-
Construction of Novel Polycyclic Ring Systems by Transition-Metal-Catalyzed C...
Construction of Novel Polycyclic Ring Systems by Transition-Metal-Catalyzed Cycloisomerization of Ene−Ene−Ynes. Interception of a Carbenoid Intermediate in Skeletal... -
Tunability of Supramolecular Kagome Lattices of Magnetic Phthalocyanines Usin...
Self-assembly of various phthalocyanine (Pc) molecules and a derivative on an epitaxial graphene monolayer (MG) has been investigated by means of in situ ultrahigh vacuum... -
Rational Designs for Highly Proton-Conductive Metal−Organic Frameworks
A novel metal−organic framework (MOF), (NH4)2(adp)[Zn2(ox)3]·3H2O (1) was synthesized and its structure was determined. We propose three types of rational design to introduce... -
Highly Luminescent, Triple- and Quadruple-Stranded, Dinuclear Eu, Nd, and Sm(...
The bis(β-diketone) ligands 1,3-bis(3-phenyl-3-oxopropanoyl)benzene, H2L1 and 1,3-bis(3-phenyl-3-oxopropanoyl) 5-ethoxy-benzene, H2L2, have been prepared for the examination of... -
Amphiphilic Janus Gold Nanoparticles via Combining "Solid-State Grafting-to" ...
Despite the great efforts that have been made toward obtaining Janus architectures, synthesizing sub-10 nanometer Janus nanoparticles (NPs) modified with different types of... -
Atomic Layer Deposition of Metal Tellurides and Selenides Using Alkylsilyl Co...
Atomic layer deposition (ALD) of metal selenide and telluride thin films has been limited because of a lack of precursors that would at the same time be safe and exhibit high... -
Mechanism of Hydrogen Sorption in Single-Walled Carbon Nanotubes
Mechanism of Hydrogen Sorption in Single-Walled Carbon Nanotubes -
Bimetallic Catalysis for Styrene Homopolymerization and Ethylene−Styrene Copo...
This communication reports the styrene homopolymerization behavior and ethylene−styrene copolymerization behavior of the covalently linked bimetallic constrained geometry... -
Pressure-Induced Amorphization and Porosity Modification in a Metal−Organic F...
The impact of modest, industrially accessible pressures (0−1.2 GPa) on the structure and porosity of the zeolitic imidazolate framework Zn(2-methylimidazole)2, ZIF-8, was... -
Coibamide A, a Potent Antiproliferative Cyclic Depsipeptide from the Panamani...
Coibamide A (1) is a new, potent antiproliferative depsipeptide which was isolated from a marine Leptolyngbya cyanobacterium collected from the Coiba National Park, Panama. The... -
Domino Coupling Relay Approach to Polycyclic Pyrrole-2-carboxylates
CuBr2-catalyzed three-component coupling of N-benzylallylamine, ethyl glyoxalate, and terminal alkynes afforded glycine-tethered 1,6-enynes, which were further transformed into... -
Catalytic Enantioselective Hydroboration of Cyclopropenes
2,2-Disubstituted cyclopropyl boronates have been synthesized with high degrees of diastereo- and enantioselectivity via the rhodium-catalyzed asymmetric hydroboration of... -
Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials
We report the H_2 uptake properties of six covalent organic frameworks (COFs) from first-principles-based grand canonical Monte-Carlo simulations. The predicted H_2 adsorption... -
Rational Design of Cavitand Receptors for Mass Sensors
This Communication describes a rational approach to the fabrication of selective mass sensors, using multiple hydrogen-bonding type interactions encoded in a single cavitand... -
Oxygen-Atom Transfer from Carbon Dioxide to a Fischer Carbene at (PNP)Ir
Dehydrogenation of the dihydride (PNP)IrH_2 with norbornylene in the presence of t-butyl methyl ether leads to formation of an iridium(I) Fischer carbene complex,... -
Photoregulated release of caged anticancer drugs from gold nanoparticles
An anticancer drug (5-fluorouracil) was conjugated to the surface of gold nanoparticles through a photocleavable o-nitrobenzyl linkage. In this system, the particle serves as... -
Total Synthesis of (±)-Chartelline C
The first total synthesis of (±)-chartelline C in a concise 10-step sequence is reported. Highlights of the completion of this decades-old puzzle include (1) chemo- and... -
Au@ZIF-8: CO Oxidation over Gold Nanoparticles Deposited to Metal−Organic Fra...
Gold nanoparticles (NPs) were deposited to a zeolite-type metal−organic framework (MOF) by a simple solid grinding method. A catalyst, Au@ZIF-8, represents the first example of... -
Chiral Arylaminophosphonium Barfates as a New Class of Charged Brønsted Acid ...
Heterochiral [7.7]-P-spirocyclic arylaminophosphonium barfates have been designed as a novel charged, cationic Bronsted acid catalyst, and their catalytic and stereocontrolling... -
Template-Directed Photoreversible Ligation of Deoxyoligonucleotides via 5-Vin...
Template-Directed Photoreversible Ligation of Deoxyoligonucleotides via 5-Vinyldeoxyuridine
