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Tunability of Supramolecular Kagome Lattices of Magnetic Phthalocyanines Usin...
Self-assembly of various phthalocyanine (Pc) molecules and a derivative on an epitaxial graphene monolayer (MG) has been investigated by means of in situ ultrahigh vacuum... -
Rational Designs for Highly Proton-Conductive Metal−Organic Frameworks
A novel metal−organic framework (MOF), (NH4)2(adp)[Zn2(ox)3]·3H2O (1) was synthesized and its structure was determined. We propose three types of rational design to introduce... -
Mechanism of Hydrogen Sorption in Single-Walled Carbon Nanotubes
Mechanism of Hydrogen Sorption in Single-Walled Carbon Nanotubes -
Pressure-Induced Amorphization and Porosity Modification in a Metal−Organic F...
The impact of modest, industrially accessible pressures (0−1.2 GPa) on the structure and porosity of the zeolitic imidazolate framework Zn(2-methylimidazole)2, ZIF-8, was... -
Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials
We report the H_2 uptake properties of six covalent organic frameworks (COFs) from first-principles-based grand canonical Monte-Carlo simulations. The predicted H_2 adsorption... -
Au@ZIF-8: CO Oxidation over Gold Nanoparticles Deposited to Metal−Organic Fra...
Gold nanoparticles (NPs) were deposited to a zeolite-type metal−organic framework (MOF) by a simple solid grinding method. A catalyst, Au@ZIF-8, represents the first example of... -
Highly Porous and Robust 4,8-Connected Metal−Organic Frameworks for Hydrogen ...
Highly porous and robust metal−organic frameworks (MOFs) were constructed based on aromatics-rich octa-carboxylate ligands and copper paddle-wheel building units. Each... -
A Selective and Sensitive Fluoroionophore for HgII, AgI, and CuIIwith Virtual...
A Selective and Sensitive Fluoroionophore for HgII, AgI, and CuII with Virtually Decoupled Fluorophore and Receptor Units -
Tin Nanoparticles Encapsulated in Porous Multichannel Carbon Microtubes: Prep...
Tin nanoparticles encapsulated in porous multichannel carbon microtubes (denoted as SPMCTs) were prepared by carbonization of electrospun PAN−PMMA−tin octoate nanofibers... -
Iridium-catalyzed borylation of benzene with diboron. Theoretical elucidation...
Iridium-catalyzed borylation of benzene with diboron was theoretically investigated with the DFT method, where an iridium(I) boryl complex, Ir(Beg)(NN) 1, and an iridium(III)... -
Responsive Periodic Mesoporous Polydiacetylene/Silica Nanocomposites
Responsive PMO materials have been synthesized through co-assembly of bridged diacetylenic silsesquioxane and surfactant. The spatially defined polydiacetylenic component,... -
Design and Construction of a 2D Metal Organic Framework with Multiple Cavitie...
A metal organic framework with two different nodes (circle and square) and a structure related to one of the 20 known 2-uniform nets has been constructed using an organic... -
"Clickable" Metal−Organic Framework
We demonstrated the metal−organic framework bearing the azide group in the organic linkers and in situ click reactions with some small alkynes. The XRPD patterns indicated that... -
Metal Carbene-Promoted Sequential Transformations for the Enantioselective Sy...
A two-step, three-component coupling of an alkyne, enol ether, and vinyl diazoester was accomplished by use of successive metal carbene-catalyzed transformations. This efficient... -
Heavy Atom Ferromagnets under Pressure: Structural Changes and the Magnetic R...
Application of physical pressure to a ferromagnetic bisdiselenazolyl radical leads to a decrease in π-stack slippage. Initially, this leads to an increase in the ferromagnetic... -
Diverse Reactivity Manifolds of Alkynyl Enone- and Alkynyl Enal-Derived Nicke...
Diverse Reactivity Manifolds of Alkynyl Enone- and Alkynyl Enal-Derived Nickelacycles: Discovery of Nickel-Promoted [3+2] and [2+1] Cycloadditions -
Single Chain Magnets Based on the Oxalate Ligand
The anionic oxalate-bridged bimetallic chain [Co(H2O)2Cr(ox)3]− shows slow relaxation of the magnetization, typical of the so-called single-chain magnets, when crystallized in... -
Isoreticular Metalation of Metal−Organic Frameworks
Sequential covalent transformation and metalation were performed on (Zn4O)3(BDC-NH2)3(BTB)4 with maintenance of crystallinity and porosity. Reaction of (Zn4O)3(BDC-NH2)3(BTB)4... -
Ruthenium(II) Dendrimers Containing Carbazole-Based Chromophores as Branches
Three new luminescent and redox-active Ru(II) complexes containing novel dendritic polypyridine ligands have been synthesized, and their absorption spectra, luminescence...
