthanide cations. The... -
Mn(II)-Induced Formation and Structural Elucidation of a [3 + 3] Benzene Dime...
Mn(II)-Induced Formation and Structural Elucidation of a [3 + 3] Benzene Dimer Derivative from m-Phenylenebis(N-tert-butylaminoxyl)
