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r37980778c78--bb1f4f032cdd2c2c3349da98fb9bd374
CpTiCl2(L) [L = C4H4N (1), 2,5-Me2C4H2N (2), 2,4-Me2C4H2N (3), 2,4-Me2-3-EtC4HN (4)], CpTiCl(2,4-Me2-3-EtC4HN)2 (5), and CpTi(C4H4N)3 (6) were prepared by treating CpTiCl3 with... -
Luminescent Lanthanide Complexes with Stereocontrolled Tris(2-pyridylmethyl)a...
A series of tris(2-pyridylmethyl)amines including one and two asymmetric centers were synthesized in a stereo-controlled fashion as potential ligands of lanthanide cations. The... -
Syntheses, Structures, Near-Infrared and Visible Luminescence, and Magnetic P...
Reactions of tripodal ligand 1,3,5-tris(imidazole-1-ylmethyl)-2,4,6-trimethylbenzene (L) with lanthanide metal salts and triethyl orthoformate led to the formation of six... -
Highly Intense Fluorescent Diarylboron Diketonate
Diarylboron diketonates were successfully prepared by the reaction of 1,3-diketone derivatives and arylboron compounds such as triphenylborane [BPh3] and... -
r37980778c78--9936f0987496119bf67c0d361a5ca781
Optical recording and luminescence readout of novel covalently linked photochrome/luminophore supramolecular complexes has been demonstrated by near-field scanning optical... -
Luminescent Lanthanide Complexes with Stereocontrolled Tris(2-pyridylmethyl)a...
A series of tris(2-pyridylmethyl)amines including one and two asymmetric centers were synthesized in a stereo-controlled fashion as potential ligands of lanthanide cations. The... -
X-ray-Excited Optical Luminescence (XEOL) and X-ray Absorption Fine Structure...
Synchrotron techniques, X-ray-excited optical luminescence (XEOL) combined with X-ray absorption fine structures (XAFS), have been used to study the electronic structure and... -
Mesoporous Silica-Templated Assembly of Luminescent Polyester Particles
We report the template assembly of luminescent poly-3-hydroxybutyrate (PHB) particles doped with rare-earth complexes. The hydrophobic polymer, PHB, has been infiltrated into... -
Photoswitchable Luminescence of Rhenium(I) Tricarbonyl Diimines
The synthesis, characterization, and X-ray crystal structures of Re(diimine)(CO)3(dpe) (dpe = 1,2-di(4-pyridyl)ethylene) compounds are reported. The cis-dpe complexes exhibit... -
Near-Field Optical Addressing of Luminescent Photoswitchable Supramolecular S...
Optical recording and luminescence readout of novel covalently linked photochrome/luminophore supramolecular complexes has been demonstrated by near-field scanning optical... -
r37980778c78--d6d08a42f0bc99e5afa83e89bbc0688e
Diarylboron diketonates were successfully prepared by the reaction of 1,3-diketone derivatives and arylboron compounds such as triphenylborane [BPh3] and... -
Syntheses, Structures, Near-Infrared and Visible Luminescence, and Magnetic P...
Reactions of tripodal ligand 1,3,5-tris(imidazole-1-ylmethyl)-2,4,6-trimethylbenzene (L) with lanthanide metal salts and triethyl orthoformate led to the formation of six... -
Highly Luminescent Homoleptic Europium Chelates
The need for efficient and photostable lanthanide luminescent materials is dramatically increasing, in particular with respect to their growing application in lighting devices... -
r37980778c78--f7c790e34f51c62f3fd6f1f3485e8109
The electronic and molecular structures of the complexes [(η5-C5H5)(CO)2MEMe] and [(η5-C5H5)(CO)3M−EMe] (M = Cr, Mo, W; E = Si, Sn, Pb) are calculated at the density-functional... -
r37980778c78--3512d613934d5053233d2075b7c28a31
The new hydridoruthenium complexes RuHCl(CO)(NHC)(PPh3) (NHC = IMes (4a), H2IMes (4b)), conveniently accessible from RuHCl(CO)(PPh3)3, exhibit high activity for hydrogenation of... -
Half-Sandwich Group 4 Metal Siloxy and Silsesquioxane Complexes: Soluble Mod...
The cuboctameric hydroxysilsesquioxane (c-C5H9)7Si8O12(OH) (2), obtained after hydrolysis of (c-C5H9)7Si8O12Cl (1), and triphenylsilanol have been applied as model supports for... -
Synthesis and Structural Analysis of (Cyclopentadienyl)(pyrrolide)titanium(IV...
CpTiCl2(L) [L = C4H4N (1), 2,5-Me2C4H2N (2), 2,4-Me2C4H2N (3), 2,4-Me2-3-EtC4HN (4)], CpTiCl(2,4-Me2-3-EtC4HN)2 (5), and CpTi(C4H4N)3 (6) were prepared by treating CpTiCl3 with...