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Bipleiophylline, an Unprecedented Cytotoxic Bisindole Alkaloid Constituted fr...
A cytotoxic bisindole alkaloid possessing an unprecedented structure in which two indole moieties are bridged by an aromatic spacer unit has been isolated from Alstonia... -
A New Synthetic Route to 3-Oxo-4-amino-1,2,3-oxadiazole from the Diazeniumdio...
Treating benzylcyanide with nitric oxide in basic methanol returns 3-oxo-4-phenyl-5-amino-1,2,3-oxadiazole (a 5-iminium-sydnone N-oxide), 5, in addition to the known... -
Isolation from <i>Eucalyptus </i><i>o</i><i>ccidentalis</i> and Identificatio...
In this paper we report the isolation and structural elucidation of a new flavonoid (1) and three known compounds, 6,8-di-C-methylkaempferol 3-methyl ether (2), oleanolic acid,... -
r37980778c78--e524ecf7e6739ebd2995e09d6c33e4da
Reaction of the cyanoruthenate anions [Ru(bpym)(CN)4]2- and [{Ru(CN)4}2(μ-bpym)]4- (bpym = 2,2‘-bipyrimidine) with lanthanide(III) salts resulted in the crystallization of... -
r37980778c78--2244525d0d43336e9f8097c81fe38ad6
We present a quantum mechanical/molecular mechanical (QM/MM) study using the AM1 Hamiltonian and a flexible MM part on the mode of action of the bovine lens leucine... -
r37980778c78--43c32c23212f0aa28a24c1d91d6c3b58
Hydrothermal reactions of manganese(II) salts with m-sulfophenylphosphonic acid (m-HO3S−Ph−PO3H2, H3L) and 1,10-phenanthroline (phen) led to six novel manganese(II)... -
r37980778c78--a13e98a6431072d56597755699e40ed6
We present a quantum mechanical/molecular mechanical (QM/MM) study using the AM1 Hamiltonian and a flexible MM part on the mode of action of the bovine lens leucine... -
Nanoparticles and Nanosheets of Aromatic Polyimides via Polycondensation in C...
Nanoparticles and nanosheets of a high-performance aromatic polyimide can be synthesized via a simple monomer adsorption/polycondensation process inside the pores of specially... -
Crystal Structures and Magnetic and Ferroelectric Properties of Chiral Layere...
Two homochiral 2D-layered frameworks composed of a Cu2O2 core and dicyanamide (dca) linkers, [Cu((R)-hmp)(dca)]n (1) and [Cu((S)-hmp)(dca)]n (2) (hmp* =... -
Visible and Near-Infrared Emission by Samarium(III)-Containing Ionic Liquid M...
Highly luminescent anionic samarium(III) β-diketonate and dipicolinate complexes were dissolved in the imidazolium ionic liquid 1-hexyl-3-methylimidazolium... -
Salt-Templated Mesoporous Solids Comprised of Interlinked Polyoxovanadate Clu...
The utility of molten salts has been demonstrated in the synthesis of the first family of mesoporous salt-inclusion solids featuring [V4O16] and [V5O17] polyoxovanadate (POV)... -
r37980778c78--3f1727f75d16a84dd0472d583f08fded
We present two porous luminescent compounds, [Ln2(fumarate)2(oxalate)(H2O)4]·4H2O (Ln = Eu, Tb), prepared by the hydrothermal method. The materials have 3D framework structure... -
Polyoxometalate-Based Porous Framework with Perovskite Topology
With the use of a flexible N-donor ligand 1,3-bis(4-pyridyl)propane (bpp), a new porous framework with Wells-Dawson clusters as nodes and Ni2+ ions as linkers,... -
Solvent Effects and Activation Parameters in the Competitive Cleavage of C−CN...
The reaction of [(dippe)NiH]2 with 2-methyl-3-butenenitrile (2M3BN) in solvents spanning a wide range of polarities shows significant differences in the ratio of C−H and C−CN... -
r37980778c78--d2b822009bb8e63af30216df0da7e03a
Studies of Mg2Cu6Ga5 reveal that this compound contains incomplete Bergman clusters in its structure and shows a pseudogap and empty bonding states just above the Fermi energy... -
Palladium-Catalyzed Aromatic C−H Halogenation with Hydrogen Halides by Means ...
Palladium-Catalyzed Aromatic C−H Halogenation with Hydrogen Halides by Means of Electrochemical Oxidation -
r37980778c78--608e5f946f95b13bf2e7869cdf8d61a9
Peptide separation selectivity in reversed-phase liquid chromatography was investigated using a training set of 165 peptides with a total of 1698 amino acid residues. Gradient... -
Synthesis of Mono- and Difluoroacetyltrialkylsilanes and the Corresponding En...
A variety of mono- and difluoroacetylsilanes and the corresponding silyl enol ethers were prepared from trifluoroethanol and chlorotrialkylsilanes in the presence of LDA through... -
r37980778c78--e70761ad6e7748a57f4e2f2bc08954ef
A variety of mono- and difluoroacetylsilanes and the corresponding silyl enol ethers were prepared from trifluoroethanol and chlorotrialkylsilanes in the presence of LDA through... -
r37980778c78--9874ce5ce8c615b42746a2478c130076
Following a critical analysis of the dioxygenase literature and injection of the insights therein into the development of new dioxygenase catalysts, two new, of four total...
