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Synthesis and Structure of Sr<sub>3</sub>GaN<sub>3</sub> and Sr<sub>6</sub>Ga...
Two new strontium gallium nitrides were obtained as single crystals by reaction in molten Na. Black Sr3GaN3 is isostructural with its transition metal analogues, Sr3MnN3,... -
Multiple Emissions and Brilliant White Luminescence from Gold(I) <i>O,O</i><i...
The Au(I) dimers Au2{S2P(OR)2}2 for R = Me, Et are found to exhibit a structure in which aurophilic interactions yield one-dimensional Au···Au chains with intermolecular... -
r37980778c78--77decee5d844927dd218e6ce40954484
We present a quantum mechanical/molecular mechanical (QM/MM) study using the AM1 Hamiltonian and a flexible MM part on the mode of action of the bovine lens leucine... -
Quantitation of Twelve Metals in Tequila and Mezcal Spirits as Authenticity P...
In this paper the differentiation of silver, gold, aged and extra-aged tequila and mezcal has been carried out according to their metal content. Aluminum, barium, calcium,... -
r37980778c78--b2cfb20019ab04cb333f9d105aa2e84d
Molecular Charge-Transfer Salt of BEDT−TTF [Bis(ethylenedithio)tetrathiafulvalene] with the Oxalate-Bridged Dimeric Anion [Fe2(C2O4)5]4- -
r37980778c78--7f786098c120aee339446c69d9bb1b25
Several highly emissive, crystalline salts (ClO4-, PF6-, BF4-, B(C6F5)4-, and tfpb-; B(C6F5)4- = tetrakis(pentafluorophenyl)borate; tfpb- =... -
Bisindolylmaleimides as Red Electroluminescence Materials
Derivatives of bisindolylmaleimide were found to form amorphous solid films which exhibit red luminescence, and can be fabricated into light-emitting diodes. The property of... -
The Use of Imidazolium-2-dithiocarboxylates in the Formation of Gold(I) Compl...
The imidazolium-2-dithiocarboxylate ligands IPr·CS2, IMes·CS2, and IDip·CS2 react with [AuCl(PPh3)] to yield [(Ph3P)Au(S2C·IPr)]+, [(Ph3P)Au(S2C·IMes)]+, and... -
New Lanthanide Complexes for Sensitized Visible and Near-IR Light Emission: ...
We describe the syntheses, the 1H NMR studies in CD3OD and D2O as solvent, the X-ray characterization, and the luminescence properties in D2O solution of the two complexes Eu·1... -
Synthesis, Structure, and Isomerization of Decapentynylcorannulene: Enediyne...
Decapentynylcorannulene (5) is prepared via aryl−alkyne coupling chemistry of decachlorocorannulene and trimethylstannylpentyne. The crystal structure of 5 is compared with the... -
r37980778c78--a5a3c47f6ff2f2bd082700fecdba83bd
The reaction of [Co6C(CO)15]2− with 2 equiv of PtCl2(Et2S)2 affords the new heterobimetallic [Co8Pt4C2(CO)24]2−, [1]2−, carbonyl cluster. [1]2− undergoes reversible chemical and... -
Charge-Transfer Salts via Cocrystallization of the Cationic Ferrocenyl Donor ...
Four new charge-transfer (CT) salts based on the cationic ferrocenylmethylpyridinium (fmp) donor (CpFeCp-CH2-Py+) and polyoxometalate (POM) acceptors, Lindqvist-type [M6O19]2−... -
Structural and Mechanistic Studies of the Dehydration of MoO<sub>2</sub>PO<su...
We report investigations into the dehydration pathway of the precursor material MoO2PO3OH·H2O to γ-(MoO2)2P2O7. The reaction occurs in three distinct stages via the formation of... -
r37980778c78--cb93bf378e256de6af0e26fd4b2fa9a0
Recent studies have demonstrated that the r-tctct isomer of ethylpyrogall[6]arene (6EPGR) can be readily isolated as a minor product of the synthesis of the corresponding... -
Syntheses, Structures, Near-Infrared and Visible Luminescence, and Magnetic P...
Reactions of tripodal ligand 1,3,5-tris(imidazole-1-ylmethyl)-2,4,6-trimethylbenzene (L) with lanthanide metal salts and triethyl orthoformate led to the formation of six... -
Structure and Magnetism of a Spin Ladder System: (C<sub>5</sub>H<sub>9</sub>...
The crystal structure of bis(cyclopentylammonium)tetrabromocuprate(II) has been determined at room temperature and at −70 °C. The room temperature structure is orthorhombic,... -
Optical Resolution of (±)-1,2-Bis(2-methylphenyl)ethylene-1,2-diamine as a Ch...
(±)-1,2-Bis(2-methylphenyl)ethylene-1,2-diamine, prepared from benzil and ammonium acetate, was optically resolved as a chiral framework for... -
Luminescent Lanthanide Oxalatophosphites with a 3D Framework Structure: [Ln(H...
Luminescent Lanthanide Oxalatophosphites with a 3D Framework Structure: [Ln(H2O)(C2O4)0.5(HPO3)]·H2O (Ln = Pr, Nd, and Sm−Lu) -
Design of a New Family of Inorganic Compounds Ae<sub>2</sub>F<sub>2</sub>SnX<...
We could predict the structure of a new family of compounds Ae2F2SnX3 (Ae = Sr, Ba; X = S, Se) from the stacking of known 2D building blocks of the rock salt and fluorite types.... -
r37980778c78--545011d4dd4486c56f37a2898bd5d021
We present a quantum mechanical/molecular mechanical (QM/MM) study using the AM1 Hamiltonian and a flexible MM part on the mode of action of the bovine lens leucine...