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Multiple Emissions and Brilliant White Luminescence from Gold(I) <i>O,O</i><i...
The Au(I) dimers Au2{S2P(OR)2}2 for R = Me, Et are found to exhibit a structure in which aurophilic interactions yield one-dimensional Au···Au chains with intermolecular... -
r37980778c78--77decee5d844927dd218e6ce40954484
We present a quantum mechanical/molecular mechanical (QM/MM) study using the AM1 Hamiltonian and a flexible MM part on the mode of action of the bovine lens leucine... -
Current-Induced Metallic State in an Organic (EDT-TSF)<sub>2</sub>GaCl<sub>4<...
A newly prepared organic conductor, (EDT-TSF)2GaCl4, shows considerable nonlinear conductance in the insulating state below 20 K, and a metallic state is restored by the... -
Investigation of Gas Adsorption Performances and H<sub>2</sub> Affinities of ...
Three isomorphous porous metal-organic frameworks (MOFs; PCN-9 (Co/Fe/Mn)) with entatic metal centers have been constructed on the basis of the trigonal planar H3TATB ligand and... -
r37980778c78--87322534952ff942405d32b83b3c885c
The first n-type FET based on TTF derivatives was prepared. TTF derivatives with halogeno-substituted quinoxaline rings showed excellent n- or p-type performances with high... -
α-Po Nets of Copper(II)-<i>trans</i>-1,4-Cyclohexanedicarboxylate Frameworks ...
Two novel three-dimensional frameworks Cu2(CDC)2(4,4‘-Bipy)·0.5H2CDC·1.25H2O (1) and Cu4(CDC)4(4,4‘-Bpe) (2) (CDC = trans-1,4-cyclohexanedicarboxylate; 4,4‘-Bipy =... -
Regioselective and Enantiospecific Rhodium-Catalyzed Allylic Alkylation React...
The transition metal-catalyzed allylic alkylation represents a fundamentally important cross-coupling reaction for the construction of ternary carbon stereogenic centers. We... -
Bisindolylmaleimides as Red Electroluminescence Materials
Derivatives of bisindolylmaleimide were found to form amorphous solid films which exhibit red luminescence, and can be fabricated into light-emitting diodes. The property of... -
r37980778c78--5920e11e67397bcd3e5b93ea22fc3268
Treatment of the bis(iminobenzyl)pyridine chelate Schiff-base ligand 8 (ligPh) with FeCl2 or CoCl2 yielded the corresponding (ligPh)MCl2 complexes 9 (Fe) and 10 (Co). The... -
Selective Hydrogenation of Aromatic Hydrocarbons Using a Triruthenium Carbony...
Selective Hydrogenation of Aromatic Hydrocarbons Using a Triruthenium Carbonyl Cluster as a Template to Control the Hydrogenation Site: First Successful Isolation of... -
Evidence for a Boroxinate Based Brønsted Acid Derivative of VAPOL as the Acti...
Evidence for a Boroxinate Based Brønsted Acid Derivative of VAPOL as the Active Catalyst in the Catalytic Asymmetric Aziridination Reaction -
Efficient Route for Cyclic Olefin Polymerization: Nonchelated Monodentate Be...
We developed a series of nonchelated monodentate benzimidazole nickel complexes, bis[2-(2,6-difluorophenyl)-1H-benzimidazole]nickel(II) dibromide (1),... -
r37980778c78--6aa49dd0ac4cda71eae14d5dde9106fc
A new layered aluminophosphate, [C6N3H17][Al2(HPO4)(PO4)2] (denoted AlPO−CJ21), has been prepared in an alcoholic system by the use of N-(2-aminoethyl)-piperazine (AEPP) as the... -
A Series of New Manganese(II) Sulfonate-Arsonates with 2D Layer, 1D Chain, an...
Hydrothermal reactions of manganese(II) salts with o-sulfophenylarsonic acid (o-HO3S−C6H4−AsO3H2, H3L) afforded Mn3(L)2(H2O)3·H2O (1) with a layered structure. When... -
6-Methoxy-<i>N</i>-alkyl Isatin Acylhydrazone Derivatives as a Novel Series o...
Recently, we discovered and reported a series of N-alkyl isatin acylhydrazone derivatives that are potent CB2 agonists. Here, we describe a novel series of selective CB2 inverse... -
r37980778c78--bc5ecf0542338cb165e42220969b7425
A robust, noncatenated, and permanently microporous metal−organic framework (MOF) material has been synthesized by combining a new nonplanar ligand,... -
Syntheses, Structures, Near-Infrared and Visible Luminescence, and Magnetic P...
Reactions of tripodal ligand 1,3,5-tris(imidazole-1-ylmethyl)-2,4,6-trimethylbenzene (L) with lanthanide metal salts and triethyl orthoformate led to the formation of six... -
r37980778c78--60cfdf79a6c7ee377ca77d83c592bdd4
A carbene transfer agent, 1,3-bis-(2,4,6-trimethylphenyl)imidazol-2-ylidene-silver(I)chloride ([IMes]AgCl), was treated with various osmium clusters. Reaction of ([IMes]AgCl)... -
Structure and Magnetism of a Spin Ladder System: (C<sub>5</sub>H<sub>9</sub>...
The crystal structure of bis(cyclopentylammonium)tetrabromocuprate(II) has been determined at room temperature and at −70 °C. The room temperature structure is orthorhombic,... -
Nickel(0) Complexes of N-Alkyl-Substituted N-Heterocyclic Carbenes and Their ...
The reaction of [Ni(COD)2] with stable N-heterocyclic carbenes R2Im (R2Im = 1,3-di(R)imidazole-2-ylidene; R2 = Me2, nPr2, MeiPr, iPr2) affords homoleptic [Ni(Me2Im)3] (1) or...
